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Carpholite Group

A group of related mineral species

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Photos of Carpholite Group (129)Discuss Carpholite Group

Carpholite Group Gallery Search Photos of Carpholite Group

Edit Carpholite Group Add Synonym Edit CIF structures Clear Cache

Carpholite

Krásno, Sokolov District, Karlovy Vary Region, Czech Republic

Ferrocarpholite

Monte Leoni, Grosseto Province, Tuscany, Italy

Vanadiocarpholite

Molinello Mine, Ne, Genoa, Liguria, Italy

Carpholite

Krásno, Sokolov District, Karlovy Vary Region, Czech Republic

Ferrocarpholite

Monte Leoni, Grosseto Province, Tuscany, Italy

Vanadiocarpholite

Molinello Mine, Ne, Genoa, Liguria, Italy

Carpholite

Krásno, Sokolov District, Karlovy Vary Region, Czech Republic

Ferrocarpholite

Monte Leoni, Grosseto Province, Tuscany, Italy

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About Carpholite GroupHide

Carpholite group minerals are double-chain silicates. Pairs of single-chains parallel to [001] are linked by Al3+ and (Mn,Mg,Fe 2+) in octahedral coordination to form a structure with several large cavities (Ferraris et al., 1992; Bertoldi et al., 2006).

Unique IdentifiersHide

Mindat ID:

30575

Long-form identifier:

