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Mathesiusite

A valid IMA mineral species
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About MathesiusiteHide

01147830017271951835010.jpg
Johannes Mathesius
Formula:
K5(UO2)4(SO4)4(VO5) · 4H2O
Colour:
Yellowish green
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
4.02 (Calculated)
Crystal System:
Tetragonal
Name:
Named in honor of Johannes Mathesius (24 June 1504, Rochlitz, Saxony – 7 October 1565, St. Joachimsthal, Bohemia), a Lutheran parson and humanist. He was also an "amateur mineralogist" and a friend of Georg Agricola, "the father of mineralogy". They both lived in St. Joachimsthal (now Jáchymov).
This page provides mineralogical data about Mathesiusite.


Unique IdentifiersHide

Mindat ID:
43918
Long-form identifier:
mindat:1:1:43918:3

IMA Classification of MathesiusiteHide

Approved
IMA Formula:
K5(U6+O2)4(S6+O4)4(V5+O5)·4H2O
Approval year:
2013
First published:
2014

Classification of MathesiusiteHide

7.DG.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MheIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MathesiusiteHide

Vitreous
Colour:
Yellowish green
Comment:
Colorless in fragments
Streak:
Greenish white
Hardness:
Comment:
~2
Tenacity:
Brittle
Cleavage:
Perfect
Perfect cleavage on {110} and weaker on {001}
Fracture:
Irregular/Uneven
Density:
4.02 g/cm3 (Calculated)

Optical Data of MathesiusiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.634(3) nε = 1.597(3)
Max. Birefringence:
δ = 0.037
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of MathesiusiteHide

Mindat Formula:
K5(UO2)4(SO4)4(VO5) · 4H2O
Element Weights:
Element% weight
U51.111 %
O28.343 %
K10.494 %
S6.885 %
V2.735 %
H0.433 %

Calculated from ideal end-member formula.
U
O
K
S
V
H

Crystallography of MathesiusiteHide

Crystal System:
Tetragonal
Class (H-M):
4/m - Dipyramidal
Space Group:
P4/n
Setting:
P4/n
Cell Parameters:
a = 14.9704(10) Å, c = 6.8170(5) Å
Ratio:
a:c = 1 : 0.455
Unit Cell V:
1527.78 ų
Z:
2
Morphology:
Acicular aggregates of prismatic crystals up to ~200 μm long and several micrometers thick.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.599 Å(100)
6.907 Å(41)
6.270 Å(5)
5.295 Å(32)
4.760 Å(2)
4.739 Å(12)
3.351 Å(2)
3.216 Å(2)
Comments:
From Type Description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47b : [Sulfates and sulfites]
47e : [Vanadates, chromates, manganates]
47f : [Uranyl (U⁶⁺) minerals]
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of MathesiusiteHide

General Appearance of Type Material:
A secondary mineral formed during post-mining processes, found on fractures of gangue.
Place of Conservation of Type Material:
Type material is deposited in the collections of the Department of Mineralogy and Petrology of the National Museum in Prague, Prague, Czech Republic, catalogue number P1P 7/2013
Associated Minerals at Type Locality:

Synonyms of MathesiusiteHide

Other Language Names for MathesiusiteHide

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Mathesiusite associated with 'Asphaltite'
4 photos of Mathesiusite associated with 'Sandstone'
2 photos of Mathesiusite associated with Ammoniomathesiusite(NH4)5(UO2)4(SO4)4(VO5) · 4H2O
2 photos of Mathesiusite associated with AdolfpateraiteK(UO2)(SO4)(OH)(H2O)
1 photo of Mathesiusite associated with NatrozippeiteNa5(UO2)8(SO4)4O5(OH)3 · 12H2O
1 photo of Mathesiusite associated with HalotrichiteFe2+Al2(SO4)4 · 22H2O
1 photo of Mathesiusite associated with GypsumCaSO4 · 2H2O

