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Adranosite
A valid IMA mineral species
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About Adranosite
Formula:
(NH4)4NaAl2(SO4)4Cl(OH)2
Colour:
Colorless, white
Lustre:
Vitreous
Specific Gravity:
2.15
Crystal System:
Tetragonal
Name:
After the Greek name of the ancient fire god Adranos (Latin: Adranus) who,according to legend, lived under Mount Etna before being driven out by Hephaestus (Latin: Vulcan). Adranos was worshipped all over Sicily, but particularly in the town of Adranus, now named Adrano.
The Al analogue of Adranosite-(Fe).
Unique combination of elements. One of a few ammonium-sodium sulfates among acmonidesite, adranosite-(Fe), lecontite, möhnite, and therasiasite.
In the crystal structure there are: (1) NaO4Cl2 tetragonal square bipyramids, that have common Cl in corners; (2) AlO6 octahedra and SO4 tetrahedra that join to form spiral chains parallel to [001].
Unique combination of elements. One of a few ammonium-sodium sulfates among acmonidesite, adranosite-(Fe), lecontite, möhnite, and therasiasite.
In the crystal structure there are: (1) NaO4Cl2 tetragonal square bipyramids, that have common Cl in corners; (2) AlO6 octahedra and SO4 tetrahedra that join to form spiral chains parallel to [001].
Unique Identifiers
Mindat ID:
39324
Long-form identifier:
mindat:1:1:39324:3
Similar Names
| Adranosite-(Fe) | A valid IMA mineral species | (NH4)4NaFe23+(SO4)4Cl(OH)2 |
IMA Classification of Adranosite
Classification of Adranosite
7.BC.
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
30.4.5.
30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
4 : Miscellaneous
30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
4 : Miscellaneous
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Arn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Adranosite
Vitreous
Transparency:
Translucent
Colour:
Colorless, white
Streak:
White
Cleavage:
None Observed
Fracture:
None observed
Density:
2.15(1) g/cm3 (Measured) 2.176 g/cm3 (Calculated)
Comment:
Measured by flotation in a tribromo- methane–trichloromethane mixture. Calculated for the empirical formula.
Optical Data of Adranosite
Type:
Uniaxial (-)
RI values:
nω = 1.55(1) nε = 1.54(1)
Max. Birefringence:
δ = 0.010
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic
(convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis
centred and vertical. The coloured rings are isochromatics, computed with the
same physics as the Michel-Lévy bar above; the dark cross is the isogyre.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Chemistry of Adranosite
Mindat Formula:
(NH4)4NaAl2(SO4)4Cl(OH)2
Element Weights:
Common Impurities:
K
Crystallography of Adranosite
Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Space Group:
I41/acd
Cell Parameters:
a = 18.118(3) Å, c = 11.320(3) Å
Ratio:
a:c = 1 : 0.625
Unit Cell V:
3,715.92 ų (Calculated from Unit Cell)
Morphology:
Acicular crystals with pointed terminations. The most common forms are {100}, {110}, and {111}.
Twinning:
None observed.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0006333 | Adranosite | Demartin F, Gramaccioli C M, Campostrini I (2010) Adranosite, (NH4)4NaAl2(SO4)4Cl(OH)2, a new ammonium sulfate chloride from La Fossa Crater, Vulcano, Aeolian Islands, Italy The Canadian Mineralogist 48 315-321 | 2010 | La Fossa Crater, Vulcano, Aeolian Islands, Italy | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 6.398 Å | (80) |
| 4.530 Å | (86) |
| 3.202 Å | (47) |
| 3.020 Å | (65) |
| 2.980 Å | (100) |
| 2.739 Å | (36) |
| 2.265 Å | (87) |
| 1.902 Å | (44) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 45a : [Sulfates, arsenates, selenates, antimonates] | |
| 45b : [Other oxidized fumarolic minerals] | |
| Stage 10b: Anthropogenic minerals | <10 Ka |
| 55 : Anthropogenic mine minerals |
Type Occurrence of Adranosite
General Appearance of Type Material:
Colorless to white sprays of prismatic crystals up to 0.3 mm in length.
Place of Conservation of Type Material:
University of Milan, Italy (#2008-06).
