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Barronite

A valid IMA mineral species
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About BarroniteHide

Formula:
(â—ŧ0.5Ba0.5)(UO2)2Si5O12(OH) · 2H2O
Empirical formula is:
(□1.369Ba0.345K0.165Ca0.086Pb0.024Fe0.011)ÎĢ2.000(U0.996O2)2Si4.989O12(OH)·2H2O.
Colour:
pale yellow
Hardness:
1 - 2
Crystal System:
Monoclinic
Name:
Named after the exploration geologist Keith Barron (born 1962), the winner of the Thayer Lindsay award (2008) for his discovery of the famous Au-Ag deposit of Fruta del Norte in Ecuador, owner of the second world's largest sapphire mine of Rock Creek, Montana, USA, and actively exploring gold, copper, base metal and uranium in Switzerland, Argentina, Ecuador, Guyana and France.
Structurally related to weeksite.


Unique IdentifiersHide

Mindat ID:
471488
Long-form identifier:
mindat:1:1:471488:6

Similar NamesHide

BarneiteA rock subtype
BarrotiteA valid IMA mineral speciesCu9Al(HSiO4)2[(SO4)(HAsO4)0.5](OH)12 · 8H2O
BartoniteA valid IMA mineral speciesK6Fe20S26S
BauranoiteA valid IMA mineral speciesBa(UO2)2(OH)6 · 1-2H2O
BerauniteA valid IMA mineral species - grandfatheredFe63+(PO4)4O(OH)4 · 6H2O
BiruniteA valid IMA mineral species - grandfathered - questionableCa18(SiO3)8.5(CO3)8.5SO4 · 15H2O(?)
BorniteA valid IMA mineral species - grandfatheredCu5FeS4
Bornite (of Pinkerton)A rock subtype
BrauniteA valid IMA mineral species - grandfatheredMn2+Mn63+(SiO4)O8
BrianiteA valid IMA mineral speciesNa2CaMg(PO4)2
GarroniteA synonym of Garronite Subgroup

IMA Classification of BarroniteHide

Classification of BarroniteHide

9.AK.30

9 : SILICATES (Germanates)
A : Nesosilicates
K : Uranyl neso- and polysilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BarrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BarroniteHide

Colour:
Pale yellow
Comment:
some of the crystals have a brown-orange tint, caused by Fe-Si-gels.
Streak:
Colourless to pale yellow
Hardness:
1 - 2 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
distinct cleavage on {100}
Fracture:
Irregular/Uneven

Optical Data of BarroniteHide

Type:
Biaxial (+)
RI values:
nα = 1.599(2) nβ = 1.607(2) nγ = 1.617(3)
2V:
Measured: 86°
Birefringence:
s biaxial (+), with Îą = 1.599(2), Îē = 1.607(2), Îģ = 1.617(3);
2V (meas.) = 86°. Optical orientation is X = b, Y ˄ a ~3° in the obtuse angle Îē. Dispersion is
distinct r>v. Pleochroism is distinct in hues of pale-yellow X
Max. Birefringence:
δ = 0.018
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 Âĩm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
distinct
Pleochroism:
Visible
Comments:
hues of pale-yellow X

Chemistry of BarroniteHide

Mindat Formula:
(â—ŧ0.5Ba0.5)(UO2)2Si5O12(OH) · 2H2O

Empirical formula is:
(□1.369Ba0.345K0.165Ca0.086Pb0.024Fe0.011)ÎĢ2.000(U0.996O2)2Si4.989O12(OH)·2H2O.
Element Weights:
Element% weight
U47.885 %
O30.577 %
Si14.125 %
Ba6.907 %
H0.507 %

Calculated from ideal end-member formula.
U
O
Si
Ba
H
Common Impurities:
K

Crystallography of BarroniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 14.211(1) Å, b = 14.017(2) Å, c = 9.6545(8) Å
β = 111.59(6)°
Ratio:
a:b:c = 1.014 : 1 : 0.689
Unit Cell V:
1,788.21 ÅÂģ (Calculated from Unit Cell)
Z:
4

