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Hematolite

A valid IMA mineral species - grandfathered
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About HematoliteHide

Formula:
(Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23
Cation requirements for charge balance suggest that there about two 3+ cations per formula unit. The original 3+ cations determined by Moore and Araki (1978) were Al-dominant. Polytypic stacking may be present resulting in formula variations.
Colour:
Brown-red, blood-red, nearly black; reddish orange to yellowish brown in transmitted light.
Lustre:
Vitreous, Sub-Vitreous, Resinous, Pearly, Sub-Metallic
Hardness:
3½
Specific Gravity:
3.49
Crystal System:
Trigonal
Name:
Named as aimatolit (Swedish) in 1884 by Lars Johan Igelstrom from the Greek αίμα for "blood" and λίθος for "stone", in allusion to its red pyrope-like colour.
Dark blood-red platy crystals (< 1 mm) and crusts.


Unique IdentifiersHide

Mindat ID:
1857
Long-form identifier:
mindat:1:1:1857:5

Similar NamesHide

IMA Classification of HematoliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
(Mn2+,Mg,Al)15(As3+O3)(As5+O4)2(OH)23

Classification of HematoliteHide

8.BE.45

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
E : With only medium-sized cations, (OH, etc.):RO4 > 2:1
43.4.6.1

43 : COMPOUND PHOSPHATES, ETC.
4 : Anhydrous Compound Phosphates, etc·, Containing Hydroxyl or Halogen
20.8.21

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
HmtIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HematoliteHide

Vitreous, Sub-Vitreous, Resinous, Pearly, Sub-Metallic
Transparency:
Translucent
Comment:
Pearly to sub-metallic on cleavage surfaces.
Colour:
Brown-red, blood-red, nearly black; reddish orange to yellowish brown in transmitted light.
Streak:
Light chocolate-brown to reddish brown
Hardness:
3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
On {0001}, perfect
Fracture:
Irregular/Uneven
Density:
3.49 g/cm3 (Measured)    3.48 g/cm3 (Calculated)

Optical Data of HematoliteHide

Type:
Uniaxial (-)
RI values:
nω = 1.733 nε = 1.714
Birefringence:
0.019
Max. Birefringence:
δ = 0.019
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Non-pleochroic
Comments:
The crystals are divided into differently oriented, anomalously biaxial sectors at times.

Chemistry of HematoliteHide

Mindat Formula:
(Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23

Cation requirements for charge balance suggest that there about two 3+ cations per formula unit. The original 3+ cations determined by Moore and Araki (1978) were Al-dominant. Polytypic stacking may be present resulting in formula variations.
Element Weights:
Element% weight
Mn50.995 %
O33.662 %
As13.909 %
H1.435 %

Calculated from ideal end-member formula.
Mn
O
As
H

Crystallography of HematoliteHide

Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 8.275 Å, c = 36.60 Å
Ratio:
a:c = 1 : 4.423
Unit Cell V:
2,170.44 ų (Calculated from Unit Cell)
Z:
3
Morphology:
Crystals thick tabular {0001} with large {0115}, or rhombohedral with {0115} alone. The rhombohedral faces are striated horizontally.
Comment:
Basic repeat distance of 12.2 A of a five-layer structure found

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000610HematoliteMoore P B, Araki T (1978) Hematolite: A complex dense-packed sheet structure American Mineralogist 63 150-15919780293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.12 Å(80)
5.63 Å(30)
5.20 Å(50)
4.14 Å(80)
3.40 Å(40)
4.22 Å(40)
2.60 Å(40)
2.39 Å(100)
1.562 Å(90)
Comments:
Berry and Graham (1948)

Geological EnvironmentHide

Paragenetic Mode(s):
Geological Setting:
Unnamed, possible ferric analog of hematolite occurs at Ogdensburg, New Jersey (Dunn and Peacor, 1983). The mineral occurs in fractures of red willemite-franklinite-calcite ore as well as on friedelite-magnetite rock.

Type Occurrence of HematoliteHide

Geological Setting of Type Material:
Veinlets or cavities in crystalline limestone of a stratabound Mn-Fe ore deposit.
Associated Minerals at Type Locality:

Synonyms of HematoliteHide

Other Language Names for HematoliteHide

Relationship of Hematolite to other SpeciesHide

Other Members of Hematolite Group:
Arakiite(Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As5+O4)2(As3+O3)(OH)23Mon. m : Bb
DixeniteCuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6Trig. 3 : R3
KraissliteZn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16Orth. 222 : C2221
McgoverniteMn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21Trig. 3m : R3c
SynadelphiteMn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2OOrth. mmm(2/m2/m2/m) : Pnma
Turtmannite(Mn,Mg)22.5Mg3-3x((V5+,As5+)O4)3(As3+O3)x(SiO4)3O5-5x(OH)20+xTrig.