Geological Setting of Type Material:
In an active medium-temperature (~250°C) intracrater fumarole on pyroclastic breccia.
Associated Minerals at Type Locality:
Synonyms of Adranosite
Other Language Names for Adranosite
Common Associates
Associations Based on Photo Data:
| 3 photos of Adranosite associated with Brontesite | (NH4)3PbCl5 |
| 3 photos of Adranosite associated with Alunite | KAl3(SO4)2(OH)6 |
| 3 photos of Adranosite associated with D'Ansite-(Fe) | Na21Fe2+(SO4)10Cl3 |
| 2 photos of Adranosite associated with Realgar | As4S4 |
| 1 photo of Adranosite associated with Russoite | (NH4)ClAs2O3(H2O)0.5 |
| 1 photo of Adranosite associated with Argesite | (NH4)7Bi3Cl16 |
| 1 photo of Adranosite associated with Huizingite-(Al) | [(NH4)9(SO4)2][(Al,Fe3+)3(OH)2(H2O)4(SO4)6] |
| 1 photo of Adranosite associated with Demicheleite-(I) | BiSI |
| 1 photo of Adranosite associated with Lucabindiite | (K,NH4)As4O6(Cl,Br) |
| 1 photo of Adranosite associated with Metaborite | HBO2 |
Related Minerals - Strunz-mindat Grouping
| 7.BC. | Viskontite | Pb5Cu2(SO4)3(SeO3)(OH)6 |
| 7.BC. | Zincochenite | Pb4Zn(SO4)2(OH)6 |
| 7.BC. | D'Ansite-(Mn) | Na21Mn2+(SO4)10Cl3 |
| 7.BC. | D'Ansite-(Fe) | Na21Fe2+(SO4)10Cl3 |
| 7.BC. | Acmonidesite | (NH4,K,Pb)8NaFe2+4(SO4)5Cl8 |
| 7.BC. | Chromviskontite | Pb5Cu2(CrO4)3(SeO3)(OH)6 |
| 7.BC. | Backite | Pb2AlTeO6Cl |
| 7.BC. | Adranosite-(Fe) | (NH4)4NaFe3+2(SO4)4Cl(OH)2 |
| 7.BC. | Agaite | Pb3CuTeO5(OH)2(CO3) |
| 7.BC. | Wildcatite | CaFe3+Te6+O5(OH) |
| 7.BC. | Hagstromite | Pb8Cu2+(Te6+O6)2(CO3)Cl4 |
| 7.BC.05 | D'Ansite | Na21Mg(SO4)10Cl3 |
| 7.BC.07 | 'Apatelite' | Fe3(SO4)2(OH)5 · 0.5H2O |
| 7.BC.07 | 'Unnamed (Ba-Fe Vanadate)' | Ba, Fe, V, O, H |
| 7.BC.10 | Jarosite | KFe3+3(SO4)2(OH)6 |
| 7.BC.10 | Dorallcharite | TlFe3+3(SO4)2(OH)6 |
| 7.BC.10 | Argentojarosite | AgFe3+3(SO4)2(OH)6 |
| 7.BC.10 | Natroalunite | NaAl3(SO4)2(OH)6 |
| 7.BC.10 | Natrojarosite | NaFe3(SO4)2(OH)6 |
| 7.BC.10 | Beaverite-(Cu) | Pb(Fe3+2Cu)(SO4)2(OH)6 |
| 7.BC.10 | Beaverite-(Zn) | Pb(Fe3+2Zn)(SO4)2(OH)6 |
| 7.BC.10 | Walthierite | Ba0.5Al3(SO4)2(OH)6 |
| 7.BC.10 | Huangite | Ca0.5Al3(SO4)2(OH)6 |
| 7.BC.10 | 'Natroalunite-2c' | (Na,Ca0.5,K)Al3(SO4)2(OH)6 |
| 7.BC.10 | Alunite | KAl3(SO4)2(OH)6 |
| 7.BC.10 | Plumbojarosite | Pb0.5Fe3+3(SO4)2(OH)6 |
| 7.BC.10 | Karlseifertite | Pb(Ga2Ge)(AsO4)2(OH)6 |
| 7.BC.10 | Hydroniumjarosite | (H3O)Fe3+3(SO4)2(OH)6 |
