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Fluorkyuygenite

A valid IMA mineral species
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02894890017272472261515.jpg
Fluorkyuygenite

Hatrurim Basin, Tamar Regional Council, Beersheba Subdistrict, Southern District, Israel
02894890017272472261515.jpg
Fluorkyuygenite

Hatrurim Basin, Tamar Regional Council, Beersheba Subdistrict, Southern District, Israel
02894890017272472261515.jpg
Fluorkyuygenite

Hatrurim Basin, Tamar Regional Council, Beersheba Subdistrict, Southern District, Israel
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About FluorkyuygeniteHide

Formula:
Ca12Al14O32[(H2O)4F2]
Colour:
Colourless
Lustre:
Vitreous
Hardness:
5 - 5½
Crystal System:
Isometric
Name:
Named for being the fluorine analogue of chlorkyuygenite.
The F analogue of chlorkyuygenite and H2O analogue of fluormayenite.

Microporous tetrahedral framework structure, with water molecules occupying about 2/3 of the structural cages.

The mayenite supergroup species (in general, coded as C12A7, or C12A7e-) show unique electrochemichal properties, with some anions in their structure (e.g., oxygen anions) migrating thorough the structure. As such, the mayenites behave as metals even though they are very non-metal in terms of general chemistry. Transitions seen in their structure may be related to superconducting. The mayenites represent a group of chemicals known as "salts of an electron", also known as electrides (e.g., Weber et al., 2021).


Unique IdentifiersHide

Mindat ID:
43913
Long-form identifier:
mindat:1:1:43913:8

IMA Classification of FluorkyuygeniteHide

Classification of FluorkyuygeniteHide

Strunz-mindat (2026):
4.CC.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
FkyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FluorkyuygeniteHide

Lustre:
Vitreous
Transparency:
Transparent
Colour:
Colourless
Comment:
In places with greenish or yellowish tint
Streak:
White
Hardness:
5 - 5½ on Mohs scale
Hardness:
VHN50=712 kg/mm2 - Vickers

Optical Data of FluorkyuygeniteHide

Type:
Isotropic
RI values:
n = 1.610(3)
Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus

Chemistry of FluorkyuygeniteHide

Mindat Formula:
Ca12Al14O32[(H2O)4F2]
Element Weights:
Element% weight
O38.899 %
Ca32.480 %
Al25.511 %
F2.566 %
H0.545 %

Calculated from ideal end-member formula.
O
Ca
Al
F
H
Elements listed:
Al, Ca, F, H, O - search for minerals with similar chemistry
Common Impurities:
Fe(III),Si,OH

Crystallography of FluorkyuygeniteHide

Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
I43d
Cell Parameters:
a = 11.966(2) Å
Unit Cell V:
1,713.35 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
51 : Pyrometamorphic minerals (see also #54 and #56)<0.36

Type Occurrence of FluorkyuygeniteHide

Synonyms of FluorkyuygeniteHide

Other Language Names for FluorkyuygeniteHide

Relationship of Fluorkyuygenite to other SpeciesHide

Member of:
Mayenite Supergroup
Other Members of Mayenite Supergroup:
ChlorkyuygeniteCa12Al14O32[(H2O)4Cl2]Iso. 43m : I43d
ChlormayeniteCa12Al14O32[◻4Cl2]Iso. 43m : I43d
FluormayeniteCa12Al14O32F2Iso. 43m : I43d

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Fluorkyuygenite associated with ShulamititeCa3TiFe3+AlO8
5 photos of Fluorkyuygenite associated with OldhamiteCaS
5 photos of Fluorkyuygenite associated with LarniteCa2SiO4
1 photo of Fluorkyuygenite associated with AravaiteBa2Ca18(SiO4)6(PO4)3(CO3)F3O
1 photo of Fluorkyuygenite associated with SpurriteCa5(SiO4)2(CO3)
1 photo of Fluorkyuygenite associated with AriegilatiteBaCa12(SiO4)4(PO4)2F2O

