Sphalerite Group
A group of related mineral species
This page is currently not sponsored. Click here to sponsor this page.
About Sphalerite Group
Formula:
AX
A = Cd, Hg, Zn, Mn, Fe, Cu
X = S, Se, Te
X = S, Se, Te
Crystal System:
Isometric
The diamond structure has two interpenetrating cubic close packed carbon lattices. Each atom of theses lattices is tetrahedrally coordinated by 4 atoms of the other lattice. If one of these lattices is replaced by cations (A) and the other replaced by anions (X), where X = S, Se, Te we get the sphalerite group.
Although the members can be lab grown as solution series, geochemical segregation usually gives fairly pure end members.
Compare Wurtzite Group.
Although the members can be lab grown as solution series, geochemical segregation usually gives fairly pure end members.
Compare Wurtzite Group.
Unique Identifiers
Mindat ID:
29333
Long-form identifier:
mindat:1:1:29333:2
Chemistry of Sphalerite Group
Mindat Formula:
AX
A = Cd, Hg, Zn, Mn, Fe, Cu
X = S, Se, Te
A = Cd, Hg, Zn, Mn, Fe, Cu
X = S, Se, Te
Age distribution
Recorded ages:
Phanerozoic : 519 Ma to 0 Ma - based on 25 recorded ages.
Sample ages:
| Sample ID | Recorded age | Geologic Time | Dating method |
|---|---|---|---|
| 1 | 2.588 Ma to present day | Pleistocene | Formed in peat. |
| 2 | 51.7 to 48.9 Ma | Eocene | fission track |
| 3 | 110 ± 2 Ma | Early/Lower Cretaceous | Rb-Sr |
| 4 | 170 ± 4 Ma | Middle Jurassic | Rb-Sr |
| 5 | 288 Ma | Cisuralian | Rb-Sr |
| 6 | 298 Ma | Cisuralian | Rb-Sr |
| 7 | 309 Ma | Pennsylvanian | Rb-Sr |
| 8 | 318 Ma | Pennsylvanian | Rb-Sr |
| 9 | 329 Ma | Mississippian | Rb-Sr |
| 10 | 338 Ma | Mississippian | Rb-Sr |
| 11 | 349 Ma | Mississippian | Rb-Sr |
| 12 | 357 Ma | Mississippian | Rb-Sr |
| 13 | 361 Ma | Late/Upper Devonian | Rb-Sr |
| 14 | 370 Ma | Late/Upper Devonian | Rb-Sr |
| 15 | 385 Ma | Middle Devonian | Rb-Sr |
| 16 | 392 Ma | Middle Devonian | Rb-Sr |
| 17 | 421 Ma | Pridoli | Rb-Sr |
| 18 | 451 Ma | Late/Upper Ordovician | Rb-Sr |
| 19 | 487 Ma | Furongian | Rb-Sr |
| 20 | 519 Ma | Cambrian Series 2 | Rb-Sr |
Sample references:
Chemical Analysis
Oxide wt%:
| 1 | 2 | |
|---|---|---|
| Zn | 62.51 % | 31.03 % |
| In | 0.56 % | 24.89 % |
| Sn | 0.2 % | |
| Fe | 2.89 % | 0.05 % |
| Cu | 0.3 % | 13.49 % |
| S | 34.23 % | 29.51 % |
| Ga | 0.96 % | |
| Cd | 0.54 % | |
| Total: | 100.69 % | 100.47 % |
Sample references:
| ID | Locality | Reference | Notes |
|---|---|---|---|
| 1 | Mount Pleasant Mine, Saint George Parish, Charlotte Co., New Brunswick, Canada | Average of 5 EMPA analyses of sphalerite witth dzhalindite inclusions associated with calcite, galena and quartz. | |
| 2 | Restauradora vein, Capillitas mining district, Andalgalá, Andalgalá Department, Catamarca Province, Argentina | average of 10 analytical spots |
Crystallography of Sphalerite Group
Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Morphology:
Composite and twinned crystals are common.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0020262 | Ishiharaite | Marquez-Zavalia M F, Galliski M A, Drabek M, Vymazalova A, Watanabe Y, Murakami H, Bernhardt H J (2015) Ishiharaite, (Cu,Ga,Fe,In,Zn)S, a new mineral from the Capillitas mine, Northwestern Argentina The Canadian Mineralogist 52 969-980 | 2015 | Capillitas mine, Argentina | 0 | 293 | |
| 0019735 | Browneite | Ma C, Beckett J R, Rossman G R (2012) Browneite, MnS, a new sphalerite-group mineral from the Zaklodzie meteorite American Mineralogist 97 2056-2059 | 2012 | Zaklodzie meteorite | 0 | 293 | |
| 0004584 | Rudashevskyite | Britvin S N, Bogdanova A N, Boldyreva M M, Aksenova G Y (2008) Rudashevskyite, the Fe-dominant analogue of sphalerite, a new mineral: Description and crystal structure American Mineralogist 93 902-909 | ![]() | 2008 | Indarch meteorite | 0 | 293 |
| 0004583 | Rudashevskyite | Britvin S N, Bogdanova A N, Boldyreva M M, Aksenova G Y (2008) Rudashevskyite, the Fe-dominant analogue of sphalerite, a new mineral: Description and crystal structure American Mineralogist 93 902-909 | ![]() | 2008 | Indarch meteorite | 0 | 293 |
| 0004582 | Rudashevskyite | Britvin S N, Bogdanova A N, Boldyreva M M, Aksenova G Y (2008) Rudashevskyite, the Fe-dominant analogue of sphalerite, a new mineral: Description and crystal structure American Mineralogist 93 902-909 | ![]() | 2008 | Indarch meteorite | 0 | 293 |
| 0018328 | Sphalerite | Nitta E, Kimata M, Hoshino M, Echigo T, Hamasaki S, Nishida N, Shimizu M, Akasak T (2008) Crystal chemistry of ZnS minerals formed as high-temperature volcanic sublimates: matraite identical with sphalerite Journal of Mineralogical and Petrological Sciences 103 145-151 | 2008 | Iwodake volcano, Satsuma-Iwojima, Kyushu, SW Japan | 0 | 293 | |
| 0000110 | Sphalerite | Skinner B J (1961) Unit-cell edges of natural and synthetic sphalerites American Mineralogist 46 1399-1411 | ![]() | 1961 | synthetic | 0 | 293 |
| 0000111 | Hawleyite | Skinner B J (1961) Unit-cell edges of natural and synthetic sphalerites American Mineralogist 46 1399-1411 | ![]() | 1961 | synthetic | 0 | 293 |
| 0011532 | Browneite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237 | 1963 | 0 | 293 | ||
| 0011527 | Tiemannite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237 | 1963 | 0 | 293 | ||
| 0011535 | Stilleite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237 | 1963 | 0 | 293 | ||
| 0011526 | Metacinnabar | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237 | 1963 | 0 | 293 | ||
| 0011517 | Hawleyite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237 | 1963 | 0 | 293 | ||
| 0011528 | Coloradoite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237 | 1963 | 0 | 293 | ||
| 0000070 | Hawleyite | Traill R J, Boyle R W (1955) Hawleyite, isometric cadmium sulphide, a new mineral American Mineralogist 40 555-559 | ![]() | 1955 | 0 | 293 | |
| 0000050 | Tiemannite | Earley J W (1950) Description and syntheses of the selenide minerals American Mineralogist 35 337-364 | ![]() | 1950 | 0 | 293 | |
| 0018216 | Browneite | Mehmed F, Haraldsen H (1938) Das magnetische Verhalten der allotropen Modifikationen des Mangan(II)- Sulfides Zeitschrift fur Anorganische und Allgemeine Chemie 235 193-200 | 1938 | 0 | 293 | ||
| 0018113 | Hawleyite | Mueller W, Loeffler G (1933) Zur Kenntnis der Faerbung von gefaelltem Cadmiumsulfid _cod_database_code 1011251 Angewandte Chemie (German Edition) 46 538-539 | 1933 | 0 | 293 | ||
| 0018099 | Sphalerite | de Jong W (1927) Marmatit und christophit _cod_database_code 1011233 Zeitschrift fur Kristallographie 66 515-515 | 1927 | 0 | 293 | ||
| 0018098 | Sphalerite | de Jong W (1927) Marmatit und christophit _cod_database_code 1011232 Zeitschrift fur Kristallographie 66 515-515 | 1927 | 0 | 293 | ||
| 0018070 | Tiemannite | de Jong W (1926) Die Struktur des Tiemannit und Koloradoit _cod_database_code 1011199 Zeitschrift fur Kristallographie 63 466-472 | 1926 | 0 | 293 | ||
| 0017442 | Coloradoite | Zachariasen W (1926) Die Kristallstruktur der Telluride von Zink, Cadmium und Quecksilber _cod_database_code 1010537 Norsk Geologisk Tidsskrift 8 302-306 | 1926 | 0 | 293 | ||
| 0017666 | Coloradoite | de Jong W (1926) Die Struktur des Tiemannit und Koloradoit. _cod_database_code 1010945 Zeitschrift fur Kristallographie 63 466-472 | 1926 | 0 | 293 | ||
| 0018121 | Hawleyite | Ulrich F, Zachariasen W (1925) Ueber die Kristallstruktur des alpha und beta Cd S, sowie des Wurtzits _cod_database_code 1011260 Zeitschrift fur Kristallographie 62 260-273 | 1925 | 0 | 293 | ||
| 0018202 | Metacinnabar | Lehmann W (1924) Roentgenographische Untersuchungen an natuerlichem und synthetischem Metacinnabarit (Hg S). _cod_database_code 1011368 Zeitschrift fur Kristallographie 60 379-413 | 1924 | 0 | 293 |
CIF Raw Data - click here to close
Relationship of Sphalerite Group to other Species
Sphalerite Group Members:
| Browneite | MnS | Iso. 43m : F43m |
| Coloradoite | HgTe | Iso. 43m : F43m |
| Hawleyite | CdS | Iso. 43m : F43m |
| Ishiharaite | (Cu,Ga,Fe,In,Zn)S | Iso. 43m : F43m |
| Metacinnabar | HgS | Iso. 43m : F43m |
| Rudashevskyite | (Fe,Zn)S | Iso. 43m : F43m |
| Sphalerite | ZnS | Iso. 43m : F43m |
| Stilleite | ZnSe | Iso. 43m : F43m |
| Tiemannite | HgSe | Iso. 43m : F43m |
Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.
Minerals structurally related to group:
| 'Isocubanite' | CuFe2S3 | |
| 'Sakuraiite' | (Cu,Zn,Fe)3(In,Sn)S4 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Sphalerite Group in petrology
An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.
Internet Links for Sphalerite Group
mindat.org URL:
https://www.mindat.org/min-29333.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
Mineral Dealers:
References for Sphalerite Group
Reference List:
Significant localities for Sphalerite Group
Showing 62 significant localities out of 28,347 recorded on mindat.org.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| [Ishiharaite] Williams et al. (2014) +2 other references |
Austria | |
| [Sphalerite var: Schalenblende] Fotini Kanaki (1972) |
| [Sphalerite, Sphalerite var: Schalenblende] | |
Azerbaijan | |
| [Rudashevskyite] Britvin et al. (2008) |
Canada | |
| [Sphalerite] Mielke (n.d.) +1 other reference |
| [Hawleyite] Traill et al. (1955) |
DR Congo | |
| [Stilleite] Ramdohr (1956) +2 other references |
France | |
| [Sphalerite] Belot (1978) |
| [Sphalerite] Mines +1 other reference |
| [Sphalerite] J F Carpenter specimen |
Germany | |
| [Sphalerite var: Schalenblende] - (1985) |
| [Sphalerite] Kirill Vlasov |
| [Tiemannite] Weiß (1990) |
| [Sphalerite] - (2005) |
| [Sphalerite var: Schalenblende] Harjo Neutkens collection. |
Ireland | |
| [Sphalerite] Flannery (n.d.) +2 other references |
| [Sphalerite] Flannery (n.d.) +1 other reference |
| [Sphalerite] Flannery (n.d.) +2 other references | |
| [Sphalerite] Moreton (1999) | |
Italy | |
| [Sphalerite] Cioffi M. (Alpi Apuane) +1 other reference |
| [Sphalerite] Biagioni et al. (2008) |
| [Sphalerite] Benvenuti et al. (2000) |
| [Sphalerite] Dini (1995) | |
| [Sphalerite] Orlandi et al. (2004) |
Japan | |
| [Metacinnabar] - (n.d.) +1 other reference |
Kazakhstan | |
| [Sphalerite] RWMW specimen +2 other references |
Kosovo | |
| [Sphalerite] Féraud J. (1979) +3 other references |
Norway | |
| [Sphalerite] Neumann (1944) |
| [Sphalerite] Torkelsen (1993) |
Peru | |
| [Sphalerite] - (1997) +2 other references |
| [Sphalerite] Imai et al. (1985) +2 other references |
| [Sphalerite] - (1997) +1 other reference |
| [Sphalerite] - (1997) |
| [Sphalerite] Burkart-Baumann +2 other references |
Poland | |
| [Sphalerite] Andrzejewski K. (1993) |
| [Browneite] Ma et al. (2012) +1 other reference |
| [Sphalerite var: Schalenblende] Haas (n.d.) +1 other reference |
Romania | |
| [Sphalerite] Mârza +10 other references |
Russia | |
| [Sphalerite] Dobovol'skaya et al. (1990) +3 other references |
South Africa | |
| [Sphalerite] Wilson (2001) |
Spain | |
| [Sphalerite] Calvo et al. (1993) +1 other reference |
| [Sphalerite] Gómez Fernández et al. (2006) |
| [Metacinnabar] Olia et al. (1990) +1 other reference |
| [Sphalerite var: Marmatite] Calvo Rebollar (2003) |
Switzerland | |
| [Sphalerite] Graeser et al. (1987) |
UK | |
| [Sphalerite] |
| [Sphalerite] Dunham (1990) | |
| [Sphalerite] David Baldwin |
USA | |
| [Metacinnabar] USBM IC8252 +7 other references |
| [Coloradoite] Dana 7:I:219. +1 other reference |
| [Coloradoite] Eckel et al. (1997) |
| [Coloradoite] Eckel et al. (1997) | |
| [Sphalerite] Robinson et al. (1984) +1 other reference |
| [Sphalerite] Januzzi (1994) +1 other reference |
| [Sphalerite] Fluorite: The Collector's Choice. Extra ... +7 other references |
| [Sphalerite] J. Zolan +2 other references |
| [Sphalerite] J. Wingard |
| [Sphalerite] Sherwood et al. (1998) |
| [Sphalerite var: Cleiophane] |
| [Sphalerite] Kyle (1976) +2 other references |
| [Sphalerite] Rocks & Min. +2 other references |








symbol to view information about a locality.
The
Mount Diablo Mine, Mount Diablo, Clayton, Contra Costa County, California, USA