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Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia i
Regional Level Types
Crven Dol Group of Ore Bodies
Allchar Deposit
Ržanovo Selo
Kavadarci Municipality Municipality
North Macedonia Country

Regional Level Types
Crven Dol	Group of Ore Bodies
Allchar	Deposit
Ržanovo	Selo
Kavadarci Municipality	Municipality
North Macedonia	Country

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Collapsed adit 21

Adit No. 21, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Inside the adit

Adit No. 21, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Lorándite, etc.

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Collapsed adit 21

Adit No. 21, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Inside the adit

Adit No. 21, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Lorándite, etc.

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Collapsed adit 21

Adit No. 21, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Inside the adit

Adit No. 21, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Latitude & Longitude (WGS84):

41° 9' 34'' North , 21° 57' 10'' East

Latitude & Longitude (decimal):

41.15963,21.95288

GRN:

N28E12

Type:

Group of Ore Bodies

Köppen climate type:

Cfb : Temperate oceanic climate

Nearest Settlements:

Place	Population	Distance
Rožden	188 (2015)	3.1km
Vitolište	456 (2015)	10.8km
Polčište	193 (2015)	10.9km
Konopište	327 (2015)	14.2km
Bešište	238 (2015)	14.5km

Mindat Locality ID:

2246

Long-form identifier:

mindat:1:2:2246:3

GUID (UUID V4):

Northern, As- and Tl-rich part of the Allchar deposit. Also known as the "Crven Dol orebody" or, incorrectly, the "Crven Dol mine" (there is no single mine).

Several (mainly collapsed) adits (nos. 21, 25, and others) and old, overgrown dumps. The ore zone is 3 km long and 200 - 300 m wide.

Note on the locality name: "Crven Dol" means red valley/gorge. GPS coordinates are centred on the general area.

Note on the mineral list: Ðorđević et al. (2020) also mention unspecified Ca-Fe-, Ca-Mn-, and Ca-Mg-arsenates.

Steinfeld et al. (2021) mention several new Tl-M(II)-arsenates (M = Ca, Mg, and/or Mn).

Select Mineral List Type

Standard Detailed Gallery Strunz Chemical Elements

Mineral List

Mineral list contains entries from the region specified including sub-localities

ⓘ Hydroniumpharmacosiderite

ⓘ Jankovićite (TL)

ⓘ Jarosite

ⓘ 'Kaolinite Subgroup'

ⓘ Manganlotharmeyerite ?

ⓘ Natropharmacosiderite

ⓘ Thalliumpharmacosiderite (TL)

ⓘ 'UM1994-01-AsO:FeHSTl'

ⓘ 'Unnamed (Tl Arsenate I)'

ⓘ 'Unnamed (Tl Arsenate II)'

ⓘ 'Unnamed (Tl(I) Oxide)'

ⓘ Vrbaite

ⓘ Wallkilldellite ?

48 valid minerals. 2 (TL) - type locality of valid minerals.

Rock Types Recorded

Rock list contains entries from the region specified including sub-localities

Select Rock List Type

Alphabetical List Tree Diagram

ⓘ Dolostone

ⓘ Limestone

Detailed Mineral List:

ⓘ Ankerite

Formula: Ca(Fe²⁺,Mg)(CO₃)₂

References:

Balić Žunić, T., Stafilov, T. & Tibljaš, D. (1993): Distribution of thallium and the ore genesis at the Crven Dol locality in Alšar. Geologica Macedonica, 7, 45-52.

ⓘ Arseniosiderite

Formula: Ca₂Fe³⁺₃(AsO₄)₃O₂ · 3H₂O

References:

Đorđević, Tamara, Drahota, Petr, Kolitsch, Uwe, Majzlan, Juraj, Peřestá, Magdaléna, Kiefer, Stefan, Stöger-Pollach, Michael, Tepe, Nathalie, Hofmann, Thilo, Mikuš, Tomáš, et al. (2021) Synergetic Tl and As retention in secondary minerals: An example of extreme arsenic and thallium pollution. Applied Geochemistry, 135. 105114 doi:10.1016/j.apgeochem.2021.105114

ⓘ Bernardite

Formula: TlAs₅S₈

References:

Färber, Gunnar (n.d.) Personal Communication, Gunnar Färber Mineralien.

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ 'Biotite'

Formula: K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Calcite

Formula: CaCO₃

References:

Ðorđević, T., Kolitsch, U., Drahota, P., Knappová, M., Majzlan, J., Kiefer, S., Mikuš, T., Serafimovski, T., Tasev, G., Boev, I. and Boev, B. (2020): Thallium mobility in mining wastes at the Crven Dol locality, Allchar deposit, North Macedonia. EGU General Assembly 2020, Vienna, Austria, May 3-8, Geophysical Research Abstracts 22, EGU2012-4959.

