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Alluaudite Supergroup

A group of related mineral species
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About Alluaudite SupergroupHide

Formula:
A(2)'A(1)M(1)M(2)2(TO4)3
Phosphates:
A(2)’ = Na, □ (vacancy)
A(1) = Na, Ca,
M(1) = Mn, Fe2+
M(2) = Mn, Fe2+, Fe3+, Mg
T = P
Arsenates:
A(2)’ = Na, □ (vacancy), Cu2+
A(1) = Cu2+, Ca, Na, □ (vacancy)
M(1) = Zn, Ca, Mg, Mn, Cu2+, Cd
M(2) = Zn, Cu2+, Mg, Mn2+, Mn, Fe3+, Mg
T = As
The Alluaudite Supergroup was established and approved by IMA in 2018. The supergroup is divided into the alluaudite group, the wyllieite group, and the bobfergusonite group.

It contains Na–Mn–Fe-bearing phosphates (found in granitic pegmatites) and Na-bearing arsenates (found in various geological environments) characterized by a monoclinic symmetry and by unit-cell parameters generally around a ~ 12, b ~ 12.5, c ~ 6.5 Å, Beta ~ 115° (Hatert 2019).



Unique IdentifiersHide

Mindat ID:
53044
Long-form identifier:
mindat:1:1:53044:6

IMA Classification of Alluaudite SupergroupHide

Pending publication
IMA status notes:
IMA Approved Group Name
Approval history:
Established and approved by IMA in 2018, with a new classification and nomenclature scheme (CNMNC Newsletter
No. 44).

Chemistry of Alluaudite SupergroupHide

Mindat Formula:
A(2)'A(1)M(1)M(2)2(TO4)3

Phosphates:
A(2)’ = Na, □ (vacancy)
A(1) = Na, Ca,
M(1) = Mn, Fe2+
M(2) = Mn, Fe2+, Fe3+, Mg
T = P
Arsenates:
A(2)’ = Na, □ (vacancy), Cu2+
A(1) = Cu2+, Ca, Na, □ (vacancy)
M(1) = Zn, Ca, Mg, Mn, Cu2+, Cd
M(2) = Zn, Cu2+, Mg, Mn2+, Mn, Fe3+, Mg
T = As

Chemical AnalysisHide

Oxide wt%:
 12
P2O543,19 %
Al2O31,31 %
Fe2O36,42 %
FeO3,64 %
MnO17,23 %18.45 %
MgO0,47 %8.84 %
CaO1,31 %0.26 %
Na2O4,94 %5.44 %
Li2O0,04 %
H2O+0,88 %
Insol0,81 %
CoO1.47 %
As2O559.51 %
CuO2.13 %
H2Ocalc2.86 %
Total:75 %98.96 %
Empirical formulas:
Sample IDEmpirical Formula
2Na(Mn0.78Mg0.22)Σ1.00(Mg1.04Mn0.70Cu0.15Co0.11)Σ 2.00[AsO4]2[AsO2(OH)2]