Related Minerals - Strunz-mindat GroupingHide

7.DG.05DarapskiteNa3(SO4)(NO3) · H2OMon. 2/m : P21/m
7.DG.10Clinoungemachite(Na, K, Fe, SO4)Mon. 2/m
7.DG.10HumberstoniteNa7K3Mg2(SO4)6(NO3)2 · 6H2OTrig. 3 : R3
7.DG.10UngemachiteK3Na8Fe(SO4)6(NO3)2 · 6H2OTrig. 3 : R3
7.DG.15ChiyokoiteCa3Si(CO3)[B(OH)4]O (OH)5 · 12H2OHex. 6 : P63
7.DG.15KottenheimiteCa 3Si(SO4)2(OH)6 · 12H2O Hex. 6/m : P63/m
7.DG.15HielscheriteCa3Si(SO4)(SO3)(OH)6 · 11H2OHex. 6 : P63
7.DG.15JouravskiteCa3Mn4+(SO4)(CO3)(OH)6 · 12H2OHex. 6 : P63
7.DG.15ThaumasiteCa3(SO4)[Si(OH)6](CO3) · 12H2OHex. 6 : P63
7.DG.15BentoriteCa6Cr2(SO4)3(OH)12 · 26H2OTrig. 3m : P31c
7.DG.15CarraraiteCa3(SO4)[Ge(OH)6](CO3) · 12H2OHex.
7.DG.15EttringiteCa6Al2(SO4)3(OH)12 · 26H2OTrig. 3m : P31c
7.DG.15BiruniteCa18(SiO3)8.5(CO3)8.5SO4 · 15H2O(?)
7.DG.15SiwaqaiteCa6Al2(CrO4)3(OH)12 · 26H2OTrig. 3m : P31c
7.DG.15BuryatiteCa3(Si,Fe3+,Al)(SO4)B(OH)4(OH,O)6 · 12H2OTrig. 3m : P31c
7.DG.15CharlesiteCa6(Al,Si)2(SO4)2[B(OH)4](OH,O)12 · 26H2OTrig. 3m : P31c
7.DG.15TatarinoviteCa3Al(SO4)[B(OH)4](OH)6 · 12H2OHex. 6 : P63
7.DG.15ImayoshiiteCa3Al(CO3)[B(OH)4](OH)6 · 12H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
7.DG.15SturmaniteCa6Fe3+2(SO4)2.5[B(OH)4](OH)12 · 25H2OTrig. 3m : P31c
7.DG.20RapidcreekiteCa2(SO4)(CO3) · 4H2OOrth. mmm(2/m2/m2/m) : Pbcn
7.DG.25TatarskiteCa6Mg2(SO4)2(CO3)2(OH)4Cl4 · 7H2OOrth.
7.DG.30NakauriiteCu8(SO4)4(CO3)(OH)6 · 48H2OOrth.
7.DG.35Chessexite(Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2OOrth.
7.DG.40FuenzalidaiteK6(Na,K)4Na6Mg10(SO4)12(IO3)12 · 12H2OTrig. 3m(32/m) : P3c1
7.DG.40CarlosruiziteK6(Na,K)4Na6Mg10(SeO4)12(IO3)12 · 12H2OTrig. 3m(32/m) : P3c1
7.DG.45'Chelyabinskite'(Ca,Mg)3(SO4,CO3)2[Si(OH)6] · 9H2O (?)Orth.
7.DG.55Ramazzoite[Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36]Iso. 43m : P43m
7.DG.60WitzkeiteNa4K4Ca(NO3)2(SO4)4 · 2H2O Mon. 2/m : B2/b

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 51.1106% 12,777,650 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 10.4942% 3,253 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity: –

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Fluorescence of MathesiusiteHide

Strong yellowish green under long and short wave UV

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MathesiusiteHide

References for MathesiusiteHide

Localities for MathesiusiteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Czech Republic (TL)
 
  • Karlovy Vary Region
    • Karlovy Vary District
      • Jáchymov
        • Svornost Mine
Williams et al. (2013) +1 other reference
Hungary
 
  • Baranya County
    • Pécs District
      • Kővágótöttös
Zsombor Eva
USA
 
  • Utah
    • Emery County
      • Temple Mountain Mining District
Analyzed by Joy Desor.
Collected by and in the collection of ...
 
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