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Labuntsovite-Fe

A valid IMA mineral species
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About Labuntsovite-FeHide

Formula:
Na4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O
Colour:
Orange
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.94
Crystal System:
Monoclinic
Name:
Named for the iron content and its relationship to Labuntsovite-Mn
This page provides mineralogical data about Labuntsovite-Fe.


Unique IdentifiersHide

Mindat ID:
11425
Long-form identifier:
mindat:1:1:11425:7

IMA Classification of Labuntsovite-FeHide

Classification of Labuntsovite-FeHide

9.CE.30e

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Lab-FeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Labuntsovite-FeHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
Orange
Streak:
White
Hardness:
Density:
2.94(2) g/cm3 (Measured)    2.93 g/cm3 (Calculated)

Optical Data of Labuntsovite-FeHide

Type:
Biaxial (+)
RI values:
nα = 1.686(2) nβ = 1.696(2) nγ = 1.835(3)
2V:
Measured: 32° (1)
Max. Birefringence:
δ = 0.149
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Pleochroism:
Visible
Comments:
X = Z = pale yellow, Y = orange.

Chemistry of Labuntsovite-FeHide

Mindat Formula:
Na4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O
Element Weights:
Element% weight
O42.455 %
Si18.067 %
Ti15.396 %
Ba11.042 %
K6.288 %
Na3.697 %
Fe2.245 %
H0.811 %

Calculated from ideal end-member formula.
O
Si
Ti
Ba
K
Na
Fe
H
Common Impurities:
Mg,Mn

Crystallography of Labuntsovite-FeHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 14.249(6) Å, b = 13.791(6) Å, c = 7.777(2) Å
β = 116.82(3)°
Ratio:
a:b:c = 1.033 : 1 : 0.564
Unit Cell V:
1,363.85 ų (Calculated from Unit Cell)
Z:
1

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012359Labuntsovite-FeRastsvetaeva R K, Chukanov N V, Pekov I V, Shlyukova Z V, Khomyakov A P (1998) Structures of two potassium-rich labuntsovites in relation to the crystal chemistry of minerals of the labuntsovite-nenadkevichite family Crystallography Reports 43 820-82719980293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.169 Å(100)
3.100 Å(62)
2.585 Å(58)
6.95 Å(56)
3.032 Å(53)
6.34 Å(34)
2.478 Å(25)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of Labuntsovite-FeHide

Synonyms of Labuntsovite-FeHide

Other Language Names for Labuntsovite-FeHide

Relationship of Labuntsovite-Fe to other SpeciesHide

Other Members of Labuntsovite Group:
Labuntsovite-MgNa4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon. 2/m : B2/m
Labuntsovite-MnNa4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2OMon. 2/m : B2/m
'UM2006-16- SiO:BaFeHKMgMnNaNbTi'K3.58Na2.06Ba1.65(H2O)1.58(Mn0.42Mg0.20Fe0.16)[Ti6.75Nb0.65(OH)0.9O0.1)8(Si4O12)4] · 11.5H2O

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Labuntsovite-Fe associated with Neskevaaraite-FeK3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2O
1 photo of Labuntsovite-Fe associated with AegirineNaFe3+Si2O6

Related Minerals - Strunz-mindat GroupingHide

9.CE.Dutkevichite-(Ce)NaZnBa2Ce2Ti2Si8O26F · H2OOrth. mm2 : Ama2
9.CE.KataniteBa3NbFe3Si2O14Trig. 32 : P321
9.CE.NiobobaotiteBa4(Ti2.5Fe2+1.5)Nb4Si4O28ClTet. 4/m : I41/a
9.CE.AmaterasuiteSr4Ti6Si4O23(OH)ClOrth. mmm(2/m2/m2/m) : Fddd
9.CE.SteiningeriteBa2Zr2(Si4O12)O2Tet. 4/mmm(4/m2/m2/m) : P4/mbm
9.CE.05PapagoiteCaCu[H3AlSi2O9]Mon. 2/m : B2/m
9.CE.10VerplanckiteBa4Mn2+2Si4O12(OH,H2O)3Cl3Hex. 6/mmm(6/m2/m2/m) : P6/mmm
9.CE.15BaotiteBa4(Ti,Nb,W)8O16(SiO3)4ClTet. 4/m : I41/a
9.CE.20NagashimaliteBa4(V,Ti)4B2Si8O27(O,OH)2ClOrth. mmm(2/m2/m2/m) : Pmmn
9.CE.20TaramelliteBa4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm(2/m2/m2/m) : Pmmn
9.CE.20TitantaramelliteBa4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm(2/m2/m2/m)
9.CE.25Bario-orthojoaquinite(Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2OOrth.
9.CE.25Byelorussite-(Ce)NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2OOrth. mm2 : Ama2
9.CE.25Joaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2OMon. 2 : B2
9.CE.25Orthojoaquinite-(La)NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2OOrth. mmm(2/m2/m2/m)
9.CE.25StrontiojoaquiniteSr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2OMon.
9.CE.25Orthojoaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2OOrth.
9.CE.25Strontio-orthojoaquinite(Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2OOrth.
9.CE.30eLabuntsovite-MnNa4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2OMon. 2/m : B2/m
9.CE.30bTsepinite-NaNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30cGjerdingenite-NaK2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2OMon. 2/m : B2/m
9.CE.30hAlsakharovite-ZnNaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30cBurovaite-Ca(Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2OMon. 2/m : B2/m
9.CE.30aNenadkevichite(Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2OOrth. mmm(2/m2/m2/m) : Pbam
9.CE.30bTsepinite-SrSr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30cGjerdingenite-MnK2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30bParatsepinite-Na(Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8 · nH2O n ~ 8Mon. 2/m : B2/m
9.CE.30dLemmleinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2OOrth.
9.CE.30cKarupmøllerite-Ca(Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2OMon. 2/m : B2/m
9.CE.30cLepkhenelmite-Zn(Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30hGutkovaite-MnK2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon. m : Bm
9.CE.30eLabuntsovite-MgNa4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon. 2/m : B2/m
9.CE.30cKuzmenkoite-ZnK2Zn(Ti,Nb)4(Si4O12)2(OH,O)4 · 6-8H2OMon. m : Bm
9.CE.30fParalabuntsovite-MgNa8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2OMon. 2/m : B2/m
9.CE.30dLemmleinite-BaNa2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon. 2/m : B2/m
9.CE.30gOrganovaite-MnK2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2OMon. 2/m : B2/m
9.CE.30gOrganovaite-ZnK2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30bVuoriyarvite-KK2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2OMon. m : Bm
9.CE.30cGjerdingenite-FeK2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30a'Unnamed (Ca-Na-ordered analogue of Korobitsynite)'(Ca,Na)2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2OOrth. 222 : P21212
9.CE.30gParakuzmenkoite-Fe(K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2OMon. 2/m : B2/m
9.CE.30aKorobitsynite(Na,◻)4Ti2(Si4O12)(O,OH)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pbam
9.CE.30cKuzmenkoite-MnK2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2OMon. 2/m : B2/m
9.CE.30bTsepinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30bParatsepinite-BaBa4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2OMon. 2/m : B2/m
9.CE.30hNeskevaaraite-FeK3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2OMon. m : Bm
9.CE.30cGjerdingenite-CaK2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30bTsepinite-Ca(Ca,K,Na)2-x(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2OMon. 2/m : B2/m
9.CE.45'Natrokomarovite'(Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2OOrth.
9.CE.45Komarovite(Ca,Mn)(Nb,Ti)2[Si2O7](O,F)3 · 3.5H2OOrth. mmm(2/m2/m2/m) : Cmmm

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 6.2877% 1,949 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity: –

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Labuntsovite-FeHide

References for Labuntsovite-FeHide

Localities for Labuntsovite-FeHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Québec
    • Montérégie
      • Lajemmerais RCM
        • Varennes & St-Amable
          • Saint-Amable sill
Horváth et al. (1998)
Russia
 
  • Murmansk Oblast
    • Kovdorsky District
      • Kovdor Massif
maurice.strahlen.org (2003) +1 other reference
    • Kukisvumchorr Mt
Lapis 28 (12)
Yakovenchuk et al. (2005)
maurice.strahlen.org (2003)
USA
 
  • Arkansas
    • Hot Spring County
      • Magnet Cove
SEM-EDS by Chris Stefano
 
and/or  
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