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020473CanutiteKampf A R, Mils S J, Hatert F, Nash B P, Dini M, Molina Donoso A A (2014) Canutite, NaMn3[AsO4][AsO3(OH)]2, a new protonated alluaudite-group mineral from the Torrecillas mine, Iquique Province, Chile Mineralogical Magazine 78 787-7952014Torrecillas mine, Iquique Province, Chile0293
0020029HatertiteKrivovichev S V, Vergasova L P, Filatov S K, rybin D S, Britvin S N, Ananiev V V (2013) Hatertite, Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3, a new alluaudite-group mineral from Tolbachik fumaroles, Kamchatka peninsula, Russia European Journal of Mineralogy 25 683-6912013Tolbachik fumaroles, Kamchatka peninsula, Russia0293
0020694ErikapohliteSchluter J, Malcherek T, Mihailova B, Gebhard G (2013) The new mineral erikapohlite, Cu3(Zn,Cu,Mg)4Ca2(AsO4)6*2H2O, the Ca-dominant analogue of keyite, from Tsumeb, Namibia Neues Jahrbuch fur Mineralogie, Abhandlungen 190 319-3252013Tsumeb, Namibia0293
0018619ManitobaiteTait K T, Ercit T S, Abdu Y A, Cerny P, Hawthorne F C (2011) The crystal structure and crystal chemistry of manitobaite, ideally (Na16_)Mn2+25Al8(PO4)30, from Cross Lake, Manitoba The Canadian Mineralogist 49 1221-12422011Cross Lake, Manitoba, Canada0293
0018618ManitobaiteTait K T, Ercit T S, Abdu Y A, Cerny P, Hawthorne F C (2011) The crystal structure and crystal chemistry of manitobaite, ideally (Na16_)Mn2+25Al8(PO4)30, from Cross Lake, Manitoba The Canadian Mineralogist 49 1221-12422011Cross Lake, Manitoba, Canada0293
0018317FerroqingheiiteHatert F, Baijot M, Philippo S, Wouters J (2010) Qingheiite-(Fe2+), Na2Fe2+MgAl(PO4)3, a new phosphate mineral from the Sebastiao Cristino pegmatite, Minas Gerais, Brazil European Journal of Mineralogy 22 459-4672010the Sebastiao Cristino pegmatite, Minas Gerais, Brazil0293
0006298GroatiteCooper M A, Hawthorne F C, Ball N A, Ramik R A, Roberts A C (2009) Groatite, NaCaMn2(PO4)[PO3(OH)]2, a new mineral species of the alluaudite group from the Tanco Pegmatite, Bernic Lake, Manitoba, Canada: Description and crystal structure The Canadian Mineralogist 47 1225-12352009Tanco Pegmatite, Bernic Lake, Manitoba, Canada0293
0007183RosemaryiteHatert F, Hermann R P, Fransolet A M, Long G J, Grandjean F (2006) A structural, infrared, and Mossbauer spectral study of rosemaryite, NdMnFe3+Al(PO4)3 European Journal of Mineralogy 18 775-7852006Buranga pegmatite, Rwanda0293
0007100YazganiteSarp H, Cerny R (2005) Yazganite, NaFe3+2(Mg,Mn)(AsO4)3*H2O, a new mineral: its description and crystal structure European Journal of Mineralogy 17 367-3732005Volcanic complex of Erciyes, Kiranardi, Turkey0293
0007138HagendorfiteRedhammer G J, Tippelt G, Bernroider M, Lottermoser W, Amthauer G, Roth G (2005) Hagendorfite (Na,Ca)MnFe2(PO4)3 from type locality Hagendorf (Bavaria, Germany): Crystal structure determination and 57Fe Mossbauer spectroscopy European Journal of Mineralogy 17 915-9322005Hagendorf, Bavaria, Germany0293
0007137HagendorfiteRedhammer G J, Tippelt G, Bernroider M, Lottermoser W, Amthauer G, Roth G (2005) Hagendorfite (Na,Ca)MnFe2(PO4)3 from type locality Hagendorf (Bavaria, Germany): Crystal structure determination and 57Fe Mossbauer spectroscopy European Journal of Mineralogy 17 915-9322005Hagendorf, Bavaria, Germany0293
0007139AlluauditeRedhammer G J, Tippelt G, Bernroider M, Lottermoser W, Amthauer G, Roth G (2005) Hagendorfite (Na,Ca)MnFe2(PO4)3 from type locality Hagendorf (Bavaria, Germany): Crystal structure determination and 57Fe Mossbauer spectroscopy European Journal of Mineralogy 17 915-9322005Buranga, Rwanda0293
0005933JohilleriteTait K T, Hawthorne F C (2004) Johillerite from Tolbachik, Kamchatka Peninsula, Russia: Crystal-structure refinement and chemical composition The Canadian Mineralogist 42 717-7222004Tolbachik, Kamchatka Peninsula, Russia0293
0005932BobfergusoniteTait K T, Hawthorne F C, Cerny P, Galliski M A (2004) Bobfergusonite from the Nancy Pegmatite, San Luis Range, Argentina: Crystal-structure refinement and chemical composition The Canadian Mineralogist 42 705-7162004Nancy Pegmatite, San Luis Range, Argentina0293
0014632NickenichiteAuernhammer M, Effenberger H, Hentschel G, Reinecke T, Tillmanns E (1993) Nickenichite, a new arsenate from the Eifel, Germany Mineralogy and Petrology 48 153-1661993Nickenich, Nickenicher Sattel, Eifel, Germany0293
0014503CaryiniteErcit T S (1993) Caryinite revisited Mineralogical Magazine 57 721-7271993Langban, Sweden0293
0014830JohilleriteKeller P, Hess H (1988) Die kristallstrukturen von o'danielit, Na(Zn,Mg)3H2(AsO4)3, und johillerit, Na(Mg,Zn)3Cu(AsO4)3 Neues Jahrbuch fur Mineralogie, Monatshefte 1988 395-4041988Tsumeb, Namibia0293
