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Klöchite

A valid IMA mineral species
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About KlöchiteHide

04758560017272471593536.jpg
Klöch, Austria
Formula:
K◻2(Fe2+Fe3+)Zn3[Si12O30]
Colour:
Blue, bright orange
Lustre:
Vitreous
Specific Gravity:
3.007 (Calculated)
Crystal System:
Hexagonal
Member of:
Name:
Named after the type locality, Klöch in Styria, Austria.

Name EncodingHide

ASCII-7:
Klochite

Unique IdentifiersHide

Mindat ID:
35832
Long-form identifier:
mindat:1:1:35832:9

Similar NamesHide

CliachiteA synonym of 'Bauxite'
KochiteA valid IMA mineral speciesNa3Ca2MnZrTi(Si2O7)2OF3

IMA Classification of KlöchiteHide

Approved
IMA Formula:
(Fe2+Fe3+)◻2KZn2+3(Si12O30)
Approval year:
2007
First published:
2011

Classification of KlöchiteHide

9.CM.05

9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si6O18]12- 6-membered double rings (sechser-Doppelringe)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
KlöIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
KloThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of KlöchiteHide

Vitreous
Transparency:
Translucent
Colour:
Blue, bright orange
Cleavage:
None Observed
Density:
3.007 g/cm3 (Calculated)
Comment:
Calculated density is 3.007 g/cm3 (empirical formula), and 3.016 g/cm3 (refined structural formula.

Optical Data of KlöchiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.594(1) nε = 1.950(1)
Max. Birefringence:
δ = 0.356
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Dispersion:
Not determined.
Pleochroism:
Strong
Comments:
ω = dark blue; ε = pale yellow.

Chemistry of KlöchiteHide

Mindat Formula:
K◻2(Fe2+Fe3+)Zn3[Si12O30]
Element Weights:
Element% weight
O41.238 %
Si28.956 %
Zn16.851 %
Fe9.596 %
K3.359 %

Calculated from ideal end-member formula.
O
Si
Zn
Fe
K

Crystallography of KlöchiteHide

Crystal System:
Hexagonal
Class (H-M):
6/mmm(6/m2/m2/m) - Dihexagonal Dipyramidal
Space Group:
P63/mmc
Cell Parameters:
a = 10.120 Å, c = 14.298 Å
Ratio:
a:c = 1 : 1.413
Unit Cell V:
1,268.14 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Hexagonal tabular. Forms include two hexagonal prisms, one hexagonal bipyramid and the basal pinacoid.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.149 Å(100)
5.540 Å(43)
4.130 Å(40)
3.736 Å(70)
3.227 Å(67)
2.920 Å(40)
2.770 Å(68)
2.530 Å(43)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
8 : Mafic igneous rocks

Type Occurrence of KlöchiteHide

General Appearance of Type Material:
Blue, hexagonal tabular crystals flattened on {001}, with a diameter up to 0.3 mm and a maximal thickness of 0.1 mm.
Place of Conservation of Type Material:
Department of Mineralogy of the Universalmuseum Joanneum, Graz, Austria, catalogue number 84.580.
Geological Setting of Type Material:
In a SiO2-rich xenolith from a nepheline basanite quarry.
Associated Minerals at Type Locality:

