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Zaykovite
A valid IMA mineral species
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Formula:
Rh3Se4
Specific Gravity:
8.32 (Calculated)
Crystal System:
Monoclinic
Name:
Named in honor of Victor Vladimirovich Zaykov (Виктор Владимирович Зайков) (3 May 1938, Vladivostok, Far Eastern Territory, USSR - 22 December 2017, Miass, Chelyabinsk Region, Russia), professor at the Institute of Mineralogy, Ural Branch of the Russian Academy of Sciences.
First approved rhodium selenide mineral (compare UM2007-33-Se:CuRhS). The Se analogue of kingstonite.
Structurally a bit different from its nickel analogue, wilkmanite.
Structurally a bit different from its nickel analogue, wilkmanite.
Unique Identifiers
Mindat ID:
54352
Long-form identifier:
mindat:1:1:54352:9
Similar Names
| Saukovite | A variety of Metacinnabar | (Hg,Cd)S |
IMA Classification of Zaykovite
Approved
First published:
2023
Classification of Zaykovite
2.DA.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
D : Metal Sulfides, M: S = 3 :4 and 2:3
A : M:S = 3:4
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
D : Metal Sulfides, M: S = 3 :4 and 2:3
A : M:S = 3:4
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Zay | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Zaykovite
Density:
8.32 g/cm3 (Calculated)
Optical Data of Zaykovite
Anisotropism:
Weak
Bireflectance:
Weak.
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 470nm | 29.3% | 30.1% |
| 546nm | 31.0% | 32.2% |
| 589nm | 32.0% | 33.4% |
| 650nm | 33.7% | 35.1% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 35.1%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Grey colour with bluish-greenish tint.
Chemistry of Zaykovite
Mindat Formula:
Rh3Se4
Elements listed:
Crystallography of Zaykovite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 10.877(1) Å, b = 11.192(1) Å, c = 6.4796(6) Å
β = 108.887(2)°
β = 108.887(2)°
Ratio:
a:b:c = 0.972 : 1 : 0.579
Unit Cell V:
746.33 ų (Calculated from Unit Cell)
Z:
6
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 5.43 Å | (37) |
| 3.275 Å | (75) |
| 3.199 Å | (100) |
| 3.061 Å | (87) |
| 2.568 Å | (62) |
| 2.545 Å | (41) |
| 3.413 Å | (34) |
| 1.697 Å | (34) |
Comments:
Kazan placers, Chelyabinsk Oblast, Russia. Data from the type description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 26 : Hadean detrital minerals | |
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Zaykovite
General Appearance of Type Material:
Crystals up to 40 μm in size within grains of Pt3Fe alloy.
Place of Conservation of Type Material:
Collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5395/1.
Geological Setting of Type Material:
Placer deposit. Possibly derived from serpentinised dunite–harzburgite or gabbro–clinopyroxenite–dunite complexes in the vicinity.
Other Language Names for Zaykovite
Related Minerals - Strunz-mindat Grouping
| 2.DA. | Ferrodimolybdenite | FeMo2S4 |
| 2.DA. | Ezochiite | Cu+(Rh3+Pt4+)S4 |
| 2.DA. | Grimmite | NiCo2S4 |
| 2.DA. | Zolenskyite | FeCr2S4 |
| 2.DA.05 | Shiranuiite | Cu+(Rh3+Rh4+)S4 |
| 2.DA.05 | Fletcherite | CuNi2S4 |
| 2.DA.05 | Florensovite | (Cu,Zn)Cr1.5Sb0.5S4 |
| 2.DA.05 | Siegenite | CoNi2S4 |
| 2.DA.05 | Cadmoindite | CdIn2S4 |
| 2.DA.05 | Kalininite | ZnCr2S4 |
| 2.DA.05 | Violarite | Fe2+Ni3+2S4 |
| 2.DA.05 | Nickeltyrrellite | CuNi2Se4 |
| 2.DA.05 | Linnaeite | Co2+Co3+2S4 |
| 2.DA.05 | Carrollite | CuCo2S4 |
| 2.DA.05 | Cuproiridsite | (Cu,Fe)Ir2S4 |
| 2.DA.05 | Cuprorhodsite | (Cu+0.5Fe3+0.5)Rh3+2S4 |
| 2.DA.05 | Berndlehmannite | Cu(CrV)S4 |
| 2.DA.05 | Polydymite | Ni2+Ni3+2S4 |
| 2.DA.05 | Trüstedtite | Ni3Se4 |
| 2.DA.05 | Daubréelite | Fe2+Cr3+2S4 |
| 2.DA.05 | Cuprokalininite | Cu(Cr3+Cr4+)S4 |
| 2.DA.05 | Greigite | Fe2+Fe3+2S4 |
| 2.DA.05 | Joegoldsteinite | MnCr2S4 |
| 2.DA.05 | Bornhardtite | Co2+Co3+2Se4 |
| 2.DA.05 | Tyrrellite | Cu(Co,Ni)2Se4 |
| 2.DA.05 | Indite | FeIn2S4 |
| 2.DA.05 | Xingzhongite | Pb2+Ir3+2S4 |
| 2.DA.05 | Malanite | Cu+(Ir3+Pt4+)S4 |
| 2.DA.10 | Rhodostannite | Cu+(Fe2+0.5Sn4+1.5)S4 |
| 2.DA.10 | Toyohaite | Ag+(Fe2+0.5Sn4+1.5)S4 |
| 2.DA.15 | Brezinaite | Cr3S4 |
| 2.DA.15 | Heideite | (Fe,Cr)1.15(Ti,Fe)2S4 |
| 2.DA.20 | Konderite | Cu3Pb(Rh,Pt,Ir)8S16 |
| 2.DA.20 | Inaglyite | Cu3Pb(Ir,Pt)8S16 |
| 2.DA.25 | Kingstonite | Rh3S4 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Zaykovite
mindat.org URL:
https://www.mindat.org/min-54352.html
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References for Zaykovite
Localities for Zaykovite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
| Miyawaki et al. (2020) +1 other reference |
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