ⓘ Christite

Formula: TlHgAsS₃

Locality: Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

References:

Ðorđević, T., Kolitsch, U., Drahota, P., Peřestá, M., Majzlan, J., Kiefer, S., Tasev, G., Serafimovski, T., Boev, I. and Boev, B. (2020): Mobility of Tl and Hg in the As-rich waste dumps of adit no. 25, former Allchar mine, North Macedonia. Goldschmidt Virtual 2020, June 21-26, 2020, Goldschmidt Abstracts, 2020, 606, https://goldschmidtabstracts.info/2020/606.pdf.

ⓘ Cinnabar

Formula: HgS

Localities:

Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Claudetite

Formula: As₂O₃

References:

Färber, Gunnar (n.d.) Personal Communication, Gunnar Färber Mineralien.

ⓘ Dolomite

Formula: CaMg(CO₃)₂

Localities:

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Dorallcharite

Formula: TlFe³⁺₃(SO₄)₂(OH)₆

Localities:

Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Fangite

Formula: Tl₃AsS₄

Localities:

Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Fibroferrite

Formula: Fe³⁺(SO₄)(OH) · 5H₂O

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Goethite

Formula: Fe³⁺O(OH)

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Gypsum

Formula: CaSO₄ · 2H₂O

Localities:

Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Hörnesite

Formula: Mg₃(AsO₄)₂ · 8H₂O

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Hydroniumjarosite

Formula: (H₃O)Fe³⁺₃(SO₄)₂(OH)₆

References:

ⓘ Hydroniumpharmacosiderite

Formula: (H₃O)Fe³⁺₄(AsO₄)₃(OH)₄ · 4H₂O

References:

ⓘ Jankovićite (TL)

Formula: Tl₅Sb₉(As,Sb)₄S₂₂

Type Locality:

References:

Cvetković, Lj., Boronikhin, V. A., Pavićević, M. K., Krajnović, D., Gržetić, I., Libowitzky, E., Giester, G., Tillmanns, E. (1995) Jankovićite, Tl5Sb9(As,Sb)4S22, a new TI-sulfosalt from Allchar, Macedonia. Mineralogy and Petrology, 53 (1) 125-131 doi:10.1007/bf01171951

Mandarino, Joseph A. (1996) Abstracts of New Mineral Descriptions. The Mineralogical Record, 27 (4) 301-306pp.302-302

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Jarosite

Formula: KFe³⁺₃(SO₄)₂(OH)₆

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ 'Kaolinite Subgroup'

Formula: Al₂Si₂O₅(OH)₄

Localities:

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Lafossaite

Formula: Tl(Cl,Br)

References:

Stephen WolfsriedIdentification: Dealer/Collection Label

ⓘ 'Limonite'

References:

ⓘ Lorándite

Formula: TlAsS₂

Localities:

Adit No. 21, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ 'Manganese Oxides'

Localities:

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Manganlotharmeyerite ?

Formula: CaMn³⁺₂(AsO₄)₂(OH)₂

References:

ⓘ Marcasite

Formula: FeS₂

References:

Naturwissenschaften Volume 75, Number 1, 37-39

American Mineralogist 74:1401

Balić Žunić, T., Stafilov, T. & Tibljaš, D. (1993): Distribution of thallium and the ore genesis at the Crven Dol locality in Alšar. Geologica Macedonica, 7, 45-52.

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Muscovite

Formula: KAl₂(AlSi₃O₁₀)(OH)₂

References:

ⓘ Native Gold

Formula: Au

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Native Gold var. Electrum

Formula: (Au,Ag)

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Native Silver

Formula: Ag

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Natropharmacosiderite

Formula: NaFe³⁺₄(AsO₄)₃(OH)₄ · 4H₂O

References:

ⓘ Orpiment

Formula: As₂S₃

Localities:

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Parapierrotite

Formula: TlSb₅S₈

References:

Färber, Gunnar (n.d.) Personal Communication, Gunnar Färber Mineralien.

ⓘ Pharmacosiderite

Formula: KFe³⁺₄(AsO₄)₃(OH)₄ · 6-7H₂O

References:

Balić Žunić, T., Stafilov, T. & Tibljaš, D. (1993): Distribution of thallium and the ore genesis at the Crven Dol locality in Alšar. Geologica Macedonica, 7, 45-52.

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Picotpaulite

Formula: TlFe₂S₃

References:

Pavićević, M. K. (1988). Lorandite from Allchar—A low energy solar neutrino dosimeter. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 271(2), 287-296.

ⓘ Picropharmacolite

Formula: Ca₄Mg(AsO₄)₂(HAsO₄)₂ · 11H₂O

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Plagionite

Formula: Pb₅Sb₈S₁₇

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Pyrite

Formula: FeS₂

References:

Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment Volume 271, Issue 2, 15 August 1988, Pages 297-300

Naturwissenschaften Volume 75, Number 1, 37-39

American Mineralogist 74:1401

Balić Žunić, T., Stafilov, T. & Tibljaš, D. (1993): Distribution of thallium and the ore genesis at the Crven Dol locality in Alšar. Geologica Macedonica, 7, 45-52.

