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Cerchiaraite-(Fe)

A valid IMA mineral species

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Cerchiaraite-(Fe)

Cerchiara Mine, Borghetto di Vara, La Spezia Province, Liguria, Italy

Cerchiaraite-(Fe), etc.

Esquire No. 7 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

Cerchiaraite-(Fe), etc.

Esquire No. 7 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

Cerchiaraite-(Fe)

Cerchiara Mine, Borghetto di Vara, La Spezia Province, Liguria, Italy

Cerchiaraite-(Fe), etc.

Esquire No. 7 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

Cerchiaraite-(Fe), etc.

Esquire No. 7 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

Cerchiaraite-(Fe)

Cerchiara Mine, Borghetto di Vara, La Spezia Province, Liguria, Italy

Cerchiaraite-(Fe), etc.

Esquire No. 7 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

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About Cerchiaraite-(Fe)Hide

Formula:

Ba₄Fe³⁺₄O₃(OH)₃(Si₄O₁₂)[Si₂O₃(OH)₄]Cl

Colour:

tan to brown; blue to bluish-green

Lustre:

Vitreous

Hardness:

4½

Specific Gravity:

3.710 (Calculated)

Crystal System:

Tetragonal

Member of:

Cerchiaraite Group

Name:

to address the mineral relation with "cerchiaraite" (now cerchiaraite-(Mn))

Co-Type Localities:

ⓘ Cerchiara Mine, Borghetto di Vara, La Spezia Province, Liguria, Italy
ⓘ Esquire No. 7 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA
ⓘ Esquire No. 8 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

The Fe analogue of cerchiaraite-(Mn) (ex-cerchiaraite) and cerchiaraite-(Al). Chemically similar to fencooperite, and somewhat to traskite and hyttsjöite.

The structure details (1) corner-sharing silicate tetrahedra, forming 4-membered rings; (2) the rings share corners with an edge-sharing chain of Fe³⁺O₆ octahedra || c; (3) the rings alternate with Cl sites alternates along c; (4) large channels in the framework host Ba around
their peripheries, statistically distributed Si₂O₃(OH)₄ dimers, and Cl atoms.

Unique IdentifiersHide

Mindat ID:

42784

Long-form identifier:

mindat:1:1:42784:1

Similar NamesHide

Cerchiaraite-(Al)	A valid IMA mineral species	Ba₄Al₄O₃(OH)₃(Si₄O₁₂)[Si₂O₃(OH)₄]Cl
Cerchiaraite-(Mn)	A valid IMA mineral species	Ba₄Mn₄³⁺(Si₄O₁₂)O₂(OH)₄Cl₂[Si₂O₃(OH)₄]
Cherchiaraite	A synonym of Cerchiaraite Group

IMA Classification of Cerchiaraite-(Fe)Hide

IMA status:

Approved

IMA Formula:

Ba₄Fe³⁺₄(Si₄O₁₂)O₂(OH)₄Cl₂[Si₂O₃(OH)₄]

Approval year:

2012

First published:

2013

Type description reference:

Kampf, A. R., Roberts, A. C., Venance, K. E., Carbone, C., Belmonte, D., Dunning, G. E., Walstrom, R. E. (2013) Cerchiaraite-(Fe) and cerchiaraite-(Al), two new barium cyclosilicate chlorides from Italy and California, USA. Mineralogical Magazine, 77 (1) 69-80 doi:10.1180/minmag.2013.077.1.07

Classification of Cerchiaraite-(Fe)Hide

Strunz-mindat (2026):

9.CF.25

9 : SILICATES (Germanates)
C : Cyclosilicates
F : [Si₄O₁₂]₈- 4-membered single rings, with insular complex anions

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference for Standard
Ccr-Fe	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Cerchiaraite-(Fe)Hide

Lustre:

Vitreous

Transparency:

Transparent

Colour:

Tan to brown; blue to bluish-green

Comment:

tan/brown: Cerchiara; blue/bluish-green: California

Streak:

Colorless to tan (Cerchiara), pale green-blue (California)

Hardness:

4½ on Mohs scale

Comment:

ca. 4.5

Tenacity:

Brittle

Cleavage:

None Observed

Fracture:

Irregular/Uneven

Density:

3.710 g/cm³ (Calculated)

Comment:

couldn't be measured due to fibrous habit

Optical Data of Cerchiaraite-(Fe)Hide

Type:

Uniaxial (+)

RI values:

n_ω = 1.741(2) n_ε = 1.768(2)

Max. Birefringence:

δ = 0.027
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Thickness: 30 µm Order divisions

Rotation:

Surface Relief:

Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.

