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Cossaite
A valid IMA mineral species
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About Cossaite
Formula:
(Mg0.5,◻)Al6(SO4)6(HSO4)F6 · 36H2O
The earlier proposed formula NaAl6(SO4)6(SO3F)F6.36H2O is false (see Demartin et al., 2011).
Colour:
Colourless
Lustre:
Vitreous
Specific Gravity:
2.08
Crystal System:
Trigonal
Name:
Named by Francesco Demartin, Carlo Maria Gramaccioli, Italo Campostrini, and C. Castellano in 2011 in honor of Alfonso Cossa (3 November 1833, Milan, Italy - 23 October 1902, Turin, Italy), for his work on the minerals and rocks of Vulcano.
[http://www.platinummetalsreview.com/pdf/pmr-v34-i4-215-221.pdf]
[http://www.platinummetalsreview.com/pdf/pmr-v34-i4-215-221.pdf]
This page provides mineralogical data about Cossaite.
Unique Identifiers
Mindat ID:
39568
Long-form identifier:
mindat:1:1:39568:5
Similar Names
| Cocite | A rock subtype | |
| Coesite | A valid IMA mineral species - grandfathered | SiO2 |
| Cossaite (of Piolti?) | A variety of Paragonite | NaAl2(AlSi3O10)(OH)2 |
| Cösite | A synonym of 'Oösite' | |
| Goyzaite | A synonym of Goyazite | |
| Jossaite | ||
| Kassite | A valid IMA mineral species | CaTi2O4(OH)2 |
IMA Classification of Cossaite
Classification of Cossaite
7.DE.
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Css | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Cossaite
Vitreous
Transparency:
Translucent
Colour:
Colourless
Streak:
White
Tenacity:
Brittle
Fracture:
Irregular/Uneven
Density:
2.08(1) g/cm3 (Measured) 2.075 g/cm3 (Calculated)
Chemistry of Cossaite
Mindat Formula:
(Mg0.5,◻)Al6(SO4)6(HSO4)F6 · 36H2O
The earlier proposed formula NaAl6(SO4)6(SO3F)F6.36H2O is false (see Demartin et al., 2011).
The earlier proposed formula NaAl6(SO4)6(SO3F)F6.36H2O is false (see Demartin et al., 2011).
Element Weights:
Crystallography of Cossaite
Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 22.023(2) Å, c = 9.237(2) Å
Ratio:
a:c = 1 : 0.419
Unit Cell V:
3,879.85 ų (Calculated from Unit Cell)
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0018525 | Cossaite | Demartin F, Gramaccioli C M, Campostrini I, Castellano C (2011) Cossaite, (Mg0.5,_)Al6(SO4)6(HSO4)F6*36H2O, a new mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy Mineralogical Magazine 75 2847-2855 | 2011 | La Fossa crater, Vulcano, Aeolian Islands, Italy | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 10.997 Å | (50) |
| 4.584 Å | (25) |
| 4.152 Å | (100) |
| 3.873 Å | (70) |
| 2.770 Å | (20) |
| 2.345 Å | (17) |
| 2.166 Å | (20) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 45a : [Sulfates, arsenates, selenates, antimonates] | |
| 45b : [Other oxidized fumarolic minerals] | |
| 47a : [Near-surface hydration of prior minerals] |
Type Occurrence of Cossaite
General Appearance of Type Material:
Stout prismatic crystals up to 0.1 mm in size, which are terminated by rhombohedral faces.
Place of Conservation of Type Material:
Reference Collection of the Dipartimento di Chimica Strutturale e Stereochimica Inorganica at the Universita degli Studi di Milano, Italy (catalogue No. 2009-1).
Geological Setting of Type Material:
Cossaite was found on altered pyroclastic breccia at the F5AT medium-temperature fumarole (T ~350ºC), which is located at the rim of La Fossa crater.
Synonyms of Cossaite
Other Language Names for Cossaite
Common Associates
Associations Based on Photo Data:
| 2 photos of Cossaite associated with Thermessaite | K2AlF3(SO4) |
Related Minerals - Strunz-mindat Grouping
| 7.DE. | Magnesioalterite | Mg2Fe3+4(SO4)4(C2O4)2(OH)4 · 17H2O |
| 7.DE. | Fabritzite | Zn9(SO4)2(OH)12Cl2 · 6H2O |
| 7.DE. | Downsite | K2(MoO3)3(SO4) · 4H2O |
| 7.DE. | Liangjunite | K2(Mo2O5)(SO4)2 · 3H2O |
| 7.DE.05 | Mangazeite | Al2(SO4)(OH)4 · 3H2O |
| 7.DE.10 | 'UKI-1975-(SO:AlCu)' | (Cu, Al, SO4, H2O) |
| 7.DE.10 | Carbonatecyanotrichite | Cu4Al2(CO3,SO4)(OH)12 · 2H2O |
| 7.DE.10 | Cyanotrichite | Cu4Al2(SO4)(OH)12 · 2H2O |
| 7.DE.15 | Schwertmannite | Fe3+16(OH,SO4)12-13O16 · 10-12H2O |
| 7.DE.20 | Tlalocite | Cu10Zn6(Te6+O4)2(Te4+O3)(OH)25Cl · 27H2O |
| 7.DE.25 | Utahite | MgCu4Zn2Te6+3O14(OH)4 · 6H2O |
| 7.DE.35 | Coquandite | Sb6+xO8+x(SO4)(OH)x(H2O)1- x (x = 0.3) |
| 7.DE.40 | Osakaite | Zn4(SO4)(OH)6 · 5H2O |
| 7.DE.42 | Alterite | Zn2Fe3+4(SO4)4(C2O4)2(OH)4 · 17H2O |
| 7.DE.45 | Barrotite | Cu9Al(HSiO4)2[(SO4)(HAsO4)0.5](OH)12 · 8H2O |
| 7.DE.45 | Wilcoxite | MgAl(SO4)2F · 17H2O |
| 7.DE.47 | Tiberiobardiite | {Cu9Al[SiO3(OH)]2(OH)12(H2O)6}(SO4)1.5 · 10H2O |
| 7.DE.50 | Bouškaite | (MoO2)2O(SO3OH)2(H2O)4 |
| 7.DE.50 | Stanleyite | (V4+O)(SO4) · 6H2O |
| 7.DE.57 | 'Khangalasite' | Fe(SO4)(OH) · 2H2O |
| 7.DE.60 | Hydrobasaluminite | Al4(SO4)(OH)10 · 12-36H2O |
| 7.DE.62 | Volaschioite | Fe4(SO4)O2(OH)6 · 2H2O |
| 7.DE.65 | Zaherite | Al12(SO4)5(OH)26 · 20H2O |
| 7.DE.75 | Camérolaite | Cu6Al3(OH)18(H2O)2[Sb(OH)6](SO4) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Cossaite
mindat.org URL:
https://www.mindat.org/min-39568.html
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References for Cossaite
Reference List:
Demartin, F., Gramaccioli, C. M., Campostrini, I., Castellano, C. (2011) Cossaite, (Mg0.5,☐)Al6(SO4)6(HSO4)F6·36H2O, a new mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy. Mineralogical Magazine, 75 (6) 2847-2855 doi:10.1180/minmag.2011.075.6.2847
Localities for Cossaite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Italy (TL) | |
| Campostrini et al. (2010) +1 other reference |
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The
La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy