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Biringuccite

A valid IMA mineral species
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About BiringucciteHide

06702890017271921538541.jpg
Vannoccio Biringuccio (1480-1538/9)
Formula:
Na2B5O8(OH) · H2O
Colour:
White to pale yellow.
Specific Gravity:
2.32
Crystal System:
Monoclinic
Name:
To honor Vannoccio Biringuccio (1480, Siena, Italy – 1538/9, ?), Italian alchemist, metallurgist, politician, mine manager and foundryman; author of the Pirotechnia, his manual on metalworking, published in 1540. He is considered by some as the father of the foundry industry as De la pirotechnia is the first written account of proper foundry practice. He was in charge of casting cannons for Venice and later Florence. In 1536, he was offered a position in Rome by the Catholic Church, and in 1538 he became head of the papal foundry, and director of munitions. He was a Senator of the city of Siena in January and February of 1531.
This page provides mineralogical data about Biringuccite.


Unique IdentifiersHide

Mindat ID:
679
Long-form identifier:
mindat:1:1:679:0

IMA Classification of BiringucciteHide

Classification of BiringucciteHide

6.EC.05

6 : BORATES
E : Pentaborates
C : Phyllo-pentaborates
26.5.7.1

26 : HYDRATED BORATES CONTAINING HYDROXYL OR HALOGEN
5 : Pentaborates
9.1.4

9 : Borates
1 : Borates of the alkalis and boric acid

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BgcIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BiringucciteHide

Transparency:
Transparent
Colour:
White to pale yellow.
Density:
2.32 g/cm3 (Measured)    2.297 g/cm3 (Calculated)
Comment:
Measured on synthetic material

Optical Data of BiringucciteHide

Type:
Biaxial (-)
RI values:
nα = 1.496(2) nβ = 1.539(2) nγ = 1.557(2)
2V:
Measured: 62° , Calculated: 64°
Max. Birefringence:
δ = 0.061
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
relatively weak

Chemistry of BiringucciteHide

Mindat Formula:
Na2B5O8(OH) · H2O
Element Weights:
Element% weight
O60.822 %
B20.549 %
Na17.479 %
H1.150 %

Calculated from ideal end-member formula.
O
B
Na
H

Crystallography of BiringucciteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/c
Setting:
P21/c
Cell Parameters:
a = 11.1955(7) Å, b = 6.5607(4) Å, c = 20.7566(9) Å
β = 93.891(6)°
Ratio:
a:b:c = 1.706 : 1 : 3.164
Unit Cell V:
1,521.06 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space group determined on synthetic material.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000418BiringucciteCorazza E, Menchetti S, Sabelli C (1974) The crystal structure of biringuccite, Na4[B10O16(OH)2].2H2O American Mineralogist 59 1005-101519740293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47c : [Carbonates, phosphates, borates, nitrates]
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals
57 : Other minerals formed by human processes

Type Occurrence of BiringucciteHide

Place of Conservation of Type Material:
University of Florence, Florence, Italy, 16802/703; National Museum of Natural History, Washington, D.C., USA, 163785.
Geological Setting of Type Material:
As scales on piping in a geothermal field.
Associated Minerals at Type Locality:

Other Language Names for BiringucciteHide

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Biringuccite associated with NasiniteNa2[B5O8(OH)] · 2H2O

Related Minerals - Strunz-mindat GroupingHide

6.EC.CalcioveatchiteSrCaB11O16(OH)5 · 5H2OMon. 2 : P21
6.EC.05NasiniteNa2[B5O8(OH)] · 2H2OOrth. mmm(2/m2/m2/m)
6.EC.10GoweriteCa[B5O8(OH)][B(OH)3] · 3H2OMon. 2/m : P21/c
6.EC.15'Veatchite-2M'Sr2B11O16(OH)5 · H2OMon. m : Bb
6.EC.15'Veatchite-A'Sr2B11O16(OH)5 · H2OTric. 1 : P1
6.EC.15VeatchiteSr2B11O16(OH)5 · H2OMon. m : Bb
6.EC.15'Veatchite-1M'Sr2B11O16(OH)5 · H2OMon. 2 : P21
6.EC.20VolkovskiteKCa4[B5O8OH]4[B(OH)3]2Cl · 4H2OTric. 1 : P1
6.EC.25TuzlaiteNaCaB5O8(OH)2 · 3H2OMon. 2/m : P21/c
6.EC.30HeidorniteNa2Ca3B5O8(SO4)2Cl(OH)2Mon. 2/m : B2/b
6.EC.35PopugaevaiteCa3[B5O6(OH)6]FCl2 · 8H2OMon. m : Pm
6.EC.35BrianroulstoniteCa3[B5O6(OH)6](OH)Cl2 · 8H2OMon. m

Other InformationHide

Notes:
Soluble in water
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BiringucciteHide

References for BiringucciteHide

Localities for BiringucciteHide

Showing 1 localities.

ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Tuscany
    • Pisa Province
      • Pomarance
Cipriani (1961) +3 other references
 
and/or  
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