0015444QingheiiteZhesheng M, Nicheng S, Zhizhong P (1983) Crystal structure of a new phosphatic mineral-qingheiite Scientia Sinica B26 876-8841983Northwestern Qinghe County, Altay Prefecture, Uygur Autonomous Region, Xinjiang0293
0000397FerrowyllieiteMoore P B, Molin-Case J (1974) Contribution to pegmatite phosphate giant crystal paragenesis: II. The crystal chemistry of wyllieite, Na2Fe2Al[PO4]3, a primary phase American Mineralogist 59 280-2901974Victory mine pegmatite, near Custer, South Dakota, USA0293
0003758AlluauditeHatert F, Rebbouh L, Hermann R P, Fransolet A M, Long G J, Grandjean F (2005) Crystal chemistry of the hydrothermally synthesized Na2(Mn1-xFe2+x)2Fe3+(PO4)3 alluaudite-type solid solution American Mineralogist 90 653-66220050293
0003757AlluauditeHatert F, Rebbouh L, Hermann R P, Fransolet A M, Long G J, Grandjean F (2005) Crystal chemistry of the hydrothermally synthesized Na2(Mn1-xFe2+x)2Fe3+(PO4)3 alluaudite-type solid solution American Mineralogist 90 653-66220050293
0003756AlluauditeHatert F, Rebbouh L, Hermann R P, Fransolet A M, Long G J, Grandjean F (2005) Crystal chemistry of the hydrothermally synthesized Na2(Mn1-xFe2+x)2Fe3+(PO4)3 alluaudite-type solid solution American Mineralogist 90 653-66220050293
0003755AlluauditeHatert F, Rebbouh L, Hermann R P, Fransolet A M, Long G J, Grandjean F (2005) Crystal chemistry of the hydrothermally synthesized Na2(Mn1-xFe2+x)2Fe3+(PO4)3 alluaudite-type solid solution American Mineralogist 90 653-66220050293
0003754AlluauditeHatert F, Rebbouh L, Hermann R P, Fransolet A M, Long G J, Grandjean F (2005) Crystal chemistry of the hydrothermally synthesized Na2(Mn1-xFe2+x)2Fe3+(PO4)3 alluaudite-type solid solution American Mineralogist 90 653-66220050293
0008874AlluauditeHatert F, Long G J, Hautot D, Fransolet A-M, Delwiche J, Hubin-Franskin M J, Grandjean F (2004) A structural, magnetic, and Mossbauer spectral study of several Na-Mn-Fe-bearing alluaudites Physics and Chemistry of Minerals 31 487-50620040293
0005825ArseniopleiteTait K T, Hawthorne F C (2003) Refinement of the crystal structure of arseniopleite: Confirmation of its status as a valid species The Canadian Mineralogist 41 71-7720030293
0002974AlluauditeHatert F, Hermann R P, Long G J, Fransolet A M, Grandjean F (2003) An X-ray Rietveld, infrared, and Mossbauer spectral study of the NaMn(Fe1-xInx)2(PO4)3 alluaudite-type solid solution American Mineralogist 88 211-22220030293
0002973AlluauditeHatert F, Hermann R P, Long G J, Fransolet A M, Grandjean F (2003) An X-ray Rietveld, infrared, and Mossbauer spectral study of the NaMn(Fe1-xInx)2(PO4)3 alluaudite-type solid solution American Mineralogist 88 211-22220030293
0002972AlluauditeHatert F, Hermann R P, Long G J, Fransolet A M, Grandjean F (2003) An X-ray Rietveld, infrared, and Mossbauer spectral study of the NaMn(Fe1-xInx)2(PO4)3 alluaudite-type solid solution American Mineralogist 88 211-22220030293
0002971AlluauditeHatert F, Hermann R P, Long G J, Fransolet A M, Grandjean F (2003) An X-ray Rietveld, infrared, and Mossbauer spectral study of the NaMn(Fe1-xInx)2(PO4)3 alluaudite-type solid solution American Mineralogist 88 211-22220030293
0015718BradaczekiteKrivovichev S V, Filatov S K, Burns P C (2001) The Jahn-Teller distortion of copper coordination polyhedra in the alluaudite structural type: Crystal structure of bradaczekite, NaCu4(AsO4)3 Zapiski Vserossijskogo Mineralogicheskogo Obshchestva 2001 1-820010293
0005498KeyiteCooper M A, Hawthorne F C (1996) The crystal structure of keyite, Cu3(Zn,Cu)4Cd2(AsO4)6(H2O)2, an oxysalt mineral with essential cadmium The Canadian Mineralogist 34 623-63019960293
0006583AlluauditeAntenucci D, Fransolet A M, Miehe G, Tarte P (1995) Synthese et cristallochimie de NaCaCdMg2(PO4)3, Phosphate nouveau a structure alluaudite sans cation trivalent European Journal of Mineralogy 7 175-18119950293
0006478AlluauditeAntenucci D, Miehe G, Tarte P, Schmahl W W, Fransolet A-M (1993) Combined X-ray Rietveld, infrared and Raman study of a new synthetic variety of alluaudite, NaCdIn2(PO4)3 European Journal of Mineralogy 5 207-21319930293
0012695FerroalluauditeCorbin D R, Whitney J F, Fultz W C, Stucky G D, Eddy M M, Cheetham A K (1986) Synthesis of open-framework transition-metal phosphates using organometallic precursors in acidic media. Preparation and structural characterization of Fe5P4O20H10 and NaFe3P3O12 Inorganic Chemistry 25 2279-228019860293
0005212BobfergusoniteErcit T S, Hawthorne F C, Cerny P (1986) The crystal structure of bobfergusonite. The Canadian Mineralogist 24 605-61419860293
0000266AlluauditeMoore P B (1971) Crystal chemistry of the alluaudite structure type: Contribution to the paragenesis of pegmatite phosphate giant crystals American Mineralogist 56 1955-197519710293
CIF Raw Data - click here to close