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Pyrrhotite

Formula: Fe_1-xS

References:

ⓘ Quartz

Formula: SiO₂

Localities:

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Raguinite

Formula: TlFeS₂

Localities:

Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Realgar

Formula: As₄S₄

Localities:

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Rebulite

Formula: Tl₅Sb₅As₈S₂₂

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Sanidine

Formula: K(AlSi₃O₈)

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Scorodite

Formula: Fe³⁺AsO₄ · 2H₂O

Localities:

Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Siderite

Formula: FeCO₃

References:

Balić Žunić, T., Stafilov, T. & Tibljaš, D. (1993): Distribution of thallium and the ore genesis at the Crven Dol locality in Alšar. Geologica Macedonica, 7, 45-52.

ⓘ Simonite

Formula: TlHgAs₃S₆

Locality: Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

References:

ⓘ Starkeyite

Formula: MgSO₄ · 4H₂O

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Stibnite

Formula: Sb₂S₃

References:

Boev, I., & Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Depost in the Republic of Macedonia. Natural Resources and Technology, 9(9), 59-76.

ⓘ Talmessite

Formula: Ca₂Mg(AsO₄)₂ · 2H₂O

References:

ⓘ Thalliumpharmacosiderite (TL)

Formula: TlFe³⁺₄[(AsO₄)₃(OH)₄] · 4H₂O

Localities:

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Type Locality: Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ 'UM1994-01-AsO:FeHSTl'

Formula: Fe₂TlAs₃O₁₂ · 4H₂O

References:

Frantz, E., Palme, H., Todt, W., El Goresy, A., Pavicevic, M. (1994) Geochemistry of Tl-As minerals and host rocks at Allchar (FYR Macedonia). Neues Jahrb. Mineral. Abh.: 167: 359-399.

Jambor, J.L., Roberts, A.C. (1995) New mineral names. American Mineralogist: 80: 1073-1077.p.1076

ⓘ 'Unnamed (Tl Arsenate I)'

Formula: Tl, As, O, H(?)

References:

ⓘ 'Unnamed (Tl Arsenate II)'

Formula: Tl, As, O, H(?)

References:

ⓘ 'Unnamed (Tl(I) Oxide)'

Formula: Tl₂O

References:

ⓘ Vrbaite

Formula: Hg₃Tl₄As₈Sb₂S₂₀

Localities:

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia
Adit No. 25, Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

ⓘ Wallkilldellite ?

Formula: Ca₂Mn²⁺₃(AsO₄)₂(OH)₄ · 9H₂O

References:

Gallery:

Tl₃AsS₄ⓘ Fangite

Fangite, etc.

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Fangite, etc.

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

Fangite, etc.