mindat:1:1:30575:2

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Year	Locality	Temp (K)
0007106	Vanadiocarpholite	Basso R, Cabella R, Lucchetti G, Martinelli A, Palenzona A (2005) Vanadiocarpholite, Mn2+V3+Al(Si2O6)(OH)4, a new mineral from the Molinello mine, northern Apennines, Italy European Journal of Mineralogy 17 501-507	2005	Molinello mine, northern Apennines, Italy	293
0007105	Carpholite	Basso R, Cabella R, Lucchetti G, Martinelli A, Palenzona A (2005) Vanadiocarpholite, Mn2+V3+Al(Si2O6)(OH)4, a new mineral from the Molinello mine, northern Apennines, Italy European Journal of Mineralogy 17 501-507	2005	Molinello mine, northern Apennines, Italy	293
0006871	Magnesiocarpholite	Fuchs Y, Mellini M, Memmi I (2001) Crystal-chemistry of magnesiocarpholite: controversial X-ray diffraction, Mossbauer, FTIR and Raman results European Journal of Mineralogy 13 533-543	2001	Monte Leoni	293
0006870	Magnesiocarpholite	Fuchs Y, Mellini M, Memmi I (2001) Crystal-chemistry of magnesiocarpholite: controversial X-ray diffraction, Mossbauer, FTIR and Raman results European Journal of Mineralogy 13 533-543	2001	Monte Argentario	293
0014864	Ferrocarpholite	Ferraris G, Ivaldi G, Goffe B (1992) Structural study of a magnesian ferrocarpholite: Are carpholites monoclinic? Neues Jahrbuch fur Mineralogie, Monatshefte 1992 337-347	1992	Mascate nappes, Ruwi, Oman	293
0001265	Carpholite	Ghose S, Sen Gupta P K, Boggs R C, Schlemper E O (1989) Crystal chemistry of a nonstoichiometric carpholite, Kx(Mn2-x,Lix)Al4Si4O12(OH)4F4: A chain silicate related to pyroxenes American Mineralogist 74 1084-1090	1989	Sawtooth batholith, Idaho, USA	293
0000849	Magnesiocarpholite	Viswanathan K (1981) The crystal structure of a Mg-rich carpholite American Mineralogist 66 1080-1085	1981	southeast Sfinari, West Crete	293
0014762	Carpholite	Lindemann W, Wogerbauer R, Berger P (1979) Die kristallstruktur von karpholith (Mn0.97Mg0.08FeII0.07)(Al1.90FeIII0.01)Si2O6(OH)4 Neues Jahrbuch fur Mineralogie, Monatshefte 1979 282-287	1979	Schlaggenwald, Bohemia	293
0017757	Ferrocarpholite	MacGillavry C H, Korst W L, Weichel Moore E J, van der Plas H J (1956) The crystal structure of ferrocarpholite Acta Crystallographica 9 773-776	1956	west of Tomata, eastern Central Celebes, Indonesia	293
0017756	Carpholite	Naumova I S, Pobedimskaya E A, Belov N V (1974) Crystal structure of carpholite MnAl2(Si2O6)(OH)4 Kristallografiya 19 1155-1160	1974		293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Vanadiocarpholite'
loop_
_publ_author_name
'Basso R'
'Cabella R'
'Lucchetti G'
'Martinelli A'
'Palenzona A'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 17 
_journal_year 2005
_journal_page_first 501
_journal_page_last 507
_publ_section_title
;
 Vanadiocarpholite, Mn2+V3+Al(Si2O6)(OH)4, a new mineral
 from the Molinello mine, northern Apennines, Italy
 Note: sample VC
;
_database_code_amcsd 0007106
_chemical_compound_source 'Molinello mine, northern Apennines, Italy'
_chemical_formula_sum 'K.168 (Mn1.84 Mg.16) (V1.98 Al2.02) Si4 O20 H8'
_cell_length_a 13.830
_cell_length_b 20.681
_cell_length_c 5.188
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1483.863
_exptl_crystal_density_diffrn      3.166
_symmetry_space_group_name_H-M 'C c c a'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,1/2+y,1/2+z'
  '1/2-x,+y,1/2+z'
  'x,1/2-y,1/2-z'
  '1/2+x,-y,1/2-z'
  'x,1/2+y,-z'
  '1/2+x,+y,-z'
  '-x,1/2-y,z'
  '1/2-x,-y,z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
K   0.00000   0.75000   0.25000   0.16800   0.01267
Mn   0.00000   0.87700   0.75000   0.92000   0.00975
Mg   0.00000   0.87700   0.75000   0.08000   0.00975
V1   0.18360   0.75000   0.75000   0.84000   0.01089
Al1   0.18360   0.75000   0.75000   0.16000   0.01089
Al2   0.00000   0.96190   0.25000   0.85000   0.00633
V2   0.00000   0.96190   0.25000   0.15000   0.00633
Si   0.19390   0.87910   0.40960   1.00000   0.00735
O1   0.20310   0.80070   0.42090   1.00000   0.00950
O2   0.08220   0.89990   0.40580   1.00000   0.00988
O3   0.24930   0.90960   0.66250   1.00000   0.00899
OA   0.09820   0.80840   0.88380   1.00000   0.01659
OB   0.06890   0.96640   0.92620   1.00000   0.01089
HA   0.89800   0.79900   0.42700   1.00000 ?
HB   0.13200   0.96200   0.92400   1.00000 ?

Relationship of Carpholite Group to other SpeciesHide

Carpholite Group Members:

Carpholite	Mn²⁺Al₂(Si₂O₆)(OH)₄	Orth. mmm (2/m 2/m 2/m) : Ccca
Ferrocarpholite	Fe²⁺Al₂Si₂O₆(OH)₄	Orth. mmm (2/m 2/m 2/m) : Ccca
Magnesiocarpholite	MgAl₂Si₂O₆(OH)₄	Orth. mmm (2/m 2/m 2/m) : Ccca
Potassiccarpholite	K(Mn²⁺,Li)₂Al₄Si₄O₁₂(OH,F)₈	Orth. mmm (2/m 2/m 2/m) : Ccca
Vanadiocarpholite	Mn²⁺V³⁺Al(Si₂O₆)(OH)₄	Orth. mmm (2/m 2/m 2/m) : Ccca

Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Carpholite GroupHide

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References for Carpholite GroupHide

Reference List:

Viswanathan, Krishnamoorthy (1981) The crystal structure of a Mg-rich carpholite. American Mineralogist, 66 (9-10) 1080-1085

Löffler, H. K. & Schwab, M. (1981): Die Karpholite der Wippraer Einheit des Unterharzes. Zeitschrift für Geologische Wissenschaften 9, 519-539 (in German).

