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Tunellite

A valid IMA mineral species
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About TunelliteHide

06134490017271927364624.jpg
George G. Tunell, Jr.
Formula:
SrB6O9(OH)2 · 3H2O
Colour:
Colourless, grayish white
Lustre:
Sub-Vitreous, Pearly
Hardness:
2½
Specific Gravity:
2.40
Crystal System:
Monoclinic
Name:
Named by R.C. Erd, V. Morgan, and J.R. Clark in 1961 in honor of George Gerard Tunell, Jr. (4 April 1900, Chicago, Illinois, USA - 4 July 1996, Montecito, California, USA), professor of geochemistry, University of California. President of the Mineralogical Society of America (1950) and Roebling Medal recipient in 1973. He made major advances in X-ray crystallography, physical chemistry, and thermodynamic analysis of minerals, especially metallic ores. The name is pronounced tŭn nĕl' īt.
This page provides mineralogical data about Tunellite.


Unique IdentifiersHide

Mindat ID:
4050
Long-form identifier:
mindat:1:1:4050:7

Similar NamesHide

TanoliteA synonym of Cordierite
TonaliteA rock classification type

IMA Classification of TunelliteHide

Approved
IMA Formula:
SrB6O9(OH)2·3H2O
First published:
1961

Classification of TunelliteHide

6.FC.05

6 : BORATES
F : Hexaborates
C : Phyllo-hexaborates
26.6.6.2

26 : HYDRATED BORATES CONTAINING HYDROXYL OR HALOGEN
6 : Hexaborates
9.3.31

9 : Borates
3 : Borates of Ca and Sr

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
TnlIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TunelliteHide

Sub-Vitreous, Pearly
Transparency:
Transparent
Comment:
Pearly on cleavages
Colour:
Colourless, grayish white
Streak:
White
Hardness:
2½ on Mohs scale
Tenacity:
Flexible
Cleavage:
Perfect
Perfect on {100}
Distinct on {001}
Density:
2.40(1) g/cm3 (Measured)    2.391 g/cm3 (Calculated)

Optical Data of TunelliteHide

Type:
Biaxial (+)
RI values:
nα = 1.519 nβ = 1.534 nγ = 1.569
2V:
Calculated: 68°
Max. Birefringence:
δ = 0.050
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v weak
Optical Extinction:
Y = b; X ∧ a = 29°; Z ∧ c = –5°.

Chemistry of TunelliteHide

Mindat Formula:
SrB6O9(OH)2 · 3H2O
Element Weights:
Element% weight
O58.249 %
Sr22.786 %
B16.868 %
H2.097 %

Calculated from ideal end-member formula.
O
Sr
B
H

Crystallography of TunelliteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/c
Cell Parameters:
a = 14.415(3) Å, b = 8.213(1) Å, c = 9.951(2) Å
β = 114.05°
Ratio:
a:b:c = 1.755 : 1 : 1.212
Unit Cell V:
1,075.83 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystals to 10 cm elongated on [001]. Flattened tabular with dominant {100}. Compact fine grained nodules. Forms include {100}, {001}, {110}, {011}, and {111}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000129TunelliteClark J R (1964) The crystal structure of tunellite, SrB6O9(OH)2.3H2O American Mineralogist 49 1549-15681964Jenifer mine, Kramer borate district, California, USA0293
0018902TunelliteClark J R (1963) Boron-oxygen polyanion in the crystal structure of tunellite Science 141 1178-11791963Jenifer mine, Kramer borate district, California, USA0293
0005416TunelliteBurns P C, Hawthorne F C (1994) Hydrogen bonding in tunellite The Canadian Mineralogist 32 895-90219940293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Loading XRD data...
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
6.57 Å(100)
4.525 Å(11)
3.867 Å(9)
5.138 Å(8)
3.592 Å(8)
2.503 Å(8)
6.78 Å(7)
Comments:
Furnace Creek district, California, USA.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)
Geological Setting:
Secondary mineral in borate deposits

Type Occurrence of TunelliteHide

General Appearance of Type Material:
White compact fine-grained nodules. Also as individual long prismatic crystals up to 1.5 cm in length and equant crystals up to 1 cm in diameter.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, number 123928.
Geological Setting of Type Material:
A secondary mineral in a borate deposit.
Associated Minerals at Type Locality:

Other Language Names for TunelliteHide

Dutch:Tunelliet
German:Tunellit
Simplified Chinese:四水锶硼石
Spanish:Tunellita

Common AssociatesHide

Associations Based on Photo Data:
28 photos of Tunellite associated with UlexiteNaCa[B5O6(OH)6] · 5H2O
8 photos of Tunellite associated with HydroboraciteCaMg[B3O4(OH)3]2 · 3H2O
3 photos of Tunellite associated with ColemaniteCa[B3O4(OH)3] · H2O
3 photos of Tunellite associated with InderiteMgB3O3(OH)5 · 5H2O
1 photo of Tunellite associated with PararealgarAs4S4

Related Minerals - Strunz-mindat GroupingHide

6.FC.05NobleiteCaB6O9(OH)2 · 3H2OMon. 2/m
6.FC.10StrontioboriteSr[B8O11(OH)4]Mon. 2 : P21
6.FC.15StrontioginoriteCaSrB14O20(OH)6 · 5H2OMon. 2/m : P21/c
6.FC.15GinoriteCa2B14O20(OH)6 · 5H2OMon. 2/m : P21/c
6.FC.20FabianiteCaB3O5(OH)Mon. 2/m : P21/c

Other InformationHide

Notes:
Soluble in cold dilute acid or strong alkaline solutions. Unaffected by glycerol or methanol. In H2SO4, a coating of SrSO4 inhibits further dissolution.

Heated in a closed tube, tunellite exfoliates perpendicular to the cleavage, turns silvery white (resembling muscovite), then turns chalky white. The water driven off has a pH of 4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TunelliteHide

References for TunelliteHide

Localities for TunelliteHide

Showing 15 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Turkey
 
  • Balikesir Province
    • Bigadiç District
Helvaci et al. (1991)
Helvaci +2 other references
Helvaci et al. (1991)
Helvaci et al. (1991)
  • Eskişehir Province
    • Seyitgazi District
      • Kirka
Baysal (1972) +1 other reference
  • Kütahya Province
    • Emet District
      • Doğanlar village
García-Veigas et al. (2010) +1 other reference
      • Emet Borate deposit
American Mineralogist +4 other references
USA
 
  • California
    • Inyo County
Erd et al. (1961) +1 other reference
      • Furnace Creek Mining District (Furnace Creek Borate Mining District)
        • Ryan
Collected it in the mine-Rock Currier +3 other references
    • Kern County
www.mineralsocal.org (1999)
U.S. Borax
Erd et al. (1961) +4 other references
Erd et al. (1961) +2 other references
    • San Bernardino County
      • East Kramer Mining District
Morgan et al. (1969) +2 other references
USGS
 
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