Relationship of Alluaudite Supergroup to other SpeciesHide

Alluaudite Supergroup Members:
Alluaudite Group 
  Alluaudite (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon. 2/m : B2/b
  'Alluaudite-Ca[]' ◻4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
  'Alluaudite-Na[]' ◻4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
  Arseniopleite NaCaMnMn2(AsO4)3Mon. 2/m
  Badalovite Na2Mg2Fe(AsO4)3Mon. 2/m : B2/b
  Bradaczekite NaCu4(AsO4)3Mon. 2/m : B2/b
  Calciohatertite NaNaCa(CaFe3+)(AsO4)3Mon. 2/m : B2/b
  Calciojohillerite NaCaMg3(AsO4)3Mon. 2/m : B2/b
  Camanchacaite NaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
  Canutite NaMn3[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
  Caryinite (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
  Erikapohlite Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2OMon. 2/m : B2/m
  Ferroalluaudite (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m : B2/b
  'Ferroalluaudite-NaNa' Na4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m : B2/m
  'Ferrohagendorfite' NaCaFe2+Fe2+2(PO4)3Mon.
  Groatite NaCaMn2(PO4)[PO3(OH)]2Mon. 2/m : B2/b
  Hagendorfite NaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
  'Hagendorfite-NaNa' NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)Mon. 2/m : B2/b
  Hatertite Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m : B2/b
  Johillerite Na(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
  Keyite Cu2+3Zn4Cd2(AsO4)6 · 2H2OMon. 2/m
  Khrenovite Na3Fe3+2(AsO4)3Mon. 2/m : B2/b
  Maghagendorfite (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3Mon. 2/m
  Magnesiocanutite NaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m : B2/b
  Magnesiohatertite (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m : B2/b
  Nickenichite Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
  O'Danielite Na(Zn,Mg)3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
  Paraberzeliite NaCa2Mg2(AsO4)3Mon. 2/m : B2/b
  'Unnamed (Mn-analogue of Alluaudite)' (Na,Ca)Mn2+(Mn3+,Fe3+,Fe2+)2(PO4)3
  'Unnamed (Na-Mg Arsenate Hydroxyarsenate)' NaMg3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
  'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)' Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2Mon. 2/m : B2/b
  Varulite NaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
  Yazganite NaFe3+2(Mg,Mn2+)(AsO4)3 · H2OMon. 2/m : B2/b
  Zhanghuifenite Na3Mn4Mg2Al(PO4)6Mon. 2/m
  Zincobradaczekite NaZn2Cu2(AsO4)3Mon. 2/m : B2/b
Bobfergusonite Group 
  Bobfergusonite Na2Mn5FeAl(PO4)6Mon. 2/m : P2/b
  Ferrobobfergusonite Na2Fe2+5Fe3+Al(PO4)6Mon.
Manitobaite Group 
  Manitobaite Na16Mn2+ 25Al8(PO4)30Mon. m : Pb
Wyllieite Group 
  Ferroqingheiite NaNaFe2+(MgAl)(PO4)3Mon. 2/m : P21/m
  Ferrorosemaryite ◻NaFe2+Fe3+Al(PO4)3Mon. 2/m
  Ferrowyllieite (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m : P21/b
  'Fupingqiuite' Mon.
  Magnesioqingheiite Na2Mg(MgAl)(PO4)3Mon. 2/m
  Qingheiite NaNaMn2+(MgAl)(PO4)3Mon. 2/m : P21/b
  Rosemaryite (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m : P21/b
  Wyllieite (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m
Johanngeorgenstadtite Ni2+4.5(AsO4)3Mon. 2/m : B2/b
Leybovite-K KCuNa(MgFe3+)(AsO4)3Mon. 2/m : B2/b
Manganobadalovite NaNaMn(MgFe3+)(AsO4)3Mon. 2/m : B2/b
Manganohatertite NaNaCa(MnFe3+)(AsO4)3Mon. 2/m : B2/b
Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Alluaudite SupergroupHide

References for Alluaudite SupergroupHide

Localities for Alluaudite SupergroupHide

Showing 326 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Angola
 
  • Namibe Province
    • Moçâmedes
      • Giraúl pegmatite field
[Alluaudite] Gonçalves et al. (2019)
Argentina
 
  • Córdoba Province
[Alluaudite Group] Colombo et al. (2012)
      • Parroquia District
[Varulite] Biglia et al. (2021)
[Maghagendorfite] Colombo et al. (2012) +1 other reference
    • San Alberto Department
      • Tránsito District
        • Pampa de Achala
[Alluaudite] Gay et al. (1991) +1 other reference
  • La Rioja Province
    • General Ángel V. Peñaloza Department
[Alluaudite, Wyllieite] Colombo et al. (2018)
  • Salta Province
    • La Poma Department
[Alluaudite] GALLISKI (1983) +1 other reference
  • San Luis Province
    • Chacabuco Department
      • Sierra de la Estanzuela
[Alluaudite] Galliski et al. (2020)
    • Coronel Pringles Department
      • Totoral pegmatitic field
[Qingheiite, Zhanghuifenite] OYARZABAL et al. (H2O) +3 other references
    • Junín Department
[Bobfergusonite, Varulite, Wyllieite] Tait et al. (2004)
    • San Martín Department
[Varulite, Wyllieite] Roda-Robles et al. (2012)
Australia
 
  • Victoria
    • East Gippsland Shire
      • Glen Valley
[Alluaudite] Eagle et al. (2015) +1 other reference
[Alluaudite] Eagle et al. (2015) +1 other reference
[Alluaudite] Eagle et al. (2015)
[Alluaudite] Dr. Bill Birch - Museum Victoria
Austria
 
  • Salzburg
    • Tamsweg District
      • Tweng
[Arseniopleite] Kolitsch et al. (2021)
Bolivia
 
  • Potosí
    • Rafael Bustillo Province
      • Llallagua
[Hagendorfite] John White collection (from David New stock, 1976) +2 other references
Brazil
 