Crven Dol, Allchar, Ržanovo, Kavadarci Municipality, North Macedonia

List of minerals arranged by Strunz 10th Edition classification

Group 1 - Elements
ⓘ	Native Gold var. Electrum	1.AA.05	(Au,Ag)
ⓘ		1.AA.05	Au
ⓘ	Native Silver	1.AA.05	Ag
Group 2 - Sulphides and Sulfosalts
ⓘ	Picotpaulite	2.CB.60	TlFe₂S₃
ⓘ	Raguinite	2.CB.60	TlFeS₂
ⓘ	Pyrrhotite	2.CC.10	Fe_1-xS
ⓘ	Cinnabar	2.CD.15a	HgS
ⓘ	Stibnite	2.DB.05	Sb₂S₃
ⓘ	Pyrite	2.EB.05a	FeS₂
ⓘ	Marcasite	2.EB.10a	FeS₂
ⓘ	Realgar	2.FA.15a	As₄S₄
ⓘ	Orpiment	2.FA.30	As₂S₃
ⓘ	Simonite	2.GC.20	TlHgAs₃S₆
ⓘ	Parapierrotite	2.HC.05f	TlSb₅S₈
ⓘ	Plagionite	2.HC.10b	Pb₅Sb₈S₁₇
ⓘ	Lorándite	2.HD.05	TlAsS₂
ⓘ	Christite	2.HD.15	TlHgAsS₃
ⓘ	Jankovićite (TL)	2.HD.20	Tl₅Sb₉(As,Sb)₄S₂₂
ⓘ	Rebulite	2.HD.25	Tl₅Sb₅As₈S₂₂
ⓘ	Bernardite	2.HD.50	TlAs₅S₈
ⓘ	Vrbaite	2.HF.20	Hg₃Tl₄As₈Sb₂S₂₀
ⓘ	Fangite	2.KA.15	Tl₃AsS₄
Group 3 - Halides
ⓘ	Lafossaite	3.AA.25	Tl(Cl,Br)
Group 4 - Oxides and Hydroxides
ⓘ	Quartz	4.00.05	SiO₂
ⓘ	Claudetite	4.CB.45	As₂O₃
ⓘ	Goethite	4.FD.10	Fe³⁺O(OH)
Group 5 - Nitrates and Carbonates
ⓘ	Calcite	5.AB.05	CaCO₃
ⓘ	Siderite	5.AB.05	FeCO₃
ⓘ	Ankerite	5.AB.10	Ca(Fe²⁺,Mg)(CO₃)₂
ⓘ	Dolomite	5.AB.10	CaMg(CO₃)₂
Group 7 - Sulphates, Chromates, Molybdates and Tungstates
ⓘ	Dorallcharite	7.BC.10	TlFe³⁺₃(SO₄)₂(OH)₆
ⓘ	Hydroniumjarosite	7.BC.10	(H₃O)Fe³⁺₃(SO₄)₂(OH)₆
ⓘ	Jarosite	7.BC.10	KFe³⁺₃(SO₄)₂(OH)₆
ⓘ	Starkeyite	7.CB.15	MgSO₄ · 4H₂O
ⓘ	Gypsum	7.CD.40	CaSO₄ · 2H₂O
ⓘ	Fibroferrite	7.DC.15	Fe³⁺(SO₄)(OH) · 5H₂O
Group 8 - Phosphates, Arsenates and Vanadates
ⓘ	Scorodite	8.CD.10	Fe³⁺AsO₄ · 2H₂O
ⓘ	Hörnesite	8.CE.40	Mg₃(AsO₄)₂ · 8H₂O
ⓘ	Talmessite	8.CG.05	Ca₂Mg(AsO₄)₂ · 2H₂O
ⓘ	Manganlotharmeyerite ?	8.CG.15	CaMn³⁺₂(AsO₄)₂(OH)₂
ⓘ	Picropharmacolite	8.CH.15	Ca₄Mg(AsO₄)₂(HAsO₄)₂ · 11H₂O
ⓘ	Arseniosiderite	8.DH.30	Ca₂Fe³⁺₃(AsO₄)₃O₂ · 3H₂O
ⓘ	Pharmacosiderite	8.DK.10	KFe³⁺₄(AsO₄)₃(OH)₄ · 6-7H₂O
ⓘ	Natropharmacosiderite	8.DK.10	NaFe³⁺₄(AsO₄)₃(OH)₄ · 4H₂O
ⓘ	Hydroniumpharmacosiderite	8.DK.10	(H₃O)Fe³⁺₄(AsO₄)₃(OH)₄ · 4H₂O
ⓘ	Thalliumpharmacosiderite (TL)	8.DK.10	TlFe³⁺₄[(AsO₄)₃(OH)₄] · 4H₂O
ⓘ	Wallkilldellite ?	8.DL.20	Ca₂Mn²⁺₃(AsO₄)₂(OH)₄ · 9H₂O
Group 9 - Silicates
ⓘ	Muscovite	9.EC.15	KAl₂(AlSi₃O₁₀)(OH)₂
ⓘ	Sanidine	9.FA.30	K(AlSi₃O₈)
Unclassified
ⓘ	'Biotite'	-	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
ⓘ	'Limonite'	-
ⓘ	'Manganese Oxides'	-
ⓘ	'Kaolinite Subgroup'	-	Al₂Si₂O₅(OH)₄
ⓘ	'Unnamed (Tl(I) Oxide)'	-	Tl₂O
ⓘ	'UM1994-01-AsO:FeHSTl'	-	Fe₂TlAs₃O₁₂ · 4H₂O
ⓘ	'Unnamed (Tl Arsenate I)'	-	Tl, As, O, H(?)
ⓘ	'Unnamed (Tl Arsenate II)'	-	Tl, As, O, H(?)

