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Unnamed (ordered srilankaite)
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Formula:
ZrTi2O6
Crystal System:
Orthorhombic
The occurrence of lamellae (in baddeleyite) of ordered ZrTi2O6 (orthorhombic space group Pbcn with a = 14.198 ± 0.002 Å, b = 5.326 ± 0.001 Å, c = 5.002 ± 0.001 Å). Single-crystal X-ray diffraction and Raman microspectroscopy results, including a calculated spectrum, are presented for the newly recognised ordered form of ZrTi2O6. In this phase, Zr is eight- and Ti is six-coordinated. It seems to be a hitherto unknown polymorph: So far, only disordered ZrTi2O6 with both Zr and Ti in octahedral sites was known to occur in nature. Revisiting known srilankite samples appears worthwhile.
Unique Identifiers
Mindat ID:
493013
Long-form identifier:
mindat:1:1:493013:2
Chemistry of Unnamed (ordered srilankaite)
Mindat Formula:
ZrTi2O6
Element Weights:
Elements listed:
Crystallography of Unnamed (ordered srilankaite)
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pbcn
Setting:
Pbcn
Cell Parameters:
a = 14.198(2) Å, b = 5.326(1) Å, c = 5.002(1) Å
Ratio:
a:b:c = 2.666 : 1 : 0.939
Unit Cell V:
378.24 ų (Calculated from Unit Cell)
Morphology:
Lamellae in baddeleyite.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Unnamed (ordered srilankaite)
mindat.org URL:
https://www.mindat.org/min-493013.html
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References for Unnamed (ordered srilankaite)
Reference List:
[1]Nasdala, Lutz; Giester, Gerald; Chanmuang N., Chutimun; Hauzenberger, Christoph; Pascale, Fabien; Dovesi, Roberto; Fernando, G.W.A. Rohan; Sameera, K.A. Geeth; Ende, Martin; Habler, Gerlinde (2025) Baddeleyite containing ordered srilankite (ZrTi2O6) from Eppawala, Sri Lanka. Lithos, 516. doi:10.1016/j.lithos.2025.108230
Localities for Unnamed (ordered srilankaite)
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Sri Lanka | |
| Nasdala et al. (2025) |
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