Synonyms of KlöchiteHide

Other Language Names for KlöchiteHide

Arabic:Klöchite
Dutch:Klöchiet
German:Klöchit

Relationship of Klöchite to other SpeciesHide

Member of:
Other Members of Osumilite Group:
Agakhanovite-(Y)K◻2(YCa)Be3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
AlmaruditeK◻2Mn2+2(Be2Al)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mmm
AluminosugiliteKNa2Al2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
ArmeniteBa(H2O)2Ca2Al3[Al3Si9O30]Orth. mmm(2/m2/m2/m) : Pnna
BerezanskiteK◻2Ti2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
BrannockiteK◻2Sn2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
ChayesiteK◻2Mg2(Mg2Fe3+)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
DarapiositeKNa2Mn2(Zn2Li)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
DusmatoviteK(K◻)Mn2+2Zn3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
EifeliteKNa2(MgNa)Mg3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
FriedrichbeckeiteK(◻Na)Mg2(Be2Mg)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
LaurentthomasiteK◻2Mg2(Be2Al)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
MerrihueiteK(◻Na)Fe2+2Fe2+3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
MilariteK(◻H2O)Ca2(Be2Al)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
OftedaliteK◻2(ScCa)Be3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
OsumiliteK◻2Fe2+2Al3[Al2Si10O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
Osumilite-(Mg)K◻2Mg2Al3[Al2Si10O30] Hex. 6/mmm(6/m2/m2/m) : P6/mcc
PlechoviteCa2[K(H2O)]KBe3Si12O30Hex. 6/mmm(6/m2/m2/m) : P6/mcc
PoudretteiteK◻2Na2B3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
RoedderiteK(◻Na)Mg2Mg3[Si12O30]Hex. 6m2 : P62c
ShibkoviteK(◻K)Ca2Zn3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
SogdianiteK◻2Zr2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
SugiliteKNa2Fe3+2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
Trattnerite◻(◻)2Fe3+2Mg3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
'UM1990-73-SiO:KMnNaZn'K(KNa0.5◻0.5)(Mn1.5Na0.5)Zn3[Si12O30]Hex.
'Unnamed (Mn3+-dominant analog of Sugilite)'KNa2Mn3+2Li3[Si12O30]
YagiiteNa◻2Mg2Al3[Al2Si10O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Klöchite associated with AegirineNaFe3+Si2O6
1 photo of Klöchite associated with FluorapatiteCa5(PO4)3F

Related Minerals - Strunz-mindat GroupingHide

9.CM.AluminosugiliteKNa2Al2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.Agakhanovite-(Y)K◻2(YCa)Be3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.PlechoviteCa2[K(H2O)]KBe3Si12O30Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05FriedrichbeckeiteK(◻Na)Mg2(Be2Mg)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05LaurentthomasiteK◻2Mg2(Be2Al)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05'UM1990-73-SiO:KMnNaZn'K(KNa0.5◻0.5)(Mn1.5Na0.5)Zn3[Si12O30]Hex.
9.CM.05EifeliteKNa2(MgNa)Mg3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05AlmaruditeK◻2Mn2+2(Be2Al)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mmm
9.CM.05ArmeniteBa(H2O)2Ca2Al3[Al3Si9O30]Orth. mmm(2/m2/m2/m) : Pnna
9.CM.05MerrihueiteK(◻Na)Fe2+2Fe2+3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05OftedaliteK◻2(ScCa)Be3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05RoedderiteK(◻Na)Mg2Mg3[Si12O30]Hex. 6m2 : P62c
9.CM.05ShibkoviteK(◻K)Ca2Zn3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05SogdianiteK◻2Zr2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05MilariteK(◻H2O)Ca2(Be2Al)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05BerezanskiteK◻2Ti2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05PoudretteiteK◻2Na2B3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05DarapiositeKNa2Mn2(Zn2Li)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05ChayesiteK◻2Mg2(Mg2Fe3+)[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05Osumilite-(Mg)K◻2Mg2Al3[Al2Si10O30] Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05OsumiliteK◻2Fe2+2Al3[Al2Si10O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05SugiliteKNa2Fe3+2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05Trattnerite◻(◻)2Fe3+2Mg3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05BrannockiteK◻2Sn2Li3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05DusmatoviteK(K◻)Mn2+2Zn3[Si12O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.05YagiiteNa◻2Mg2Al3[Al2Si10O30]Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CM.10FaizieviteK2Na(Ca6Na)Ti4Li6[Si6O18]2[Si12O30]F2Tric. 1 : P1

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 3.3591% 1,041 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity: –

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Fluorescence of KlöchiteHide

Not fluorescent

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KlöchiteHide

References for KlöchiteHide

Localities for KlöchiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria (TL)
 
  • Styria
    • Südoststeiermark District
      • Klöch
Bojar et al. (2011)
Portugal
 
  • Madeira
    • Madeira Island
      • Machico
        • Porto da Cruz
Alves (n.d.)
 
and/or  
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