List of minerals for each chemical element

H	Hydrogen
H	ⓘ Arseniosiderite	Ca₂Fe₃³⁺(AsO₄)₃O₂ · 3H₂O
H	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
H	ⓘ Dorallcharite	TlFe₃³⁺(SO₄)₂(OH)₆
H	ⓘ Fibroferrite	Fe³⁺(SO₄)(OH) · 5H₂O
H	ⓘ Goethite	Fe³⁺O(OH)
H	ⓘ Gypsum	CaSO₄ · 2H₂O
H	ⓘ Hörnesite	Mg₃(AsO₄)₂ · 8H₂O
H	ⓘ Hydroniumjarosite	(H₃O)Fe₃³⁺(SO₄)₂(OH)₆
H	ⓘ Jarosite	KFe₃³⁺(SO₄)₂(OH)₆
H	ⓘ Muscovite	KAl₂(AlSi₃O₁₀)(OH)₂
H	ⓘ Pharmacosiderite	KFe₄³⁺(AsO₄)₃(OH)₄ · 6-7H₂O
H	ⓘ Picropharmacolite	Ca₄Mg(AsO₄)₂(HAsO₄)₂ · 11H₂O
H	ⓘ Scorodite	Fe³⁺AsO₄ · 2H₂O
H	ⓘ Natropharmacosiderite	NaFe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
H	ⓘ Starkeyite	MgSO₄ · 4H₂O
H	ⓘ Talmessite	Ca₂Mg(AsO₄)₂ · 2H₂O
H	ⓘ Wallkilldellite	Ca₂Mn₃²⁺(AsO₄)₂(OH)₄ · 9H₂O
H	ⓘ Manganlotharmeyerite	CaMn₂³⁺(AsO₄)₂(OH)₂
H	ⓘ Hydroniumpharmacosiderite	(H₃O)Fe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
H	ⓘ Kaolinite Subgroup	Al₂Si₂O₅(OH)₄
H	ⓘ Thalliumpharmacosiderite	TlFe₄³⁺[(AsO₄)₃(OH)₄] · 4H₂O
H	ⓘ UM1994-01-AsO:FeHSTl	Fe₂TlAs₃O₁₂ · 4H₂O
H	ⓘ Unnamed (Tl Arsenate I)	Tl, As, O, H(?)
H	ⓘ Unnamed (Tl Arsenate II)	Tl, As, O, H(?)
C	Carbon
C	ⓘ Ankerite	Ca(Fe²⁺,Mg)(CO₃)₂
C	ⓘ Calcite	CaCO₃
C	ⓘ Dolomite	CaMg(CO₃)₂
C	ⓘ Siderite	FeCO₃
O	Oxygen
O	ⓘ Ankerite	Ca(Fe²⁺,Mg)(CO₃)₂
O	ⓘ Arseniosiderite	Ca₂Fe₃³⁺(AsO₄)₃O₂ · 3H₂O
O	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
O	ⓘ Calcite	CaCO₃
O	ⓘ Claudetite	As₂O₃
O	ⓘ Dolomite	CaMg(CO₃)₂
O	ⓘ Dorallcharite	TlFe₃³⁺(SO₄)₂(OH)₆
O	ⓘ Fibroferrite	Fe³⁺(SO₄)(OH) · 5H₂O
O	ⓘ Goethite	Fe³⁺O(OH)
O	ⓘ Gypsum	CaSO₄ · 2H₂O
O	ⓘ Hörnesite	Mg₃(AsO₄)₂ · 8H₂O
O	ⓘ Hydroniumjarosite	(H₃O)Fe₃³⁺(SO₄)₂(OH)₆
O	ⓘ Jarosite	KFe₃³⁺(SO₄)₂(OH)₆
O	ⓘ Muscovite	KAl₂(AlSi₃O₁₀)(OH)₂
O	ⓘ Pharmacosiderite	KFe₄³⁺(AsO₄)₃(OH)₄ · 6-7H₂O
O	ⓘ Picropharmacolite	Ca₄Mg(AsO₄)₂(HAsO₄)₂ · 11H₂O
O	ⓘ Quartz	SiO₂
O	ⓘ Sanidine	K(AlSi₃O₈)
O	ⓘ Scorodite	Fe³⁺AsO₄ · 2H₂O
O	ⓘ Siderite	FeCO₃
O	ⓘ Natropharmacosiderite	NaFe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
O	ⓘ Starkeyite	MgSO₄ · 4H₂O
O	ⓘ Talmessite	Ca₂Mg(AsO₄)₂ · 2H₂O
O	ⓘ Wallkilldellite	Ca₂Mn₃²⁺(AsO₄)₂(OH)₄ · 9H₂O
O	ⓘ Manganlotharmeyerite	CaMn₂³⁺(AsO₄)₂(OH)₂
O	ⓘ Hydroniumpharmacosiderite	(H₃O)Fe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
O	ⓘ Kaolinite Subgroup	Al₂Si₂O₅(OH)₄
O	ⓘ Thalliumpharmacosiderite	TlFe₄³⁺[(AsO₄)₃(OH)₄] · 4H₂O
O	ⓘ Unnamed (Tl(I) Oxide)	Tl₂O
O	ⓘ UM1994-01-AsO:FeHSTl	Fe₂TlAs₃O₁₂ · 4H₂O
O	ⓘ Unnamed (Tl Arsenate I)	Tl, As, O, H(?)
O	ⓘ Unnamed (Tl Arsenate II)	Tl, As, O, H(?)
F	Fluorine
F	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