Focus:

In focus

Interference Figure:

This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Thickness: 30 µm

Pleochroism:

Weak

Comments:

colorless (O), yellow (E), O < E

Chemistry of Cerchiaraite-(Fe)Hide

Mindat Formula:

Ba₄Fe³⁺₄O₃(OH)₃(Si₄O₁₂)[Si₂O₃(OH)₄]Cl

Element Weights:

Element	% weight
Ba	39.699 %
O	28.907 %
Fe	16.144 %
Si	12.179 %
Cl	2.562 %
H	0.510 %

Calculated from ideal end-member formula.

Elements listed:

Ba, Cl, Fe, H, O, Si - search for minerals with similar chemistry

Common Impurities:

Ti,Al

Crystallography of Cerchiaraite-(Fe)Hide

Crystal System:

Tetragonal

Class (H-M):

4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal

Space Group:

I4/mmm

Cell Parameters:

a = 14.3354(19) Å, c = 6.0151(8) Å

Ratio:

a:c = 1 : 0.42

Unit Cell V:

1230.6 Å³

Crystal StructureHide

Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4

View
CIF File Best | x | y | z | a | b | c

Rotation
Stop | Start

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0019795	Cerchiaraite-(Fe)	Kampf A R, Roberts A C, Venance K E, Carbone C, Belmonte D, Dunning G E, Walstrom R E (2013) Cerchiaraite-(Fe) and cerchiaraite-(Al), two new barium cyclosilicate chlorides from Italy and California, USA Mineralogical Magazine 77 69-80		2013	Esquire No. 8 claim, Big Creek, Fresno County, California, USA	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Cerchiaraite-(Fe)'
loop_
_publ_author_name
'Kampf A R'
'Roberts A C'
'Venance K E'
'Carbone C'
'Belmonte D'
'Dunning G E'
'Walstrom R E'
_journal_name_full 'Mineralogical Magazine'
_journal_volume 77 
_journal_year 2013
_journal_page_first 69
_journal_page_last 80
_publ_section_title
;
 Cerchiaraite-(Fe) and cerchiaraite-(Al), two new barium cyclosilicate chlorides
 from Italy and California, USA
;
_database_code_amcsd 0019795
_chemical_compound_source 'Esquire No. 8 claim, Big Creek, Fresno County, California, USA'
_chemical_formula_sum 'Ba4 (Fe2.384 Al1.616) Si6.04 Cl2.68 O25.12 H8.16'
_cell_length_a 14.3554
_cell_length_b 14.3554
_cell_length_c 6.0065
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1237.805
_exptl_crystal_density_diffrn      3.758
_symmetry_space_group_name_H-M 'I 4/m m m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  '-y,-x,z'
  '1/2-y,1/2-x,1/2+z'
  'y,x,-z'
  '1/2+y,1/2+x,1/2-z'
  'y,-x,-z'
  '1/2+y,1/2-x,1/2-z'
  '-y,x,z'
  '1/2-y,1/2+x,1/2+z'
  'x,-y,z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,-z'
  '1/2-x,1/2+y,1/2-z'
  'x,y,-z'
  '1/2+x,1/2+y,1/2-z'
  '-x,-y,z'
  '1/2-x,1/2-y,1/2+z'
  'y,x,z'
  '1/2+y,1/2+x,1/2+z'
  '-y,-x,-z'
  '1/2-y,1/2-x,1/2-z'
  '-y,x,-z'
  '1/2-y,1/2+x,1/2-z'
  'y,-x,z'
  '1/2+y,1/2-x,1/2+z'
  '-x,y,z'
  '1/2-x,1/2+y,1/2+z'
  'x,-y,-z'
  '1/2+x,1/2-y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,1/2-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ba   0.21637   0.00000   0.00000   1.00000   0.02750
FeM   0.25000   0.25000   0.25000   0.59600   0.01900
AlM   0.25000   0.25000   0.25000   0.40400   0.01900
Si1   0.38855   0.38855   0.00000   1.00000   0.01650
Si2   0.41830   0.11210   0.00000   0.25500   0.02700
Cl1   0.00000   0.00000   0.00000   1.00000   0.02790
Cl2   0.50000   0.13880   0.11800   0.21000   0.08200
O1   0.34600   0.34600   0.22680   1.00000   0.02180
O2   0.17660   0.30760   0.00000   0.50000   0.02930
O-H2   0.17660   0.30760   0.00000   0.50000   0.02930
O3   0.36860   0.50000   0.00000   1.00000   0.02560
O4   0.39400   0.00000   0.00000   0.24000   0.03600
O-H5   0.50000   0.12600   0.24700   0.52000   0.13900
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Ba 0.03490 0.02220 0.02540 0.00000 0.00000 0.00000
FeM 0.02070 0.02070 0.01560 -0.00750 0.00010 0.00010
AlM 0.02070 0.02070 0.01560 -0.00750 0.00010 0.00010
Si1 0.01640 0.01640 0.01670 -0.00100 0.00000 0.00000
Si2 0.04100 0.01900 0.02300 0.00600 0.00000 0.00000
Cl1 0.02400 0.02400 0.03600 0.00000 0.00000 0.00000
Cl2 0.03700 0.07300 0.14000 0.00000 0.00000 -0.04200
O1 0.02540 0.02540 0.01500 -0.00500 0.00180 0.00180
O2 0.02600 0.03900 0.02400 -0.00900 0.00000 0.00000
O-H2 0.02600 0.03900 0.02400 -0.00900 0.00000 0.00000
O3 0.03700 0.01100 0.02800 0.00000 0.00000 0.00000
O4 0.04000 0.01600 0.05000 0.00000 0.00000 0.00000
O-H5 0.22000 0.10000 0.09000 0.00000 0.00000 -0.07400

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
4.403 Å	(26)
3.327 Å	(48)
3.016 Å	(70)
2.595 Å	(100)
2.258 Å	(29)
1.812 Å	(39)
1.411 Å	(43)
1.298 Å	(29)

Locality:

Esquire No. 8 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

Reference:

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)

Geological Setting:

quartz-sanbomite vein assemblages resulting from fluid interaction along the margin of the vein (Esquire #7 and #8 claims)

Type Occurrence of Cerchiaraite-(Fe)Hide

Co-Type Localities:

General Appearance of Type Material:

thin prisms and matted fibers (Italy); irregular prisms in subparallel crystal aggregates, generally less than 1 mm across (California, USA)

Place of Conservation of Type Material:

Natural History Museum of Los Angeles County, Los Angeles, California, USA, catalogue numbers 63515, 63516, 63517 and 63518

Geological Setting of Type Material:

small fractures and veinlets within metacherts of a Jurassic ophiolitic sequence; genesis: re-equilibration of the ophiolitic sequences during tectonometamorphic overprinting, aged ca. 80 Ma, in prehnite-pumpellyite facies conditions (2–3kB, 250–300^{o^C)}

Associated Minerals at Type Locality:

Aegirine	Calcite	Feldspar Group	Hematite	Norrishite
Quartz	'Schefferite'

Reference:

Synonyms of Cerchiaraite-(Fe)Hide

IMA2012-012

Other Language Names for Cerchiaraite-(Fe)Hide

Dutch:Cerchiaraiet-(Fe)

German:Cerchiarait-(Fe)

Relationship of Cerchiaraite-(Fe) to other SpeciesHide

Member of:

Cerchiaraite Group

Other Members of Cerchiaraite Group:

Cerchiaraite-(Al)	Ba₄Al₄O₃(OH)₃(Si₄O₁₂)[Si₂O₃(OH)₄]Cl	Tet. 4/mmm(4/m2/m2/m) : I4/mmm
Cerchiaraite-(Mn)	Ba₄Mn³⁺₄(Si₄O₁₂)O₂(OH)₄Cl₂[Si₂O₃(OH)₄]	Tet. 4/mmm(4/m2/m2/m) : I4/mmm

Common AssociatesHide

Associations Based on Photo Data:

13 photos of Cerchiaraite-(Fe) associated with Sanbornite	BaSi₂O₅
13 photos of Cerchiaraite-(Fe) associated with Quartz	SiO₂
7 photos of Cerchiaraite-(Fe) associated with Pyrrhotite	Fe_1-xS
7 photos of Cerchiaraite-(Fe) associated with Titantaramellite	Ba₄(Ti,Fe³⁺,Fe²⁺,Mg)₄(B₂Si₈O₂₇)O₂Cl_x
5 photos of Cerchiaraite-(Fe) associated with Gillespite	BaFe²⁺Si₄O₁₀
4 photos of Cerchiaraite-(Fe) associated with 'Tobermorite-11Å'
4 photos of Cerchiaraite-(Fe) associated with Hedenbergite	CaFe²⁺Si₂O₆
4 photos of Cerchiaraite-(Fe) associated with Muirite	Ba₁₀(Ca₂Mn²⁺Ti)[Si₈O₂₄]O₂Cl₁₀
4 photos of Cerchiaraite-(Fe) associated with Pellyite	Ba₂CaFe²⁺₂Si₆O₁₇
3 photos of Cerchiaraite-(Fe) associated with Calcite	CaCO₃