Ferraris, G., Ivaldi, G., and Goffé, B. (1992): Structural study of a magnesian ferrocarpholite: are carpholites monoclinic? Neues Jahrbuch für Mineralogie, Monatshefte, 337-347.

Bertoldi, C. (2006) Calorimetric data for naturally occurring magnesiocarpholite and ferrocarpholite. American Mineralogist, 91 (2) 441-445 doi:10.2138/am.2006.1958

Basso, R., Carbone, C. (2010) Relationships between crystal data and crystal chemistry of carpholite-group minerals. Periodico di Mineralogia, 79, 91-98.

Localities for Carpholite GroupHide

Showing 106 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

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Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Australia
Western Australia Meekatharra Shire Gabanintha Quinns gold area ⓘ Franklin prospect	[Magnesiocarpholite] Hassan (2017)

Belgium
Wallonia Liège ⓘ Lienne valley	[Carpholite] de Koninck (1878) +4 other references
ⓘ Stoumont	[Carpholite] Hatert et al. (2002)
ⓘ Bierleux	[Carpholite] Michel Blondieau collection
ⓘ Rahier	[Carpholite] Hatert et al. (2002)
ⓘ Meuville	[Carpholite] Handbook of Mineralogy. +5 other references
ⓘ Rouge Thier	[Carpholite] Michel Blondiau collection +2 other references
ⓘ Xhierfomont	[Carpholite] Hatert et al. (2002)
Luxembourg Manhay ⓘ Dochamps	[Carpholite] Corin (1931) +1 other reference
ⓘ Malempré	[Carpholite] Corin (1931) +1 other reference
Vielsalm Bihain ⓘ Ottré	[Carpholite] Corin (1931) +2 other references

Brazil
Minas Gerais Ouro Preto Antônio Pereira ⓘ Conta História mine ?	[Carpholite] Cabral et al. (2002)

China
Jilin Yanbian Chaoxianzu Yanji City ⓘ Kaishantun ophiolite suite	[Carpholite] Wu Hanquan et al. (2003)
Qinghai Haibei Tibetan Autonomous Prefecture ⓘ Qilian Co.	[Carpholite] Song et al. (2007)

Czech Republic
Karlovy Vary Region Sokolov District ⓘ Horní Slavkov	[Carpholite] Werner (1817)
ⓘ Krásno	[Ferrocarpholite] Jeff Weissman / Photographic Guide to ...
ⓘ Huber stock (Huber shaft; Hub stock)	[Carpholite] Petr Pauliš (2000)

France
Auvergne-Rhône-Alpes Rhône Villefranche-sur-Saône Les Ardillats ⓘ La Verrière (Montchonay) ?	[Carpholite] Favreau G. et al. (1996)
Savoie ⓘ Vanoise	[Magnesiocarpholite] Goffé et al. (1973) +1 other reference
New Caledonia Northern Province Poum ⓘ Ao Mine	[Ferrocarpholite] Briggs (1978)
Provence-Alpes-Côte d'Azur Alpes-de-Haute-Provence Barcelonnette Saint-Paul-sur-Ubaye ⓘ Maljasset	[Magnesiocarpholite] Goffé (2023)

Germany
Saxony-Anhalt Mansfeld-Südharz Mansfeld ⓘ Biesenrode	[Carpholite] Siemroth (1990)
ⓘ Sengelbach valley	[Carpholite] Siemroth (1990)
ⓘ Wippra Metamorphic Zone	[Carpholite, Ferrocarpholite, Magnesiocarpholite] Theye et al. (1993)

Greece
ⓘ Crete	[Carpholite] Theye et al. (1992)
Chania Kissamos ⓘ Nopigia	[Magnesiocarpholite] Theye et al. (1992)
ⓘ Sfinari	[Magnesiocarpholite] Viswanathan et al. (1979)
Heraklion Viannos ⓘ Viannos	[Magnesiocarpholite] Theye et al. (1992)
Lasithi Sitia ⓘ Roussa Ekklissia-Arniko area	[Ferrocarpholite] Theye et al. (1992)
ⓘ Sykia area	[Ferrocarpholite] Theye et al. (1992)
Rethymno Agios Vasileios ⓘ Kerames	[Ferrocarpholite] Theye et al. (1992)
Mylopotamos ⓘ Sisses	[Magnesiocarpholite] Viswanathan et al. (1979)
Peloponnese Laconia Sparta ⓘ Arna	[Magnesiocarpholite] Theye et al. (1992)
ⓘ Soubouro	[Magnesiocarpholite] Theye et al. (1992)

Indonesia
Central Sulawesi Province Morowali Regency ⓘ Peleroe	[Ferrocarpholite] de Roever (1951)
ⓘ Tamondjengi	[Ferrocarpholite] de Roever (1951)
ⓘ Tomata (Tomate)	[Ferrocarpholite] de Roever (1951)

Italy
Aosta Valley La Thuile ⓘ Breuil Valley	[Ferrocarpholite] Goffé et al. (1997)
Calabria Cosenza Province Mormanno ⓘ Mormanno ferrocarpholite outcrops	[Ferrocarpholite] Busato et al. (1983)
Liguria Genoa ⓘ Busalla	[Magnesiocarpholite] Marchesini (1994) +1 other reference
Ne ⓘ Cassagna Mine	[Carpholite] XRD analysis at Euratom of Ispra (Varese)
ⓘ Molinello Mine	[Carpholite, Vanadiocarpholite] 415. +1 other reference
Reppia ⓘ Gambatesa Mine	[Carpholite, Vanadiocarpholite] Pipino (1984)
Statale ⓘ Scrava Mine (Statale Mine)	[Vanadiocarpholite] Castellaro et al. (2023)
Savona Province Bormida ⓘ Bormida di Pàllare River (Ponte di Romana)	[Ferrocarpholite] Bracco (2003)
ⓘ Osiglia	[Magnesiocarpholite] Bracco (2003)
Piedmont Cuneo Province ⓘ Acceglio	[Magnesiocarpholite] Piccoli et al. (2007)
ⓘ Colle Ciarbonet	[Ferrocarpholite] Scaini et al. (1976) +3 other references
Castelmagno ⓘ Esischie Pass	[Magnesiocarpholite] Piccoli (2002)
Demonte Arma Valley ⓘ San Giacomo streamlet head	[Ferrocarpholite] Goffé (2002)
Marmora ⓘ Marmora Valley	[Ferrocarpholite] Goffé (2002)
Montaldo di Mondovì ⓘ Corsaglia	[Magnesiocarpholite] Piccoli et al. (2007)
Priola Casario ⓘ Casario - Bric delle Piombere	[Magnesiocarpholite] Rossetti P. (2008)
Robilante ⓘ Cialancie Valley	[Magnesiocarpholite] Goffé (2002) +1 other reference
ⓘ Sant'Anna	[Magnesiocarpholite] Goffé (2002) +1 other reference
Metropolitan City of Turin Sestriere ⓘ Fraiteve Massif	[Ferrocarpholite] Goffé (2023)
Verbano-Cusio-Ossola Province ⓘ Isorno Valley	[Ferrocarpholite] Piccoli et al. (2007)
Ornavasso ⓘ ~~Ornavasso pegmatite~~	[Carpholite] Mattioli (1987)
Tuscany Grosseto Province Isola del Giglio ⓘ Giglio Island	[Ferrocarpholite] Jolivet L. et al. (1998) +2 other references
Franco Promontory ⓘ Cala dei Mugni (Mugni beach)	[Ferrocarpholite] Reinhardt J. (2004)
ⓘ Monte Argentario	[Ferrocarpholite, Magnesiocarpholite] Eur. J. Mineral.
ⓘ Forte Stella	[Ferrocarpholite, Magnesiocarpholite] Theye et al. (1997) +2 other references
ⓘ Punta di Torre Ciana area	[Ferrocarpholite, Magnesiocarpholite] Theye et al. (1997) +2 other references
ⓘ Monte Leoni	[Ferrocarpholite, Magnesiocarpholite] Fuchs +3 other references

Japan
Hyogo Prefecture Taka District ⓘ Fukuzumi mine	[Carpholite] Yoshimura & Aoki (1966)

Kazakhstan
Karaganda Region Karkaraly ⓘ Kent Massif	[Carpholite] Evseev (1995) +1 other reference

Oman
Muscat Governorate Muscat Area ⓘ Ruwi	[Ferrocarpholite] Handbook of Mineralogy (http://www.handbookofmineralogy.org/pdfs/ferrocarpholite.pdf)
ⓘ Wadi Aday	[Magnesiocarpholite] e-rocks.com (n.d.)

Poland
Lower Silesian Voivodeship Wrocław County Gmina Kobierzyce ⓘ Pustków Wilczkowski	[Carpholite] Ł. Kruszewski PXRD & pXRF data (paper in preparation)

Romania
Suceava County Iacobeni ⓘ Arșița mine	[Carpholite] minerals-of-the-carpathians.eu (2008)
Tolovanu ⓘ Tolovanu (Tolovan) Mn deposit	[Carpholite] Hîrtopanu (1997) +1 other reference

Spain
Andalusia Almería Tabernas ⓘ Schist outcrops	[Ferrocarpholite, Magnesiocarpholite] Goffé +3 other references
Granada ⓘ Lanjarón	[Magnesiocarpholite] Eur. J. Mineral.
Monachil Trevenque ⓘ Cerro del Trevenque	[Ferrocarpholite] Eur. J. Mineral.
Otívar ⓘ Alcázar	[Carpholite] Goffe et al. (1989)
Salobreña occurrence ⓘ Metapelite outcrops	[Ferrocarpholite, Magnesiocarpholite] Goffé +3 other references
ⓘ Schist outcrops	[Ferrocarpholite, Magnesiocarpholite] Azañón et al. (1997)
Canary Islands Santa Cruz de Tenerife Province Tenerife ⓘ ~~Los Blanquitos~~	[Carpholite] Dill et al. (2023)
Catalonia Tarragona Baix Camp Vilanova d'Escornalbou Escornalbou Castle ⓘ Barite mine ?	[Carpholite] Aufschluss 1975 (6)

Switzerland
Grisons Engiadina Bassa/Val Müstair Region Valsot Martina ⓘ Tea Alp	[Carpholite, Magnesiocarpholite] Stalder et al. (1998)

UK
England Cornwall Calstock Gunnislake Clitters United Mines ⓘ ~~Hingston Down Consols~~	[Carpholite] Kingsbury et al. (1957) +1 other reference
St Stephen-in-Brannel Foxhole ⓘ ~~Stenna Gwyn Mine (Stennagwyn Mine)~~	[Carpholite] [Specimen in the Natural History Museum +1 other reference
Stokeclimsland Callington Kit Hill United Mines (incl. Kit Hill Great Consols) ⓘ ~~Kit Hill Mine (Kit Hill Consols)~~	[Carpholite] Kingsbury et al. (1957) +1 other reference
Cumbria Eden Mungrisdale ⓘ ~~Carrock Mine~~	[Carpholite] Kingsbury et al. (1957) +3 other references
ⓘ ~~Emerson vein~~	[Carpholite] Kingsbury et al. (1957) +1 other reference
ⓘ ~~Grains Gill~~	[Carpholite] [Specimen in the Natural History Museum +1 other reference

USA
Alaska Yukon-Koyukuk Census Area Koyukuk Mining District ⓘ Dietrich Quarry	[Magnesiocarpholite] Nikischer (2019)
Idaho Boise County ⓘ Ardeth Lake	[Potassiccarpholite] W.C. van Laer: the Sawtooth batholith
ⓘ Centerville Mining District	[Carpholite] Ream (2004)
ⓘ Glens Peak	[Potassiccarpholite] William C. van Laer collection
Elmore County Glens Peak area ⓘ Glens Peak prospects	[Carpholite, Potassiccarpholite] van Laer
ⓘ Sawtooth Batholith	[Carpholite, Potassiccarpholite] Rocks & Min. 70:246 +3 other references

Quick NavTop About Carpholite Group Unique Identifiers Crystal Structure Relationships Other Information Internet Links References Localities Locality List

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