Na	Sodium
Na	ⓘ Natropharmacosiderite	NaFe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
Mg	Magnesium
Mg	ⓘ Ankerite	Ca(Fe²⁺,Mg)(CO₃)₂
Mg	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
Mg	ⓘ Dolomite	CaMg(CO₃)₂
Mg	ⓘ Hörnesite	Mg₃(AsO₄)₂ · 8H₂O
Mg	ⓘ Picropharmacolite	Ca₄Mg(AsO₄)₂(HAsO₄)₂ · 11H₂O
Mg	ⓘ Starkeyite	MgSO₄ · 4H₂O
Mg	ⓘ Talmessite	Ca₂Mg(AsO₄)₂ · 2H₂O
Al	Aluminium
Al	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
Al	ⓘ Muscovite	KAl₂(AlSi₃O₁₀)(OH)₂
Al	ⓘ Sanidine	K(AlSi₃O₈)
Al	ⓘ Kaolinite Subgroup	Al₂Si₂O₅(OH)₄
Si	Silicon
Si	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
Si	ⓘ Muscovite	KAl₂(AlSi₃O₁₀)(OH)₂
Si	ⓘ Quartz	SiO₂
Si	ⓘ Sanidine	K(AlSi₃O₈)
Si	ⓘ Kaolinite Subgroup	Al₂Si₂O₅(OH)₄
S	Sulfur
S	ⓘ Bernardite	TlAs₅S₈
S	ⓘ Christite	TlHgAsS₃
S	ⓘ Cinnabar	HgS
S	ⓘ Dorallcharite	TlFe₃³⁺(SO₄)₂(OH)₆
S	ⓘ Fangite	Tl₃AsS₄
S	ⓘ Fibroferrite	Fe³⁺(SO₄)(OH) · 5H₂O
S	ⓘ Gypsum	CaSO₄ · 2H₂O
S	ⓘ Hydroniumjarosite	(H₃O)Fe₃³⁺(SO₄)₂(OH)₆
S	ⓘ Jankovićite	Tl₅Sb₉(As,Sb)₄S₂₂
S	ⓘ Jarosite	KFe₃³⁺(SO₄)₂(OH)₆
S	ⓘ Lorándite	TlAsS₂
S	ⓘ Marcasite	FeS₂
S	ⓘ Orpiment	As₂S₃
S	ⓘ Parapierrotite	TlSb₅S₈
S	ⓘ Picotpaulite	TlFe₂S₃
S	ⓘ Plagionite	Pb₅Sb₈S₁₇
S	ⓘ Pyrite	FeS₂
S	ⓘ Pyrrhotite	Fe_1-xS
S	ⓘ Raguinite	TlFeS₂
S	ⓘ Realgar	As₄S₄
S	ⓘ Rebulite	Tl₅Sb₅As₈S₂₂
S	ⓘ Simonite	TlHgAs₃S₆
S	ⓘ Starkeyite	MgSO₄ · 4H₂O
S	ⓘ Stibnite	Sb₂S₃
S	ⓘ Vrbaite	Hg₃Tl₄As₈Sb₂S₂₀
Cl	Chlorine
Cl	ⓘ Lafossaite	Tl(Cl,Br)
K	Potassium
K	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
K	ⓘ Jarosite	KFe₃³⁺(SO₄)₂(OH)₆
K	ⓘ Muscovite	KAl₂(AlSi₃O₁₀)(OH)₂
K	ⓘ Pharmacosiderite	KFe₄³⁺(AsO₄)₃(OH)₄ · 6-7H₂O
K	ⓘ Sanidine	K(AlSi₃O₈)
Ca	Calcium
Ca	ⓘ Ankerite	Ca(Fe²⁺,Mg)(CO₃)₂
Ca	ⓘ Arseniosiderite	Ca₂Fe₃³⁺(AsO₄)₃O₂ · 3H₂O
Ca	ⓘ Calcite	CaCO₃
Ca	ⓘ Dolomite	CaMg(CO₃)₂
Ca	ⓘ Gypsum	CaSO₄ · 2H₂O
Ca	ⓘ Picropharmacolite	Ca₄Mg(AsO₄)₂(HAsO₄)₂ · 11H₂O
Ca	ⓘ Talmessite	Ca₂Mg(AsO₄)₂ · 2H₂O
Ca	ⓘ Wallkilldellite	Ca₂Mn₃²⁺(AsO₄)₂(OH)₄ · 9H₂O
Ca	ⓘ Manganlotharmeyerite	CaMn₂³⁺(AsO₄)₂(OH)₂
Ti	Titanium
Ti	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
Mn	Manganese
Mn	ⓘ Wallkilldellite	Ca₂Mn₃²⁺(AsO₄)₂(OH)₄ · 9H₂O
Mn	ⓘ Manganlotharmeyerite	CaMn₂³⁺(AsO₄)₂(OH)₂
Fe	Iron
Fe	ⓘ Ankerite	Ca(Fe²⁺,Mg)(CO₃)₂
Fe	ⓘ Arseniosiderite	Ca₂Fe₃³⁺(AsO₄)₃O₂ · 3H₂O
Fe	ⓘ Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
Fe	ⓘ Dorallcharite	TlFe₃³⁺(SO₄)₂(OH)₆
Fe	ⓘ Fibroferrite	Fe³⁺(SO₄)(OH) · 5H₂O
Fe	ⓘ Goethite	Fe³⁺O(OH)
Fe	ⓘ Hydroniumjarosite	(H₃O)Fe₃³⁺(SO₄)₂(OH)₆
Fe	ⓘ Jarosite	KFe₃³⁺(SO₄)₂(OH)₆
Fe	ⓘ Marcasite	FeS₂