  • Minas Gerais
    • Conselheiro Pena
      • Barra do Cuieté
[Alluaudite] Cassedanne et al. (1982)
    • Divino das Laranjeiras
      • Linópolis
[Wyllieite] Cassedanne (1983) +1 other reference
[Ferroqingheiite] Hatert et al. (2010) +1 other reference
    • Galiléia
      • Laranjeiras
[Alluaudite] Cassedanne et al. (1981)
  • Pará
    • Canaã dos Carajás
      • Serra Sul complex
        • S11D deposit
[Ferrowyllieite] SALLUN FILHO (orgs.) +2 other references
  • Rio Grande do Norte
    • Parelhas
[Alluaudite, Varulite] Amores et al. (2014) +1 other reference
  • Tocantins
[Hagendorfite] Coelho et al. (2025)
Canada
 
  • Manitoba
    • Cross Lake
      • North Group
[Alluaudite, Bobfergusonite, Manitobaite] Černý et al. (1998) +1 other reference
    • Lac-du-Bonnet area
      • Bernic Lake
[Alluaudite] Econ Geol (1995)
[Alluaudite, Groatite] Can.Rockhound. 3 (2)
      • Cat Lake - Winnipeg River pegmatite field
[Alluaudite] Bannatyne (1985)
[Alluaudite] Černý et al. (1998) +1 other reference
  • Northwest Territories
    • Yellowknife Pegmatite field
[Alluaudite Group] Wise et al. (1990)
[Alluaudite] Northern Mineral Showings Database
  • Ontario
    • Kenora District
[Alluaudite] Avalon Advanced Materials Inc.
    • Thunder Bay District
      • Barbara Lake Area
[Alluaudite] Hewitt (1967)
[Alluaudite] Traill (1983)
[Alluaudite] Traill (1983)
  • Yukon
    • Dawson mining district
[Alluaudite, Ferroalluaudite, Hagendorfite, Maghagendorfite] Robinson et al. (1992)
[Alluaudite] Robinson et al. (1992)
[Alluaudite, Ferroalluaudite, Ferroalluaudite-NaNa] 150-152. +2 other references
Chile
 
  • Tarapacá
    • Iquique Province
      • Iquique
[Camanchacaite, Canutite, Magnesiocanutite, Unnamed (Na-Mg Arsenate Hydroxyarsenate)] Williams et al. (2013) +1 other reference
China
 
  • Xinjiang
    • Ili Kazakh Autonomous Prefecture
      • Altay Prefecture (Aletai Prefecture)
        • Qinghe Co. (Qinggil Co.; Chinggil Co.)
[Qingheiite] Yu et al. (1983) +1 other reference
Czech Republic
 
  • Central Bohemian Region
    • Kutná Hora District
      • Vlkaneč
[Ferroalluaudite] Povondra et al. (eds.) +1 other reference
  • Karlovy Vary Region
    • Cheb District
      • Aš
[Ferrohagendorfite, Hagendorfite] Breiter K.
  • Plzeň Region
    • Domažlice District
      • Otov
[Alluaudite, Hagendorfite] Masau +2 other references
  • Vysočina Region
    • Žďár nad Sázavou District
      • Bory
[Alluaudite] Staněk (1991) +4 other references
[Alluaudite] Staněk (1997)
Europe
 
[Alluaudite, Rosemaryite, Wyllieite] Berbain et al. (2012)
Finland
 
  • Kanta-Häme
    • Tammela
[Alluaudite, Ferroalluaudite, Varulite] Wilke (1976) +1 other reference
  • Päijänne Tavastia
    • Heinola
[Alluaudite] Mattila
  • Pirkanmaa
    • Orivesi
      • Eräjärvi area
[Alluaudite] Lahti (1981)
[Varulite] Lahti (2000)
  • South Ostrobothnia
    • Alavus
[Alluaudite, Varulite] Haapala (1966) +1 other reference
    • Kuortane
[Alluaudite, Varulite] Makitie et al. (2001)
    • Seinäjoki
[Alluaudite] Mäkitie et al. (1.86-1.79 Ga)
      • Peräseinäjoki
[Varulite]
  • Southwest Finland
[Ferroalluaudite] Ilkka Mikkola Collection XRD+ ...
      • Kimitoön Island
[Alluaudite] Ilkka Mikkola personal collection
[Alluaudite] - (1899)
[Ferroalluaudite, Unnamed (Mn-analogue of Alluaudite)] Pavel M. Kartashov analytical data 2019
[Alluaudite, Varulite] Acta Acad. Aboensis (1939) +1 other reference
    • Somero
[Alluaudite] Uher et al. (2008)
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Bellac
        • Bessines-sur-Gartempe
[Alluaudite] perso.wanadoo.fr (2004)
        • Razès
[Alluaudite, Ferroalluaudite] Meisser et al. (2008)
[Alluaudite-Na[]] Moore et al. (1979)
[Alluaudite] Mineralogical Magazine (1979)
[Alluaudite] Boisson (1988)
[Alluaudite] Guide geologique de la Haute Vienne
      • Limoges
        • Saint-Sylvestre
[Alluaudite] perso.wanadoo.fr (2005)
  • Occitanie
    • Ariège
      • Saint-Girons
        • Le Port
          • Col d'Agnès
            • Etang de Lers
[Alluaudite] Bull. Soc. Franç. Minéralo. ...
    • Pyrénées-Orientales
      • Céret
        • Argelès-sur-Mer
[Rosemaryite, Wyllieite] Berbain et al. (2012)
        • Collioure
[Alluaudite, Rosemaryite, Wyllieite] Berbain et al. (2012)
  • Provence-Alpes-Côte d'Azur
    • Var
      • Toulon
        • Le Pradet
          • Cap Garonne Mine
[Bradaczekite] Galéa-Clolus et al. (2025) +1 other reference
Germany
 
