Ferrostalderite
A valid IMA mineral species
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About Ferrostalderite
Formula:
CuFe2TlAs2S6
Colour:
Black
Lustre:
Metallic
Specific Gravity:
4.691 (Calculated)
Crystal System:
Tetragonal
Member of:
Name:
For its relation to stalderite and its iron content. Stalderite was named after Hans-Anton Stalder (1925-2011), curator, Natural History Museum, Bern and professor of mineralogy, University of Bern (Switzerland).
Type Locality:
The iron analogue of stalderite. Chemically similar to ferrovoronstovite.
Structure and crystallochemistry details (Biagioni et al., 2016): Cu present in the M1 and Zn in M2 site; the framework is built of (Cu,Fe)-centered tetrahedra and has channels (parallel to [001]) where dissimetric TlS6 and (As,Sb)S3 polyhedra reside.
Structure and crystallochemistry details (Biagioni et al., 2016): Cu present in the M1 and Zn in M2 site; the framework is built of (Cu,Fe)-centered tetrahedra and has channels (parallel to [001]) where dissimetric TlS6 and (As,Sb)S3 polyhedra reside.
Unique Identifiers
Mindat ID:
46561
Long-form identifier:
mindat:1:1:46561:0
IMA Classification of Ferrostalderite
Approved
IMA Formula:
Cu1+Fe2+2Tl1+As3+2S2-6
Approval year:
2014
First published:
2016
Type description reference:
Biagioni, Cristian, Bindi, Luca, Nestola, Fabrizio, Cannon, Ralph, Roth, Philippe, Raber, Thomas (2016) Ferrostalderite, CuFe2TlAs2S6, a new mineral from Lengenbach, Switzerland: occurrence, crystal structure, and emphasis on the role of iron in sulfosalts. Mineralogical Magazine, 80 (1) 175-186 doi:10.1180/minmag.2015.079.7.10
Classification of Ferrostalderite
2.GA.40
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
A : Neso-sulfarsenites, etc. without additional S
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
A : Neso-sulfarsenites, etc. without additional S
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Fstd | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Ferrostalderite
Metallic
Transparency:
Opaque
Colour:
Black
Streak:
Black
Tenacity:
Brittle
Fracture:
Irregular/Uneven
Density:
4.691 g/cm3 (Calculated)
Optical Data of Ferrostalderite
Anisotropism:
Weakly anisotropic, with yellowish to bluish rotation tints
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 471nm | 24.2% | 25.4% |
| 548nm | 23.7% | 24.7% |
| 586nm | 22.9% | 23.8% |
| 652nm | 21.0% | 22.0% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 25.4%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Dark gray
Internal Reflections:
Very weak
Chemistry of Ferrostalderite
Mindat Formula:
CuFe2TlAs2S6
Element Weights:
Crystallography of Ferrostalderite
Crystal System:
Tetragonal
Class (H-M):
42m - Scalenohedral
Space Group:
I42m
Cell Parameters:
a = 9.8786(5) Å, c = 10.8489(8) Å
Ratio:
a:c = 1 : 1.098
Unit Cell V:
1058.71 Ã
Âģ
Z:
4
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0020619 | Ferrostalderite | Biagioni C, Bindi L, Nestola F, Cannon R, Roth P, Raber T (2016) Ferrostalderite, CuFe2TlAs2S6, a new mineral from Lengenbach, Switzerland: occurrence, crystal structure, and emphasis on the role of iron in sulfosalts Mineralogical Magazine 80 175-186 | 2016 | Lengenbach quarry, Binn Valley, Wallis, Switzerland | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.092 Ã | (70) |
| 3.493 Ã | (23) |
| 3.396 Ã | (35) |
| 3.124 Ã | (17) |
| 2.937 Ã | (100) |
| 2.656 Ã | (19) |
| 2.470 Ã | (19) |
| 2.435 Ã | (33) |
Reference:
Biagioni, Cristian, Bindi, Luca, Nestola, Fabrizio, Cannon, Ralph, Roth, Philippe, Raber, Thomas (2016) Ferrostalderite, CuFe2TlAs2S6, a new mineral from Lengenbach, Switzerland: occurrence, crystal structure, and emphasis on the role of iron in sulfosalts. Mineralogical Magazine, 80 (1) 175-186 doi:10.1180/minmag.2015.079.7.10
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Ferrostalderite
General Appearance of Type Material:
Crystals, equant to prismatic, up to 50 Âĩm.
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collection of the Museo di Storia Naturale, Università di Firenze, Via La Pira 4, Firenze, Italy, catalogue number 3148/I.
Associated Minerals at Type Locality:
Reference:
Biagioni, Cristian, Bindi, Luca, Nestola, Fabrizio, Cannon, Ralph, Roth, Philippe, Raber, Thomas (2016) Ferrostalderite, CuFe2TlAs2S6, a new mineral from Lengenbach, Switzerland: occurrence, crystal structure, and emphasis on the role of iron in sulfosalts. Mineralogical Magazine, 80 (1) 175-186 doi:10.1180/minmag.2015.079.7.10
Synonyms of Ferrostalderite
Other Language Names for Ferrostalderite
Dutch:Ferrostalderiet
German:Ferrostalderit
Relationship of Ferrostalderite to other Species
Member of:
Other Members of Routhierite Group:
| Arsiccioite | AgHg2Tl(As,Sb)2S6 | Tet. 42m : I42m |
| Ralphcannonite | AgZn2TlAs2S6 | Tet. 42m : I42m |
| Routhierite | Tl(Cu,Ag)(Hg,Zn)2(As,Sb)2S6 | Tet. 42m : I42m |
| Stalderite | Tl(Cu,Ag)(Zn,Fe,Hg)2(As,Sb)2S6 | Tet. 42m : I42m |
| 'Unnamed (Ag-Fe endmember of Routhierite Group)' | AgFe2TlAs2S6 |
Related Minerals - Strunz-mindat Grouping
| 2.GA. | Pyradoketosite | Ag3SbS3 |
| 2.GA. | Arsiccioite | AgHg2Tl(As,Sb)2S6 |
| 2.GA. | Eckerite | Ag2CuAsS3 |
| 2.GA.05 | Proustite | Ag3AsS3 |
| 2.GA.05 | Pyrargyrite | Ag3SbS3 |
| 2.GA.10 | Xanthoconite | Ag3AsS3 |
| 2.GA.10 | Pyrostilpnite | Ag3SbS3 |
| 2.GA.15 | Samsonite | Ag4MnSb2S6 |
| 2.GA.20 | BytÃzite | Cu3SbSe3 |
| 2.GA.20 | Skinnerite | Cu3SbS3 |
| 2.GA.20 | Wittichenite | Cu3BiS3 |
| 2.GA.25 | Lapieite | NiCuSbS3 |
| 2.GA.25 | Lisiguangite | PtCuBiS3 |
| 2.GA.25 | Malyshevite | PdCuBiS3 |
| 2.GA.25 | RoterbÃĪrite | PdBiCuSe3 |
| 2.GA.25 | MÞckeite | NiCu(Bi,Sb)S3 |
| 2.GA.30 | Aktashite | Cu6Hg3As4S12 |
| 2.GA.30 | Nowackiite | Cu6Zn3As4S12 |
| 2.GA.30 | Zhengminghuaite | Cu6Fe3As4S12 |
| 2.GA.30 | Gruzdevite | Cu6Hg3Sb4S12 |
| 2.GA.35 | Laffittite | AgHgAsS3 |
| 2.GA.40 | 'Unnamed (Ag-Fe endmember of Routhierite Group)' | AgFe2TlAs2S6 |
| 2.GA.40 | Routhierite | Tl(Cu,Ag)(Hg,Zn)2(As,Sb)2S6 |
| 2.GA.40 | Stalderite | Tl(Cu,Ag)(Zn,Fe,Hg)2(As,Sb)2S6 |
| 2.GA.40 | Ralphcannonite | AgZn2TlAs2S6 |
| 2.GA.45 | Erniggliite | Tl2SnAs2S6 |
| 2.GA.50 | Cerromojonite | CuPbBiSe3 |
| 2.GA.50 | Seligmannite | PbCuAsS3 |
| 2.GA.50 | SouÄekite | CuPbBi(S,Se)3 |
| 2.GA.50 | 'Unnamed (Pb-Cu-Bi Selenide)' | PbCuBiSe3 |
| 2.GA.50 | Bournonite | PbCuSbS3 |
| 2.GA.55 | EldragÃģnite | Cu6BiSe4(Se2) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Ferrostalderite
mindat.org URL:
https://www.mindat.org/min-46561.html
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References for Ferrostalderite
Reference List:
HÃĨlenius, U., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2015, CNMNC Newsletter No 24. Mineralogical Magazine, 79 (2) 247-251 doi:10.1180/minmag.2015.079.2.03
Biagioni, Cristian, Bindi, Luca, Nestola, Fabrizio, Cannon, Ralph, Roth, Philippe, Raber, Thomas (2016) Ferrostalderite, CuFe2TlAs2S6, a new mineral from Lengenbach, Switzerland: occurrence, crystal structure, and emphasis on the role of iron in sulfosalts. Mineralogical Magazine, 80 (1) 175-186 doi:10.1180/minmag.2015.079.7.10
Localities for Ferrostalderite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Switzerland (TL) | |
| HÃĨlenius et al. (2015) +1 other reference |
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The
Lengenbach Quarry, FÃĪld, Binn, Goms, Valais, Switzerland