Fe	ⓘ Pharmacosiderite	KFe₄³⁺(AsO₄)₃(OH)₄ · 6-7H₂O
Fe	ⓘ Picotpaulite	TlFe₂S₃
Fe	ⓘ Pyrite	FeS₂
Fe	ⓘ Pyrrhotite	Fe_1-xS
Fe	ⓘ Raguinite	TlFeS₂
Fe	ⓘ Scorodite	Fe³⁺AsO₄ · 2H₂O
Fe	ⓘ Siderite	FeCO₃
Fe	ⓘ Natropharmacosiderite	NaFe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
Fe	ⓘ Hydroniumpharmacosiderite	(H₃O)Fe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
Fe	ⓘ Thalliumpharmacosiderite	TlFe₄³⁺[(AsO₄)₃(OH)₄] · 4H₂O
Fe	ⓘ UM1994-01-AsO:FeHSTl	Fe₂TlAs₃O₁₂ · 4H₂O
As	Arsenic
As	ⓘ Arseniosiderite	Ca₂Fe₃³⁺(AsO₄)₃O₂ · 3H₂O
As	ⓘ Bernardite	TlAs₅S₈
As	ⓘ Christite	TlHgAsS₃
As	ⓘ Claudetite	As₂O₃
As	ⓘ Fangite	Tl₃AsS₄
As	ⓘ Hörnesite	Mg₃(AsO₄)₂ · 8H₂O
As	ⓘ Jankovićite	Tl₅Sb₉(As,Sb)₄S₂₂
As	ⓘ Lorándite	TlAsS₂
As	ⓘ Orpiment	As₂S₃
As	ⓘ Pharmacosiderite	KFe₄³⁺(AsO₄)₃(OH)₄ · 6-7H₂O
As	ⓘ Picropharmacolite	Ca₄Mg(AsO₄)₂(HAsO₄)₂ · 11H₂O
As	ⓘ Realgar	As₄S₄
As	ⓘ Rebulite	Tl₅Sb₅As₈S₂₂
As	ⓘ Scorodite	Fe³⁺AsO₄ · 2H₂O
As	ⓘ Simonite	TlHgAs₃S₆
As	ⓘ Natropharmacosiderite	NaFe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
As	ⓘ Talmessite	Ca₂Mg(AsO₄)₂ · 2H₂O
As	ⓘ Vrbaite	Hg₃Tl₄As₈Sb₂S₂₀
As	ⓘ Wallkilldellite	Ca₂Mn₃²⁺(AsO₄)₂(OH)₄ · 9H₂O
As	ⓘ Manganlotharmeyerite	CaMn₂³⁺(AsO₄)₂(OH)₂
As	ⓘ Hydroniumpharmacosiderite	(H₃O)Fe₄³⁺(AsO₄)₃(OH)₄ · 4H₂O
As	ⓘ Thalliumpharmacosiderite	TlFe₄³⁺[(AsO₄)₃(OH)₄] · 4H₂O
As	ⓘ UM1994-01-AsO:FeHSTl	Fe₂TlAs₃O₁₂ · 4H₂O
As	ⓘ Unnamed (Tl Arsenate I)	Tl, As, O, H(?)
As	ⓘ Unnamed (Tl Arsenate II)	Tl, As, O, H(?)
Br	Bromine
Br	ⓘ Lafossaite	Tl(Cl,Br)
Ag	Silver
Ag	ⓘ Native Gold var. Electrum	(Au,Ag)
Ag	ⓘ Native Silver	Ag
Sb	Antimony
Sb	ⓘ Jankovićite	Tl₅Sb₉(As,Sb)₄S₂₂
Sb	ⓘ Parapierrotite	TlSb₅S₈
Sb	ⓘ Plagionite	Pb₅Sb₈S₁₇
Sb	ⓘ Rebulite	Tl₅Sb₅As₈S₂₂
Sb	ⓘ Stibnite	Sb₂S₃
Sb	ⓘ Vrbaite	Hg₃Tl₄As₈Sb₂S₂₀
Au	Gold
Au	ⓘ Native Gold var. Electrum	(Au,Ag)
Au	ⓘ Native Gold	Au
Hg	Mercury
Hg	ⓘ Christite	TlHgAsS₃
Hg	ⓘ Cinnabar	HgS
Hg	ⓘ Simonite	TlHgAs₃S₆
Hg	ⓘ Vrbaite	Hg₃Tl₄As₈Sb₂S₂₀
Tl	Thallium
Tl	ⓘ Bernardite	TlAs₅S₈
Tl	ⓘ Christite	TlHgAsS₃
Tl	ⓘ Dorallcharite	TlFe₃³⁺(SO₄)₂(OH)₆
Tl	ⓘ Fangite	Tl₃AsS₄
Tl	ⓘ Jankovićite	Tl₅Sb₉(As,Sb)₄S₂₂
Tl	ⓘ Lorándite	TlAsS₂
Tl	ⓘ Parapierrotite	TlSb₅S₈
Tl	ⓘ Picotpaulite	TlFe₂S₃
Tl	ⓘ Raguinite	TlFeS₂
Tl	ⓘ Rebulite	Tl₅Sb₅As₈S₂₂
Tl	ⓘ Simonite	TlHgAs₃S₆
Tl	ⓘ Vrbaite	Hg₃Tl₄As₈Sb₂S₂₀
Tl	ⓘ Lafossaite	Tl(Cl,Br)
Tl	ⓘ Thalliumpharmacosiderite	TlFe₄³⁺[(AsO₄)₃(OH)₄] · 4H₂O
Tl	ⓘ Unnamed (Tl(I) Oxide)	Tl₂O
Tl	ⓘ UM1994-01-AsO:FeHSTl	Fe₂TlAs₃O₁₂ · 4H₂O
Tl	ⓘ Unnamed (Tl Arsenate I)	Tl, As, O, H(?)
Tl	ⓘ Unnamed (Tl Arsenate II)	Tl, As, O, H(?)
Pb	Lead
Pb	ⓘ Plagionite	Pb₅Sb₈S₁₇