  • Bavaria
    • Lower Bavaria
      • Regen District
        • Zwiesel
          • Rabenstein
[Alluaudite, Hagendorfite] Weiß (1990)
    • Upper Palatinate
      • Neustadt an der Waldnaab District
        • Waidhaus
[Hagendorfite] Dill (2009)
[Alluaudite, Hagendorfite] Dill et al. (2013)
[Hagendorfite] Neues Jahrb.Min. (1954) +1 other reference
  • North Rhine-Westphalia
    • Arnsberg
      • Märkischer Kreis
        • Iserlohn
          • Letmathe
            • Helmke quarry nature reserve
[Ferroalluaudite, Johillerite, Varulite] Bender et al. (1994) +1 other reference
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Pellenz
        • Nickenich
          • Nickenicher Sattel
[Nickenichite] Auernhammer et al. (1993)
[Nickenichite] Blass et al. (2006)
  • Saxony
    • Erzgebirgskreis
      • Ehrenfriedersdorf
[Wyllieite] Thomas et al. (2000)
[Johanngeorgenstadtite] Kampf et al. (2020) +1 other reference
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Km 3
          • Kaminiza mines
[Keyite] Rieck (1999)
          • Km 3 mines
[Keyite] Rieck (1999)
India
 
  • Rajasthan
    • Ajmer District
[Alluaudite] Singh et al. (2016)
Italy
 
  • Aosta Valley
    • Nus
      • Saint-Barthélemy
[Arseniopleite] Barresi et al. (2005)
  • Campania
    • Metropolitan City of Naples
[Nickenichite] Russo et al. (2022)
  • Liguria
    • Savona Province
      • Magliolo
[Ferroalluaudite] Castellaro-Kampf
  • Lombardy
    • Lecco Province
      • Colico
[Alluaudite] VIGNOLA et al. (2007)
[Ferrowyllieite] Vignola et al. (2011) +1 other reference
  • Piedmont
    • Cuneo Province
      • Canosio
        • Vallone della Valletta
[Arseniopleite, Caryinite] Cámara et al. (2014)
  • Sicily
    • Metropolitan City of Catania
      • Biancavilla
[Badalovite, Calciojohillerite] Sicurella et al. (2025) +1 other reference
  • Trentino-Alto Adige/Südtirol
    • Trento Province
      • Rabbi
        • Ceresè
[Alluaudite] Vignola et al. (2018)
Japan
 
  • Fukushima Prefecture
    • Iwaki City
[Arseniopleite] The Mineral Species of Japan (5th ed) +1 other reference
  • Ibaraki Prefecture
    • Kasumigaura City
      • Chiyoda-machi
[Alluaudite, Varulite] The Mineral Species of Japan (5th ed) +1 other reference
Jordan
 
  • Amman Governorate
    • Transjordan Plateau
      • Daba-Siwaqa complex
[Alluaudite Group] Britvin et al. (2025)
Morocco
 
  • Drâa-Tafilalet Region
    • Ouarzazate Province
      • Amerzgane Cercle
        • Ouisselsate Caïdat
[Ferroalluaudite, Ferroalluaudite-NaNa] Pavel M. Kartashov (n.d.) +1 other reference
  • Marrakesh-Safi Region
    • Rehamna Province
      • Sidi Bou Othmane Cercle
        • Jebilet Mountain (Djebilet Mountain)
[Alluaudite, Alluaudite-Na[]] Fontan (1978)
Namibia
 
  • Erongo Region
    • Dâures Constituency
[Alluaudite] von Bezing (2007)
[Alluaudite] Keller (1985)
    • Karibib Constituency
      • Abbabis Farm 70
[Ferrowyllieite] Förch (1998)
      • Daheim Farm 106
[Alluaudite] Keller (1991)
      • Okatjimukuju Farm 55 (Friedrichsfelde Farm)
[Alluaudite] Keller et al. (1989) +1 other reference
[Alluaudite] Keller (1991)
      • Okongava Ost Farm 72
[Varulite] Keller et al. (2007)
[Alluaudite] Keller (1991)
      • Onanis Mountain
[Alluaudite] Keller (1991)
      • Tsaobismund Farm 85
[Alluaudite, Hagendorfite] Keller (1991) +1 other reference
[Alluaudite, Alluaudite-Na[]] Fransolet et al. (1986) +1 other reference
  • Oshikoto Region
    • Tsumeb
[Erikapohlite, Johillerite, Keyite, O'Danielite] Keller et al. (1982)
Poland
 
