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Peterandresenite

A valid IMA mineral species
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About PeterandreseniteHide

04415330017272472279520.jpg
Any gaidonnayites to be seen?
Formula:
Mn4Nb6O19 · 14H2O
Colour:
Orange
Lustre:
Vitreous, Resinous
Hardness:
2 - 2½
Specific Gravity:
3.10
Crystal System:
Monoclinic
Name:
Named after the Norwegian mineral collector Peter Andresen, who first found the mineral.
The first naturally occurring hexaniobate. It has a novel structure consisting of six edge-sharing NbO6 octahedra forming a super octahedron known as a Lindqvist ion. Three such complex ions are interconnected by one Mn2+-centred octahedron to form a two-dimensional layer perpendicular to c. The second Mn2+-centred octahedron bridges the Lindqvist ion, protrudes into the adjacent layer along c, and takes part in the formation of 3D structure via hydrogen bonds.

Somewhat chemically and visually similar are the heteropolyniobates menezesite and aspedamite. Also chemically similar to hansesmarkite.


Unique IdentifiersHide

Mindat ID:
43796
Long-form identifier:
mindat:1:1:43796:3

IMA Classification of PeterandreseniteHide

Approved
IMA Formula:
Mn2+4Nb5+6O19(H2O)12·2H2O
Approval year:
2012

Classification of PeterandreseniteHide

7.GB.60

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
G : Molybdates, Wolframates and Niobates
B : With additional anions and/or H2O

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
PanIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PeterandreseniteHide

Vitreous, Resinous
Transparency:
Transparent, Translucent
Colour:
Orange
Streak:
Pale orange
Hardness:
2 - 2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
3.10(1) g/cm3 (Measured)    3.05 g/cm3 (Calculated)

Optical Data of PeterandreseniteHide

Type:
Biaxial (-)
RI values:
nα = 1.760(5) nβ = 1.795(5) nγ = 1.800(5)
2V:
Measured: 43° (2), Calculated: 40°
Max. Birefringence:
δ = 0.040
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
Strong (r>v)
Pleochroism:
Visible
Comments:
X (colourless) < Z (pale orange)<

Chemistry of PeterandreseniteHide

Mindat Formula:
Mn4Nb6O19 · 14H2O
Element Weights:
Element% weight
Nb41.806 %
O39.597 %
Mn16.481 %
H2.117 %

Calculated from ideal end-member formula.
Nb
O
Mn
H

Crystallography of PeterandreseniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 15.329(1) Å, b = 9.4121(5) Å, c = 11.2832(9) Å
β = 118.650(4)°
Ratio:
a:b:c = 1.629 : 1 : 1.199
Unit Cell V:
1428.6 ų
Z:
2

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.898 Å(82)
7.710 Å(42)
7.469 Å(39)
7.103 Å(63)
3.410 Å(30)
3.301 Å(20)
2.926 Å(100)
2.029 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]

Type Occurrence of PeterandreseniteHide

General Appearance of Type Material:
It occurs as equidimensional, transparent to translucent orange crystals up to 1 mm with a pale orange streak and a vitreous to resinous lustre.
Place of Conservation of Type Material:
In the collections of the Natural History Museum, University of Oslo, Oslo, Norway, catalogue numbers 43490 and 43492, and the Mineral Sciences Department, Natural History Museum of Los Angeles County, Los Angeles, California, USA, catalogue number 64008.
Geological Setting of Type Material:
The mineral was found on fracture surfaces and in tiny vugs in the centre of a miaskitic pegmatite dike.

Synonyms of PeterandreseniteHide

Other Language Names for PeterandreseniteHide

Common AssociatesHide

Associations Based on Photo Data:
15 photos of Peterandresenite associated with Gonnardite(Na,Ca)2(Si,Al)5O10 · 3H2O
10 photos of Peterandresenite associated with NatroliteNa2Al2Si3O10 · 2H2O
4 photos of Peterandresenite associated with ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2O
2 photos of Peterandresenite associated with HansesmarkiteCa2Mn2Nb6O19 · 20H2O
1 photo of Peterandresenite associated with FayaliteFe2+2(SiO4)