Related Minerals - Strunz-mindat GroupingHide

4.CC.BernwooditeCa5TiAl2Si2O14Mon. 2/m : B2/b
4.CC.XuiteCa3Fe3+2[(AlO3(OH)]3Iso. m3m(4/m32/m)
4.CC.Yttriaite-(Y)Y2O3Iso. m3(2/m3)
4.CC.AllendeiteSc4Zr3O12Trig. 3 : R3
4.CC.ChlorkyuygeniteCa12Al14O32[(H2O)4Cl2]Iso. 43m : I43d
4.CC.OboniobiteMg4Nb2O9Trig. 3m(32/m) : P3c1
4.CC.BotuobinskiteSrFe2+Mg2(Cr3+6Ti4+12)[O36(OH)2]Trig. 3 : R3
4.CC.MirnyiteSrZr4+Mg2(Cr3+6Ti4+12)O38Trig. 3 : R3
4.CC.Haitaite-(La)LaU4+Fe3+2(Ti13Fe2+4Fe3+)O38Trig. 3 : R3
4.CC.ShagamiteKFe11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.BitikleiteCa3(Sb5+Sn4+)[AlO4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.Anzaite-(Ce)Ce3+ 4Fe2+Ti6O18 (OH)2Mon. 2/m : B2/m
4.CC.Heamanite-(Ce)(K0.5Ce0.5)TiO3Iso. m3m(4/m32/m)
4.CC.Priscillagrewite-(Y)(Ca2Y)Zr2(AlO4)3Iso.
4.CC.StranditePb3Mn3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) : P63/mcm
4.CC.SaranovskiteSrCaFe2+2(Cr4Ti2)Ti12O38Trig. 3 : R3
4.CC.05ChrombismiteBi3+16Cr6+O27Iso. m3m(4/m32/m)
4.CC.10FreudenbergiteNa2(Ti,Fe)8O16Mon.
4.CC.10FluormayeniteCa12Al14O32F2Iso. 43m : I43d
4.CC.15GrossiteCaAl4O7Mon. 2/m : B2/b
4.CC.17GoldschmidtiteKNbO3Iso. m3m(4/m32/m) : Pm3m
4.CC.20'Unnamed (HBU UK-4)'NaFe2+Zn2(Ti,Fe3+,Nb)6Ti12O38Trig. 3 : R3
4.CC.20ChlormayeniteCa12Al14O32[◻4Cl2]Iso. 43m : I43d
4.CC.20PaseroitePbMn2+(Mn2+,Fe3+)2(V5+,Ti,◻)18O38 Trig. 3 : R3
4.CC.20Mianningite(◻,Pb,Ce,Na)(U4+,Mn,U6+)Fe3+2 (Ti,Fe3+)18O38Trig. 3 : R3
4.CC.20'UM1987-03-O:FePbTiU'~(U,Pb)(Ti,Fe3+,Fe2+,Mn)21O38Trig. 3 : R3
4.CC.22GoreriteCaAlFe3+11O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.22KahlenbergiteKAl11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.25HopmanniteBa2(Ti5Fe)O13Mon. 2/m : B2/m
4.CC.25NixoniteNa2Ti6O13Mon. 2/m : B2/m
4.CC.25YafsoaniteCa3Te6+2(ZnO4)3Iso. m3m(4/m32/m) : Ia3d
4.CC.30LatrappiteCa2NbFe3+O6Orth. mmm(2/m2/m2/m) : Pnma
4.CC.30NatroniobiteNaNbO3Mon.
4.CC.30PerovskiteCaTiO3Orth. mmm(2/m2/m2/m) : Pnma
4.CC.30LueshiteNaNbO3Orth. mmm(2/m2/m2/m)
4.CC.30BariolakargiiteBaZrO3Iso. m3m(4/m32/m) : Pm3m
4.CC.30BarioperovskiteBaTiO3Orth. mm2 : Amm2
4.CC.30MegawiteCaSnO3Orth. mmm(2/m2/m2/m) : Pban
4.CC.30LakargiiteCa(Zr,Sn,Ti)O3Orth. mmm(2/m2/m2/m) : Pnma
4.CC.32UsturiteCa3(Sb5+Zr)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.32ElbrusiteCa3(U6+0.5Zr1.5)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.32MonteneveiteCa3Sb5+2(Fe3+2Fe2+)O12Iso. m3m(4/m32/m) : Ia3d
4.CC.32DzhuluiteCa3(Sb5+Sn4+)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.35TausoniteSrTiO3Iso. 43m
4.CC.35Loparite(Na,REE)2Ti2O6Iso. m3m(4/m32/m)
4.CC.35Panguite(Ti,Al,Sc,Mg,Zr,Ca)1.8O3Orth. mmm(2/m2/m2/m) : Pbca
4.CC.35Isolueshite(Na,La)NbO3Iso. m3m(4/m32/m) : Pm3m
4.CC.35MacedonitePbTiO3Tet. 4/mmm(4/m2/m2/m) : P4/nmm
4.CC.37PauloabibiteNaNbO3Trig. 3 : R3
4.CC.40LandauiteNaMnZn2(Ti,Fe)6Ti12O38Trig. 3 : R3
4.CC.40Mathiasite(Mg,Cr,Fe,Ca,K)2(Ti,Zr,Cr,Fe)5O12Trig. 3 : R3
4.CC.40SenaitePb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38Trig. 3 : R3