  • Lower Silesian Voivodeship
    • Dzierżoniów County
      • Gmina Niemcza
        • Gilów
[Alluaudite, Hagendorfite] Pieczka A. et al. (2004)
      • Piława Górna
        • DSS Piława Górna Quarry
[Alluaudite] Pieczka et al. (2018)
    • Świdnica County
      • Gmina Świdnica
[Alluaudite, Ferrohagendorfite, Hagendorfite] Pieczka A. et al. (SW Poland, Lower Silesia, Góry Sowie Mts.)
[Alluaudite, Ferroalluaudite, Ferrowyllieite, Hagendorfite, Maghagendorfite, Qingheiite, Rosemaryite, Wyllieite, Wyllieite Group] Łodziński M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts)
[Alluaudite, Ferrowyllieite, Hagendorfite, Qingheiite, Rosemaryite, Wyllieite] Pieczka et al. (2017)
    • Ząbkowice Śląskie County
      • Gmina Ząbkowice Śląskie
        • Szklary
[Alluaudite, Bobfergusonite, Varulite] Pieczka (2007) +1 other reference
Portugal
 
[Alluaudite Group, Hagendorfite] Figueiras +3 other references
  • Viana do Castelo
    • Viana do Castelo
      • Montaria
[Rosemaryite, Wyllieite] Dias P et al. (2014)
  • Viseu
    • Mangualde
      • Mangualde (Mesquitela e Cunha Alta)
[Alluaudite, Hagendorfite, Varulite]
    • Sátão
      • Ferreira de Aves
        • Aldeia Nova
[Alluaudite] PROSPEG – Projecto de prospecção +2 other references
Romania
 
  • Maramureș County
    • Târgu Lăpuș
[Caryinite] HÎRTOPANU et al. (2025)
Russia
 
  • Kamchatka Krai
    • Milkovsky District
      • Tolbachik Volcanic field
[Bradaczekite] [Canadian Mineralogist (2001) +1 other reference
[Hatertite, Johillerite] Tait et al. (2004)
[Bradaczekite, Johillerite] Glavatskikh et al. (1998) +2 other references
[Alluaudite, Badalovite, Bradaczekite, Calciohatertite, Calciojohillerite, Hatertite, Johillerite, Khrenovite, Leybovite-K, Magnesiohatertite, Manganobadalovite, Manganohatertite, Nickenichite, Paraberzeliite] Pekov et al. (2025)
[Johillerite] Pekov et al. (2019)
[Johillerite]
[Bradaczekite, Zincobradaczekite] Pekov et al. (2020)
        • Mountain 1004
[Johillerite] Shchipalkina et al. (2020)
  • Krasnoyarsk Krai
    • Boguchansky District
      • Chadobets alkaline complex
[Ferrohagendorfite] Sharygin +10 other references
Rwanda
 
  • Southern Province
    • Muhanga District
      • Nyamabuye
        • Muhanga
[Alluaudite] Royal Museum for Central Africa
      • Nyarusange
[Alluaudite, Hagendorfite] Can Min (2004)
  • Western Province
[Ferroalluaudite] Anthony et al. (2016)
    • Ngororero District
      • Bwira
[Ferrorosemaryite] Lefèvre et al. (http://www.minsocam.org/msa/special/pig/PIG_articles/Elba%20Abstracts%2012%20Lefevre.pdf) +1 other reference
      • Gatumba pegmatite field
[Varulite] Hulsbosch et al. (2019)
      • Muhororo
[Alluaudite, Alluaudite-Na[], Rosemaryite, Varulite, Wyllieite] Bertossa (1968) +1 other reference
[Alluaudite] Can Mineral April 1998 v. 36 no. 2 p. ...
Spain
 
  • Balearic Islands
    • Majorca
      • Llucmajor
[Qingheiite, Wyllieite] Merino et al. (2019)
  • Castile and Leon
[Alluaudite Group] Errandonea-Martin et al. (2022)
    • Salamanca
      • Aldea del Obispo
[Varulite] Roda-Robles M E et al. (2014)
      • Aldehuela de la Bóveda
[Alluaudite] Roda et al. (2001)
      • Garcirrey
[Alluaudite] Encarnación Roda-Robles (2007)
      • Golpejas
        • Golpejas Mining group
[Ferrobobfergusonite] Calvo Rebollar et al. (2022)
[Alluaudite, Rosemaryite, Varulite, Wyllieite] Encarnación Roda-Robles (2007) +1 other reference
      • Pereña de la Ribera
[Alluaudite, Ferroalluaudite] Roda-Robles et al. (2012)
    • Zamora
      • Villar del Buey
[Alluaudite] Roda-Robles et al. (1998)
[Alluaudite]
  • Catalonia
    • Girona
      • Alt Empordà
        • Cadaqués
[Alluaudite, Wyllieite] Bareche (2005)
[Alluaudite, Wyllieite] & locality references +1 other reference
  • Galicia
    • Pontevedra
      • Forcarei
[Ferroalluaudite] Calvo Rebollar (2015)
  • Navarre
    • Lesaka
      • Cinco Villas Massif
[Alluaudite] King (n.d.)
Sweden
 
