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Unnamed (ordered srilankaite)

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Formula:
ZrTi2O6
Crystal System:
Orthorhombic
The occurrence of lamellae (in baddeleyite) of ordered ZrTi2O6 (orthorhombic space group Pbcn with a = 14.198 ± 0.002 Å, b = 5.326 ± 0.001 Å, c = 5.002 ± 0.001 Å). Single-crystal X-ray diffraction and Raman microspectroscopy results, including a calculated spectrum, are presented for the newly recognised ordered form of ZrTi2O6. In this phase, Zr is eight- and Ti is six-coordinated. It seems to be a hitherto unknown polymorph: So far, only disordered ZrTi2O6 with both Zr and Ti in octahedral sites was known to occur in nature. Revisiting known srilankite samples appears worthwhile.


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Unique IdentifiersHide

Mindat ID:
493013
Long-form identifier:
mindat:1:1:493013:2

Chemistry of Unnamed (ordered srilankaite)Hide

Mindat Formula:
ZrTi2O6
Element Weights:
Element% weight
O33.927 %
Ti33.834 %
Zr32.240 %

Calculated from ideal end-member formula.
O
Ti
Zr

Crystallography of Unnamed (ordered srilankaite)Hide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pbcn
Setting:
Pbcn
Cell Parameters:
a = 14.198(2) Å, b = 5.326(1) Å, c = 5.002(1) Å
Ratio:
a:b:c = 2.666 : 1 : 0.939
Unit Cell V:
378.24 ų (Calculated from Unit Cell)
Morphology:
Lamellae in baddeleyite.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Unnamed (ordered srilankaite)Hide

References for Unnamed (ordered srilankaite)Hide

Localities for Unnamed (ordered srilankaite)Hide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Sri Lanka
 
  • North Central Province
    • Anuradhapura District
Nasdala et al. (2025)
 
and/or  
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