Localities in this Region

North Macedonia

Kavadarci Municipality
- Ržanovo
  - Allchar
    - Crven Dol
      - Adit No. 21
      - Adit No. 25

Other Regions, Features and Areas containing this locality

Eurasian PlateTectonic Plate

DinaridesAccretionary Complex

EuropeContinent

This page contains all mineral locality references listed on mindat.org. This does not claim to be a complete list. If you know of more minerals from this site, please register so you can add to our database. This locality information is for reference purposes only. You should never attempt to visit any sites listed in mindat.org without first ensuring that you have the permission of the land and/or mineral rights holders for access and that you are aware of all safety precautions necessary.

References

Balić Žunić, T., Stafilov, T. & Tibljaš, D. (1993): Distribution of thallium and the ore genesis at the Crven Dol locality in Alšar. Geologica Macedonica, 7, 45-52.

Janković, S., Jelenković, R. (1994) Thallium mineralization in the Allchar Sb-As-Tl-Au deposit. Neues Jahrbuch für Mineralogie, Abhandlungen: 167: 283-297.

Karamata, S., Pavićević, M.K., Korikovskij, S.K., Boronihin, V.A., Amthauer, G. (1994) Petrology and mineralogy of Neogene volcanic rocks from the Allchar area, the FY Republic of Macedonia. Neues Jahrbuch für Mineralogie, Abhandlungen: 167: 317-328.

Boev, I., Boev, B. (2015). The Crven Dol Arsenic-Thalium Mineralization in Alsar Deposit in the Republic of Macedonia. Natural Resources and Technology: 9(9): 59-76.

Ðorđević, T., Kolitsch, U., Drahota, P., Knappová, M., Majzlan, J., Kiefer, S., Mikuš, T., Serafimovski, T., Tasev, G., Boev, I., Boev, B. (2020) Thallium mobility in mining wastes at the Crven Dol locality, Allchar deposit, North Macedonia. EGU General Assembly 2020, Vienna, Austria, May 3-8, Geophysical Research Abstracts 22, EGU2012-4959.

Ðorđević, T., Drahota, P., Kolitsch, U., Majzlan, J., Kiefer, S., Tepe, N., Hofmann, T., Serafimovski, T., Tasev, G., Boev, I., Boev, B. (2021) Geogenic thallium-extreme environments: in which secondary phases is Tl(I) incorporated? Oral presentation, MinPet 2021, Vienna, Austria, September 19-21, 2021; abstract in Mitteilungen der Österreichischen Mineralogischen Gesellschaft: 167: 84.

Steinfeld, A., Ðorđević, T., Kolitsch, U., Nagl, P., Tasev, G., Serafimovski, T., Boev, I., Boev, B. (2021): An update on secondary thallium minerals. Poster, MinPet 2021, Vienna, Austria, September 19-21, 2021; abstract in Mitteilungen der Österreichischen Mineralogischen Gesellschaft: 167: 145.

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