  • Örebro County
    • Hällefors
      • Grythyttan
[Arseniopleite, Caryinite] Igelström (1888)
  • Östergötland County
    • Motala
      • Godegård
[Hagendorfite, Varulite] MinMag vol 73 1979
  • Stockholm County
    • Haninge
      • Norrö
[Alluaudite, Ferroalluaudite, Ferroalluaudite-NaNa, Hagendorfite] Gustafsson (1989)
[Alluaudite]
[Alluaudite] Wik et al. (2005)
    • Sigtuna
      • Arlanda
[Alluaudite, Ferroalluaudite] Nysten (1998)
  • Värmland County
    • Filipstad
      • Långban Ore District
[Arseniopleite, Caryinite] Holtstam et al. (1999)
[Arseniopleite] Natural History Museum
[Caryinite] Adolfsson (1979)
    • Torsby
[Ferrowyllieite, Wyllieite] Museum Victoria collection M 43287 +1 other reference
  • Västerbotten County
    • Skellefteå
[Alluaudite, Alluaudite-Na[], Hagendorfite, Varulite] Quensel (1937) +1 other reference
  • Västmanland County
    • Norberg
[Arseniopleite] Nysten (2020)
  • Västra Götaland County
    • Tidaholm
[Wyllieite] Ek et al. (1990)
Switzerland
 
  • Grisons
    • Albula Region
      • Surses
        • Tinizong (Tinzen)
          • Err valley
[Arseniopleite]
[Arseniopleite] Analyses par N. Meisser
    • Viamala Region
      • Ferrera
        • Ausserferrera
[Caryinite] Brugger J. (1996)
  • Ticino
    • Locarno
[Maghagendorfite] Vignola et al. (2008)
  • Valais
    • Visp
      • Zermatt
        • Gorner glacier area
          • Stockhorn
[Magnesioqingheiite] Bosi et al. (2023)
Turkey
 
  • Kayseri Province
    • Talas District
      • Kiranardi
        • Kültepe
          • Hisarcık
[Yazganite] Sarp et al. (2005)
  • Muğla Province
    • Milâs District
[Ferroalluaudite] Hikmet Kinaci et al. (2023)
UK
 
  • England
    • Cornwall
      • Breage
[Alluaudite]
USA
 
  • Arizona
    • Yavapai County
[Wyllieite] London et al. (1982)
  • Colorado
    • Larimer County
      • Crystal Mountain Pegmatite Mining District (Storm Mountain Mining District)
[Alluaudite] Eckel et al. (1997)
[Alluaudite] Eckel et al. (1997)
        • Storm Mountain
[Alluaudite] Rocks & Min.: 62: 234.
      • Purple Haze and Rainbows End claims
[Alluaudite] King et al. (1991)
      • Stove Prairie Area
[Alluaudite] Eckel et al. (1997)
  • Connecticut
    • Fairfield County
      • Redding
        • Branchville
[Alluaudite] Januzzi (1994)
  • Maine
    • Oxford County
      • Paris
[Hagendorfite] SEM/EDS analyzed by Lloyd W. Alexander ... +1 other reference
      • Rumford
[Alluaudite] Tim Blake and Scott Soucey specimens
  • New Hampshire
    • Grafton County
      • Groton
[Alluaudite Group] King (n.d.)
[Alluaudite Group] King (n.d.)
[Ferrohagendorfite, Hagendorfite, Hagendorfite-NaNa] Moore (1965)
[Ferrohagendorfite, Hagendorfite] Dr. Paul Moore collection
    • Sullivan County
      • Newport
[Alluaudite, Ferroqingheiite, Ferrowyllieite] Moore et al. (1979)
[Alluaudite] Mineralogical Society of America - ...
  • South Dakota
    • Custer County
      • Custer Mining District
        • Berne
[Alluaudite] Smith et al. (2000)
        • Custer
[Alluaudite] Smith et al. (2000)
[Alluaudite] Smith et al. (2000) +1 other reference
[Alluaudite] Smith et al. (2000)
[Alluaudite] Smith et al. (2000) +1 other reference
[Alluaudite, Wyllieite] Smith et al. (2000)
[Alluaudite, Rosemaryite] Smith et al. (2000)
[Ferrobobfergusonite, Ferrowyllieite, Wyllieite] Rocks & Min.: 57:55.
        • Fourmile
[Alluaudite] Rocks & Minerals: 60: 117.
[Alluaudite, Alluaudite Group] Moore et al. (1979)
[Alluaudite, Alluaudite-Na[]] Smith et al. (2000)
[Alluaudite, Wyllieite] Rocks & Minerals: 60: 117. +1 other reference
        • Pringle
[Alluaudite, Alluaudite-Na[]] Smith et al. (2000)
[Alluaudite] Smith et al. (2000)
[Alluaudite-Na[]] King (2000)
    • Pennington County
      • Keystone Mining District
[Maghagendorfite] Moore et al. (1979) +2 other references
        • Glendale
[Alluaudite] Campbell et al. (1985)
        • Keystone
[Alluaudite] Rocks & Minerals: 67 (6)
[Wyllieite] Yedlin (1973)
  • Wisconsin
    • Florence County
[Alluaudite, Varulite] Cordua (1998)
Zimbabwe
 
  • Mashonaland West
    • Karoi District
      • Mwami (Miami)
[Alluaudite] Anthony et al. (2000)
 
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