Related Minerals - Strunz-mindat Grouping Hide

9.CF.	Bobmeyerite	Pb₄(Al₃Cu)(Si₄O₁₂)(S_0.5Si_0.5O₄)(OH)₇Cl(H₂O)₃	Orth. mmm(2/m2/m2/m) : Pnnm
9.CF.05	Ashburtonite	Pb₄Cu₄(Si₄O₁₂)(HCO₃)₄(OH)₃Cl · H₂O	Tet.
9.CF.10	Kainosite-(Y)	Ca₂Y₂(SiO₃)₄(CO₃) · H₂O	Orth. mmm(2/m2/m2/m)
9.CF.15	Clinophosinaite	Na₁₂(Ca,Sr)₄(Si₄O₁₂)(PO₄)₄	Mon. 2/m : P2/b
9.CF.15	Phosinaite-(Ce)	Na₁₃Ca₂(Ce,La,Th,Nd,Pr)(Si₄O₁₂)(PO₄)₄	Orth. 222 : P2₁2₁2
9.CF.20	Strakhovite	NaBa₃Mn²⁺₂Mn³⁺₂Si₆O₁₉(OH)₃	Orth. mmm(2/m2/m2/m)
9.CF.25	Cerchiaraite-(Al)	Ba₄Al₄O₃(OH)₃(Si₄O₁₂)[Si₂O₃(OH)₄]Cl	Tet. 4/mmm(4/m2/m2/m) : I4/mmm
9.CF.25	Cerchiaraite-(Mn)	Ba₄Mn³⁺₄(Si₄O₁₂)O₂(OH)₄Cl₂[Si₂O₃(OH)₄]	Tet. 4/mmm(4/m2/m2/m) : I4/mmm

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Cerchiaraite-(Fe)Hide

mindat.org URL:

https://www.mindat.org/min-42784.html
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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from D. Joyce minerals

References for Cerchiaraite-(Fe)Hide

Reference List:

Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2012) New minerals and nomenclature modifications approved in 2012. CNMNC Newsletter No 13. Mineralogical Magazine, 76 (3) 807-817 doi:10.1180/minmag.2012.076.3.26

(2016) Cerchiaraite-(Fe). Handbook of Mineralogy. Mineralogical Society of America

Localities for Cerchiaraite-(Fe)Hide

Showing 9 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Canada
Yukon Watson Lake mining district Itsi Mountain Wilson Lake ⓘ Gun claim	McNeil et al. (2013) +1 other reference
ⓘ Trench 1	Kampf et al. (2014)

Italy (TL)
Liguria La Spezia Province Borghetto di Vara ⓘ Cerchiara Mine (TL)	Williams et al. (2012) +1 other reference

Mexico
Baja California Tres Pozos ⓘ Madrelena Mine	Frank K. Mazdab collection (petrography + EPMA characterized) +2 other references

Sweden
Örebro County Askersund Zinkgruvan ⓘ Zinkgruvan mine	Cámara et al. (2021)

USA (TL)
California Fresno County Big Creek-Rush Creek Mining District Big Creek ⓘ Esquire No. 7 claim (TL)	Walstrom (n.d.) +2 other references
ⓘ Esquire No. 8 claim (TL)	Walstrom (n.d.) +2 other references
Mariposa County East Belt Clearing House Mining District Clearing House Trumbull Peak ⓘ Trumbull Peak Ba-silicate deposit	Kampf et al. (2013)
Tulare County Dumtah ⓘ Van Gordon Creek Prospect	Walstrom (n.d.)

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Cerchiaraite-(Fe)

About Cerchiaraite-(Fe)Hide

Unique IdentifiersHide

Similar NamesHide

IMA Classification of Cerchiaraite-(Fe)Hide

Classification of Cerchiaraite-(Fe)Hide

Mineral SymbolsHide

Physical Properties of Cerchiaraite-(Fe)Hide

Optical Data of Cerchiaraite-(Fe)Hide

Chemistry of Cerchiaraite-(Fe)Hide

Crystallography of Cerchiaraite-(Fe)Hide

Crystal StructureHide

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of Cerchiaraite-(Fe)Hide

Synonyms of Cerchiaraite-(Fe)Hide

Other Language Names for Cerchiaraite-(Fe)Hide

Relationship of Cerchiaraite-(Fe) to other SpeciesHide

Common AssociatesHide

Related Minerals - Strunz-mindat GroupingHide

Other InformationHide

Internet Links for Cerchiaraite-(Fe)Hide

References for Cerchiaraite-(Fe)Hide

Localities for Cerchiaraite-(Fe)Hide

Locality ListHide

Related Minerals - Strunz-mindat Grouping Hide