4.CC.40Gramaccioliite-(Y)(Pb,Sr)(Y,Mn)Fe3+2(Ti,Fe3+)18O38Trig. 3 : R3
4.CC.40Lindsleyite(Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38Trig.
4.CC.40CrichtoniteSr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38Trig. 3 : R3
4.CC.40Loveringite(Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38Trig. 3 : R3
4.CC.40Cleusonite(Pb,Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38Trig. 3 : R3
4.CC.40Davidite-(Ce)Ce(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig. 3 : R3
4.CC.40Davidite-(La)La(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig. 3 : R3
4.CC.40'Davidite-(Y)'(La,Ce,Na,Ca,Pb)(Y,Fe2+,◻)(Fe2+,Mn2+)2(Ti,Fe3+,Nb,Zr)18O38 (hypothetical)Trig.
4.CC.40'Uhligite'Ca3(Ti,Al,Zr)9O20 ?Iso.
4.CC.40Dessauite-(Y)(Sr,Pb)(Y,U)(Ti,Fe3+)20O38Trig. 3 : R3
4.CC.45DiaoyudaoiteNaAl11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45YimengiteK(Cr,Ti,Fe,Mg)12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45NežilovitePbZn2Mn4+2Fe3+8O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HawthorneiteBaMgTi3Cr4Fe2+2Fe3+2O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45Mizraite-(Ce)Ce(Al11Mg)O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HaggertyiteBaFe2+4Fe3+2Ti5MgO19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45LindqvistitePb2Mn2+Fe16O27Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HiboniteCaAl12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45Kangite(Sc,Ti,Al,Zr,Mg,Ca,◻)2O3 Iso. m3(2/m3)
4.CC.45ChihuahuaiteFeAl12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45BarioferriteBaFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45PlumboferritePb[Fe3+10.67Mn2+0.33Pb]O18.33Trig. 32 : P312
4.CC.45BatiferriteBaTi2Fe3+8Fe2+2O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45MagnetoplumbitePbFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.50JeppeiteK2Ti6O13Mon. 2/m : B2/m
4.CC.55ZenzénitePb3Fe3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) : P63/mcm
4.CC.60'Mengxianminite (of Huang et al.)'(Ca,Na)3(Fe,Mn)2Mg2(Sn,Zn)5Al8O29

Fluorescence of FluorkyuygeniteHide

In UV light:
Does not show fluorescence

Other InformationHide

Notes:
Raman bands: 2600–3500 cm−1 (ν H2O); other bands as for fluormayenite
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FluorkyuygeniteHide

References for FluorkyuygeniteHide

Localities for FluorkyuygeniteHide

Showing 7 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Israel (TL)
 
  • Southern District
    • Beersheba Subdistrict
      • Tamar Regional Council
Galuskin et al. (2015)
Galuskin et al. (2018) +1 other reference
          • Wadi Zohar
Galuskin +1 other reference
Jordan
 
  • Amman Governorate
    • Transjordan Plateau
      • Daba-Siwaqa complex
Galuskina et al. (2019)
Middle East
 
Vapnik et al. (2014)
Palestine
 
  • West Bank
    • Bethlehem Governorate
Galuskina et al. (2019)
Russia
 
  • Sverdlovsk Oblast
    • Sysertsky District
      • Dvurechensk
Ерохин Ю.В.
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