| 7.BC.10 | Ammonioalunite | (NH4)Al3(SO4)2(OH)6 |
| 7.BC.10 | Ammoniojarosite | (NH4)Fe3+3(SO4)2(OH)6 |
| 7.BC.10 | Osarizawaite | Pb(Al2Cu2+)(SO4)2(OH)6 |
| 7.BC.10 | Schlossmacherite | (H3O)Al3(SO4)2(OH)6 |
| 7.BC.15 | Ye'elimite | Ca4Al6(SO4)O12 |
| 7.BC.20 | Nabokoite | KCu7(SO4)5(Te4+O3)OCl |
| 7.BC.20 | Puninite | Na2Cu3O(SO4)3 |
| 7.BC.20 | Atlasovite | K(BiO)Cu6Fe3+(SO4)5O3Cl |
| 7.BC.25 | Chlorothionite | K2Cu(SO4)Cl2 |
| 7.BC.30 | Euchlorine | KNaCu3(SO4)3O |
| 7.BC.30 | Fedotovite | K2Cu3(SO4)3O |
| 7.BC.35 | Kamchatkite | KCu3(SO4)2OCl |
| 7.BC.40 | Piypite | K4Cu4O2(SO4)4 · (Na,Cu)Cl |
| 7.BC.45 | Alumoklyuchevskite | K3Cu3(Al,Fe3+)(SO4)4O2 |
| 7.BC.45 | Belousovite | KZn(SO4)Cl |
| 7.BC.45 | Klyuchevskite | K3Cu3(Fe3+,Al)(SO4)4O2 |
| 7.BC.47 | Müllerite | Pb2Fe3+(Te6+O6)Cl |
| 7.BC.50 | Caledonite | Pb5Cu2(SO4)3(CO3)(OH)6 |
| 7.BC.50 | Elasmochloite | Na3Cu6BiO4(SO4)5 |
| 7.BC.52 | Eleomelanite | (K2Pb)Cu4O2(SO4)4 |
| 7.BC.55 | Falgarite | K4(VO)3(SO4)5 |
| 7.BC.55 | Wherryite | Pb7Cu2(SO4)4(SiO4)2(OH)2 |
| 7.BC.57 | Krasheninnikovite | KNa2CaMg(SO4)3F |
| 7.BC.60 | Wulffite | K3NaCu4O2(SO4)4 |
| 7.BC.60 | Parawulffite | K5Na3Cu8O4(SO4)8 |
| 7.BC.60 | Mammothite | Pb6Cu4AlSb5+O2(OH)16Cl4(SO4)2 |
| 7.BC.62 | Shuvalovite | K2(Ca2Na)(SO4)3F |
| 7.BC.65 | Saccoite | Ca2Mn3+2F(OH)8 · 0.5(SO4) |
| 7.BC.65 | Linarite | PbCu(SO4)(OH)2 |
| 7.BC.65 | Therasiaite | (NH4)3KNa2Fe2+Fe3+(SO4)3Cl5 |
| 7.BC.65 | Franksousaite | PbCu(Se6+O4)(OH)2 |
| 7.BC.65 | Munakataite | Pb2Cu2(Se4+O3)(SO4)(OH)4 |
| 7.BC.65 | Schmiederite | Pb2Cu2(Se6+O4)(Se4+O3)(OH)4 |
| 7.BC.70 | Chenite | Pb4Cu(SO4)2(OH)6 |
| 7.BC.75 | Krivovichevite | Pb3Al(OH)6(SO4)(OH) |
| 7.BC.80 | Anhydrokainite | KMg(SO4)Cl |
Fluorescence of Adranosite
Not fluorescent.
Other Information
Notes:
The mineral is not hygroscopic and is stable in open air.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Adranosite
mindat.org URL:
https://www.mindat.org/min-39324.html
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References for Adranosite
Localities for Adranosite
Showing 5 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Germany | |
| Witzke et al. (2015) |
Hungary | |
| Szabó et al. (2015) |
Italy | |
| Russo et al. (2017) |
| Demartin et al. (2010) |
USA | |
| R. Peter Richards Collection |
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La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy