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Mckelveyite-(Y)

A valid IMA mineral species
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About Mckelveyite-(Y)Hide

05127760017271925344859.jpg
Vincent Ellis McKelvey
Formula:
NaCaBa3Y(CO3)6 · 3H2O
Colour:
Yellow, orange-brown, gray, greenish-brown, nearly black.
Lustre:
Vitreous, Greasy, Dull
Hardness:
3½ - 4
Specific Gravity:
3.25
Crystal System:
Triclinic
Name:
Named in honor of Vincent Ellis McKelvey (6 April 1916, Huntingdon, Pennsylvania, USA - 23 January 1987, St. Cloud, Florida, USA), director of the US Geological Survey, for his studies of the Phosphoria Formation of Wyoming and Idaho. It was originally named without the suffix. The suffix was added in 1987 by the IMA to follow the Levinson rule for minerals with essential REE, in this case indicating the predominance of yttrium.
Monoclinic polytype known: Mckelveyite-(Y)-2M (proposal IMA2005-012a, subsequently withdrawn). The Y analogue of mckelveyite-(Nd); compare ewaldite.


Unique IdentifiersHide

Mindat ID:
2617
Long-form identifier:
mindat:1:1:2617:4

Similar NamesHide

MckelveyiteA synonym
Mckelveyite-(Nd)A valid IMA mineral species - pending publicationNaCaBa3Nd(CO3)6 · 3H2O

IMA Classification of Mckelveyite-(Y)Hide

Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
NaBa3CaY(CO3)6·3H2O
First published:
1965

Classification of Mckelveyite-(Y)Hide

5.CC.05

5 : CARBONATES (NITRATES)
C : Carbonates without additional anions, with H2O
C : With rare earth elements (REE)
15.3.4.2

15 : HYDRATED NORMAL CARBONATES
3 : AmBn(XO3)p·xH2O, with (m+n):p = 1:1
11.8.20

11 : Carbonates
8 : Carbonates of the rare earths

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Mkv-YIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Mckelveyite-(Y)Hide

Vitreous, Greasy, Dull
Transparency:
Transparent, Translucent, Opaque
Colour:
Yellow, orange-brown, gray, greenish-brown, nearly black.
Hardness:
3½ - 4 on Mohs scale
Density:
3.25(5) g/cm3 (Measured)    3.37 g/cm3 (Calculated)

Optical Data of Mckelveyite-(Y)Hide

Type:
Biaxial (-)
RI values:
nα = 1.55 - 1.554 nβ = 1.55 - 1.554 nγ = 1.649 - 1.658
Max. Birefringence:
δ = 0.099 - 0.104
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (180°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Dispersion:
weak to distinct
Pleochroism:
Visible
Comments:
In greens.
Comments:
Absorption: O > E.

Chemistry of Mckelveyite-(Y)Hide

Mindat Formula:
NaCaBa3Y(CO3)6 · 3H2O
Element Weights:
Element% weight
Ba42.123 %
O34.353 %
Y9.090 %
C7.368 %
Ca4.098 %
Na2.351 %
H0.618 %

Calculated from ideal end-member formula.
Ba
O
Y
C
Ca
Na
H

Crystallography of Mckelveyite-(Y)Hide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Comment:
Mckelveyite-(Y)-2M
NaCaBa3Y(CO3)6 · 3H2O
Monoclinic 
m - Domatic
Bb
Cc
a = 15.8213(7) Å, b = 9.1364(4) Å, c = 13.7522(6) Å
β = 112.44(1)°
a:b:c = 1.732 : 1 : 1.505
V 1,837.35 ų
(Calculated from Unit Cell)
 
Pseudo-rhombohedral.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0006180Mckelveyite-(Y)Demartin F, Gramaccioli C M, Campostrini I, Diella V (2008) The crystal structure of mckelveyite-(Y)-2M, a new monoclinic polytype from Val Malenco, Italian Alps The Canadian Mineralogist 46 195-2032008"Cava Fabi," talc quarry near Lanzada, Val Malenco, Lombardy, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.942 Å(100)
4.47 Å(85)
2.648 Å(40)
6.40 Å(35)
3.32 Å(30)
2.040 Å(30)
4.15 Å(20)
Comments:
Sweetwater Co., Wyoming, USA.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of Mckelveyite-(Y)Hide

General Appearance of Type Material:
Rare green, tabular to pyramidal pseudorhombohedral crystals. Also dark green or black, massive and crystal aggregates.
Place of Conservation of Type Material:
The Natural History Museum, London, England, number 1971,138.
National Museum of Natural History, Washington, D.C., USA, numbers 121683, 162607.
Geological Setting of Type Material:
From core in the Green River formation. Dolomitic marlstone.
Associated Minerals at Type Locality:

Synonyms of Mckelveyite-(Y)Hide

Other Language Names for Mckelveyite-(Y)Hide

Relationship of Mckelveyite-(Y) to other SpeciesHide

Other Members of Mckelveyite Group:
Alicewilsonite-(YCe)Na2Sr2YCe(CO3)6 · 3H2OTric. 1 : P1
Alicewilsonite-(YLa)Na2Sr2YLa(CO3)6 · 3H2OTric. 1 : P1
Bainbridgeite-(NdCe)Na2Ba2NdCe(CO3)6 · 3H2OTric. 1 : P1
Bainbridgeite-(YCe)Na2Ba2YCe(CO3)6 · 3H2OTric. 1 : P1
Donnayite-(Y)NaCaSr3Y(CO3)6 · 3H2OTric. 1 : P1
EwalditeBa(Na,Ca,Y,Ce,K)(CO3)2 · 2.6H2OHex. 6mm : P63mc
Mckelveyite-(Nd)NaCaBa3Nd(CO3)6 · 3H2OMon. m : Bb
WeloganiteNa2Sr3Zr(CO3)6 · 3H2OTric. 1 : P1

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Mckelveyite-(Y) associated with Donnayite-(Y)NaCaSr3Y(CO3)6 · 3H2O
1 photo of Mckelveyite-(Y) associated with NatroliteNa2Al2Si3O10 · 2H2O

Related Minerals - Strunz-mindat GroupingHide

5.CC.Bainbridgeite-(NdCe)Na2Ba2NdCe(CO3)6 · 3H2OTric. 1 : P1
5.CC.Yuchuanite-(Y)Y2(CO3)3 · H2OTric. 1 : P1
5.CC.Alicewilsonite-(YCe)Na2Sr2YCe(CO3)6 · 3H2OTric. 1 : P1
5.CC.05Donnayite-(Y)NaCaSr3Y(CO3)6 · 3H2OTric. 1 : P1
5.CC.05Alicewilsonite-(YLa)Na2Sr2YLa(CO3)6 · 3H2OTric. 1 : P1
5.CC.05Mckelveyite-(Nd)NaCaBa3Nd(CO3)6 · 3H2OMon. m : Bb
5.CC.05EwalditeBa(Na,Ca,Y,Ce,K)(CO3)2 · 2.6H2OHex. 6mm : P63mc
5.CC.05'UM1992-05-CO:CaCeLaNaSr'(Sr,Na,Y,REE,Ca,Ba)2(CO3)2 · H2OTrig. 3m : R3m
5.CC.05WeloganiteNa2Sr3Zr(CO3)6 · 3H2OTric. 1 : P1
5.CC.05Mckelveyite GroupA3B3(CO3)6 · 3H2O
5.CC.05Bainbridgeite-(YCe)Na2Ba2YCe(CO3)6 · 3H2OTric. 1 : P1
5.CC.05'Unnamed (MSH UK-37A)'Sr3NaCaY(CO3)6 · 3H2OHex. 6mm : P63mc
5.CC.10Tengerite-(Y)Y2(CO3)3 · 2-3H2OOrth. mmm(2/m2/m2/m) : Pnnm
5.CC.15Lokkaite-(Y)Ca(Y,Gd,Nd,Dy)4(CO3)7 · 9H2OOrth.
5.CC.15Kimuraite-(Y)Ca(Y,Nd)2(CO3)4 · 6H2OOrth.
5.CC.15Hizenite-(Y)Ca2Y6(CO3)11 · 14H2O Orth.
5.CC.20Shomiokite-(Y)Na3Y[CO3]3 · 3H2OOrth. mm2
5.CC.25Lanthanite-(Ce)Ce2(CO3)3 · 8H2OOrth. mmm(2/m2/m2/m)
5.CC.25Lanthanite-(La)La2(CO3)3 · 8H2OOrth. mmm(2/m2/m2/m)
5.CC.25Lanthanite-(Nd)Nd2(CO3)3 · 8H2OOrth. mmm(2/m2/m2/m)
5.CC.25Calkinsite-(Ce)(Ce,La)2(CO3)3 · 4H2OOrth.
5.CC.30Adamsite-(Y)NaY[CO3]2 · 6H2OTric. 1 : P1
5.CC.35Decrespignyite-(Y)Cu(Y,REE)4(CO3)4(OH)5Cl · 2H2OMon.
5.CC.40Galgenbergite-(Ce)Ca(Ce,La,Nd)2(CO3)4 · H2OTric. 1 : P1
5.CC.45Lecoqite-(Y)Na3Y(CO3)3 · 6H2OHex. 6 : P63

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Mckelveyite-(Y)Hide

References for Mckelveyite-(Y)Hide

Reference List:

Localities for Mckelveyite-(Y)Hide

Showing 14 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Bolivia
 
  • Cochabamba
    • Ayopaya Province
Anthony R. Kampf
Canada
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Grice (1989) +1 other reference
Italy
 
  • Lombardy
    • Sondrio Province
      • Lanzada
        • Mt. Motta
[Mckelveyite-(Y)-2M] Demartin et al. (2008)
Demartin et al. (2008)
Russia
 
  • Murmansk Oblast
Zaitsev et al. (1997) +3 other references
PEKOV et al. (2013)
    • Kolsky District
Sorokhtina et al. (2008)
    • Kukisvumchorr Mt
[World of Stones 95:5-6
        • 252 m level
Pekov (2003)
...
    • Northern Karelia
Zaitsev et al. (2004)
... +1 other reference
USA (TL)
 
  • Wyoming
    • Sweetwater County
Milton et al. (1965)
 
and/or  
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