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Hematolite associated with AllactiteMn2+7(AsO4)2(OH)8
4 photos of Hematolite associated with PyrochroiteMn(OH)2
4 photos of Hematolite associated with SynadelphiteMn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2O
4 photos of Hematolite associated with CalciteCaCO3
4 photos of Hematolite associated with MagnetiteFe2+Fe3+2O4
3 photos of Hematolite associated with DolomiteCaMg(CO3)2
1 photo of Hematolite associated with JacobsiteMn2+Fe3+2O4
1 photo of Hematolite associated with AkrochorditeMnMn2Mn2(AsO4)2(OH)4(H2O)4
1 photo of Hematolite associated with BaryteBaSO4

Related Minerals - Strunz-mindat GroupingHide

8.BE.05AugeliteAl2(PO4)(OH)3Mon. 2/m : B2/m
8.BE.10GrattarolaiteFe3+3(PO4)O3Trig. 3m : R3m
8.BE.15CornetiteCu3(PO4)(OH)3Orth. mmm(2/m2/m2/m) : Pbca
8.BE.20ClinoclaseCu3(AsO4)(OH)3Mon. 2/m : P21/b
8.BE.25GilmariteCu3(AsO4)(OH)3Tric. 1 : P1
8.BE.25ArhbariteCu2Mg(AsO4)(OH)3Tric. 1 : P1
8.BE.30FlinkiteMn2+2Mn3+(AsO4)(OH)4Orth. mmm(2/m2/m2/m) : Pnma
8.BE.30ArganditeMn7(VO4)2(OH)8Mon. 2/m : P21/m
8.BE.30RaadeiteMg7(PO4)2(OH)8Mon. 2/m
8.BE.30AllactiteMn2+7(AsO4)2(OH)8Mon. 2/m : P21/b
8.BE.35'Mineral E (of Dunn, et. al., 1982)'Orth. mmm(2/m2/m2/m)
8.BE.35Chlorophoenicite(Mn,Mg)3Zn2(AsO4)(OH,O)6Mon. 2/m : B2/m
8.BE.35Magnesiochlorophoenicite(Mg,Mn)3Zn2(AsO4)(OH,O)6Mon. 2/m : B2/m
8.BE.40Gerdtremmelite(Zn,Fe)(Al,Fe)2(AsO4)(OH)5Tric.
8.BE.45DixeniteCuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6Trig. 3 : R3
8.BE.45McgoverniteMn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21Trig. 3m : R3c
8.BE.45Turtmannite(Mn,Mg)22.5Mg3-3x((V5+,As5+)O4)3(As3+O3)x(SiO4)3O5-5x(OH)20+xTrig.
8.BE.45CarlfrancisiteMn2+3(Mn2+,Mg,Fe3+,Al)42[As3+O3]2(As5+O4)4[(Si,As5+)O4]6[(As5+,Si)O4]2(OH)42Trig. 3m : R3c
8.BE.45Arakiite(Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As5+O4)2(As3+O3)(OH)23Mon. m : Bb
8.BE.45KraissliteZn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16Orth. 222 : C2221
8.BE.50SynadelphiteMn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2OOrth. mmm(2/m2/m2/m) : Pnma
8.BE.55Holdenite(Mn2+,Mg)6Zn3(AsO4)2(SiO4)(OH)8Orth. mmm(2/m2/m2/m) : Ccca
8.BE.60KoliciteMn2+7Zn4(AsO4)2(SiO4)2(OH)8Orth. mmm(2/m2/m2/m) : Cmca
8.BE.65Sabelliite(Cu,Zn)2Zn(AsO4,SbO4)(OH)3Trig. 3 : P3
8.BE.70JarosewichiteMn2+3Mn3+(AsO4)(OH)6Orth. 222
8.BE.75TheisiteCu5Zn5(AsO4,SbO4)2(OH)14Orth.
8.BE.80CoparsiteCu4(AsO4,VO4)O2ClOrth. mmm(2/m2/m2/m) : Pbcm
8.BE.85WaterhouseiteMn2+7(PO4)2(OH)8Mon. 2/m : P21/b
8.BE.90VasilseverginiteCu9O4(AsO4)2(SO4)2Mon. 2/m

Fluorescence of HematoliteHide

Not fluorescent in UV

Other InformationHide

Notes:
Readily soluble in acids.

Alters to Manganite.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HematoliteHide

References for HematoliteHide

Reference List:

Localities for HematoliteHide

Showing 8 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Sweden
 
  • Värmland County
    • Filipstad
      • Långban Ore District
Holtstam et al. (1999)
Natural History Museum
Österberg (2003)
Gatedal (n.d.) +2 other references
Moore (1978)
Nysten (1987)
Igelström (1884) +3 other references
      • Persberg ore district
        • Pajsberg
Nysten (2004)
 
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