X-Ray Powder DiffractionHide

Type Occurrence of BarroniteHide

General Appearance of Type Material:
globular/acicular aggregates, consisting of long-prismatic crystals, up to 0.3 mm in length
Place of Conservation of Type Material:
Cotype material is deposited in the collections of the Department of Mineralogy and Petrology, National Museum, CirkusovÃĄ 1740, 19300 Praha 9, Czech Republic, catalogue number P1P27/2024, and the MusÃĐum Cantonal des Sciences Naturelles (NaturÃĐum), DÃĐpartement de GÃĐologie, UniversitÃĐ de Lausanne, Anthropole, Dorigny, 1015 Lausanne, Switzerland, catalogue number MGL 087280
Geological Setting of Type Material:
Barronite is of supergene origin; its formation is the result of the oxidation-hydration of uraninite/pitchblende in the supergene zone in-situ along with other uranyl silicates and, also most probably, phosphates/arsenates.
Associated Minerals at Type Locality:

Synonyms of BarroniteHide

Other Language Names for BarroniteHide

Dutch:Barroniet
German:Barronit

Related Minerals - Strunz-mindat GroupingHide

9.AK.'Orlite'Pb3(UO2)3(Si2O7)2 · 6H2O
9.AK.05Soddyite(UO2)2SiO4 · 2H2OOrth. mmm(2/m2/m2/m) : Fddd
9.AK.10SklodowskiteMg(UO2)2(SiO3OH)2 · 6H2OMon. 2/m : B2/m
9.AK.10CuprosklodowskiteCu(UO2)2(SiO3OH)2 · 6H2OTric. 1 : P1
9.AK.10OursiniteCo(UO2)2(SiO3OH)2 · 6H2OOrth. mmm(2/m2/m2/m) : Cmca
9.AK.15ParauranophaneCa(UO2)2(SiO3OH)2 · 5H2OMon. 2/m : P21/b
9.AK.15UranophaneCa(UO2)2(SiO3OH)2 · 5H2OMon. 2 : P21
9.AK.15NatroboltwooditeNa(UO2)(SiO3OH) · H2OOrth. 222 : P212121
9.AK.15KasolitePb(UO2)(SiO4) · H2OMon. 2/m : P21/b
9.AK.15Boltwoodite(K,Na)(UO2)(SiO3OH) · 1.5H2OMon. 2 : P21
9.AK.20Swamboite-(Nd)Nd0.333[(UO2)(SiO3OH)](H2O)~2.5Mon. 2/m : P21/b
9.AK.25HaiweeiteCa(UO2)2[Si5O12(OH)2] · 6H2OOrth. mmm(2/m2/m2/m) : Pbcn
9.AK.25MetahaiweeiteCa(UO2)2Si6O15 · nH2OMon. 2/m : P2/b
9.AK.30WeeksiteK2(UO2)2(Si5O13) · 4H2OMon. 2/m : B2/m
9.AK.30CoutinhoiteThxBa(1-2x)(UO2)2Si5O13 · (H2O)1+y (0 < x < 0.5 and 0 < y < (2+x))Orth. mmm(2/m2/m2/m)
9.AK.35MagnioursiliteMg4(UO2)4(Si2O5)5(OH)6 · 20H2O
9.AK.35CalcioursiliteCa4(UO2)4(Si2O5)5(OH)6 · 15H2OOrth.
9.AK.40UranosiliteUO3 · 7SiO2Orth.

RadioactivityHide

Fluorescence of BarroniteHide

It is non-fluorescent in SW and LW ultraviolet light

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BarroniteHide

References for BarroniteHide

Localities for BarroniteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany (TL)
 
  • Baden-WÞrttemberg
    • Freiburg Region
      • Waldshut
        • St Blasien
          • Menzenschwand
PlÃĄÅĄil et al. (2024)
 
and/or  
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