Related Minerals - Strunz-mindat GroupingHide

7.GB.Stunorthropite(NH4)4[Mo2O6(MoO4)2]Tric. 1 : P1
7.GB.HartkoppeiteCa4Mn2+Mo6+6As5+4O32(OH)2(H2O)14 · 5H2OTric. 1 : P1
7.GB.WangpuiteK3(PO4)(Mo12O36)Iso. m3m(4/m32/m) : Pn3m
7.GB.AlexearliteHg3S2(MoO4)Orth. mmm(2/m2/m2/m) : Pnma
7.GB.OotanniteTh4+2W6+4O16 · 5H2OMon. 2/m : P21/b
7.GB.NatromolybditeNa2MoO4 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
7.GB.Marsaalamite-(Y)Y(MoO4)(OH)Mon. 2/m : P21/b
7.GB.05LindgreniteCu3(MoO4)2(OH)2Mon. 2/m : P21/m
7.GB.10SzenicsiteCu3(MoO4)(OH)4Orth. mmm(2/m2/m2/m) : Pnnm
7.GB.15'UM1999-38-WO:CrV'(V, Cr, W, O, H) [V:Cr:W ratio about 2:1:3]
7.GB.15HueniteCu4(MoO4)3(OH)2Trig. 3m : P31c
7.GB.15CuprotungstiteCu2(WO4)(OH)2Tet. 422 : P41212
7.GB.20Phyllotungstite(H2O,M)x(W,Fe)(O,OH)3 · yH2O (M = Ca, Cs, Pb or K)Hex. 6/mmm(6/m2/m2/m) : P63/mmc
7.GB.25RankachiteCa0.5(V4+,V5+)(W6+,Fe3+)2O8(OH) · 2H2OMon. 2/m : P21/m
7.GB.30FerrimolybditeFe2(MoO4)3 · nH2OOrth. mmm(2/m2/m2/m) : Pmmn
7.GB.35MpororoiteWAlO3(OH)3 · 2(H2O)Tric.
7.GB.35AnthoiniteAlWO3(OH)3Tric. 1
7.GB.40Obradovicite-KCu[K2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3]Orth. mmm(2/m2/m2/m) : Pmna
7.GB.45Paramendozavilite[KAl4(H2O)30][Mo12P6Fe3+6O60(OH)13]Mon.
7.GB.45Mendozavilite-NaFe[Na2(H2O)15Fe3+(H2O)6][Mo8P2Fe3+3O35(OH)2]Mon. 2/m : B2/m
7.GB.45Obradovicite-NaCuNa2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] Orth. mmm(2/m2/m2/m) : Pmna
7.GB.45Obradovicite-NaNa[Na2(H2O)16Na(H2O)6][Mo8As2Fe3+3O33(OH)4] Orth.
7.GB.50Tancaite-(Ce)FeCe(MoO4)3 · 3H2O Trig. 3 : R3
7.GB.50Mendozavilite-NaCu[Na2(H2O)15Cu(H2O)6][Mo8P2Fe3+3O34(OH)3] Mon. 2/m : B2/m
7.GB.50Mendozavilite-KCa[K2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O34(OH)3] Mon. 2/m : B2/m
7.GB.60HansesmarkiteCa2Mn2Nb6O19 · 20H2OTric. 1 : P1
7.GB.60MelcheriteBa2Na2Mg[Nb6O19] · 6H2OTrig. 3 : R3
7.GB.65IchnusaiteTh(MoO4)2 · 3H2OMon. 2/m : P21/b
7.GB.70MarkascheriteCu3(MoO4)(OH)4Mon. 2/m : P21/m
7.GB.75NuragheiteTh(MoO4)2 · H2OMon. 2/m : P21/b
7.GB.80OphiriteCa2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46H2OTric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PeterandreseniteHide

References for PeterandreseniteHide

Localities for PeterandreseniteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Namibia
 
  • Erongo Region
    • Dâures Constituency
      • Brandberg Area
        • Karlowa Pegmatite Swarm
von Bezing et al. (2016)
Norway (TL)
 
  • Vestfold
    • Larvik Commune
      • Tvedalen
        • Tuften
Williams et al. (2013) +1 other reference
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
        • Arico
Dill et al. (2023)
 
and/or  
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