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Franklinfurnaceite

A valid IMA mineral species
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About FranklinfurnaceiteHide

Formula:
Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8
Zn is tetrahedrally coordinated.
Colour:
Dark reddish brown to brownish black
Lustre:
Sub-Vitreous, Resinous, Waxy
Hardness:
3
Specific Gravity:
3.66
Crystal System:
Monoclinic
Member of:
Name:
Named in 1987 by Pete J. Dunn, Donald R. Peacor, Robert A. Ramik, Shu-Chun Su, and Roland C. Rouse for an old name of the town, "Franklin Furnace". The town became "Franklin [borough]" on April 23, 1913.
Isostructural with:
Intergrown clusters or rosettes of dark red brown plates implanted on hodgkinsonite crystals in open cavities. A second much more uncommon find occurred as nearly black filamentous crystals associated with nelenite in open cavities. Franklinfurnaceite has the chlorite group structure, but has unusual chemical composition. It represents the very rare case of a zincosilicate, in which zinc atoms replace Si atoms in (SiO4) tetrahedra (Gaines et al., 1997).


Unique IdentifiersHide

Mindat ID:
1597
Long-form identifier:
mindat:1:1:1597:0

IMA Classification of FranklinfurnaceiteHide

Classification of FranklinfurnaceiteHide

9.EC.55

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.4.3.1

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
4 : Sheets of 6-membered rings interlayered 1:1, 2:1, and octahedra
14.7.23

14 : Silicates not Containing Aluminum
7 : Silicates of Ba, Sr and Zn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
FkfIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
FkfWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of FranklinfurnaceiteHide

Sub-Vitreous, Resinous, Waxy
Transparency:
Translucent
Comment:
Luster is not vitreous
Colour:
Dark reddish brown to brownish black
Streak:
Dark brown
Hardness:
Tenacity:
Very brittle
Cleavage:
Perfect
{001}
Fracture:
Micaceous
Density:
3.66 g/cm3 (Measured)    3.74 g/cm3 (Calculated)

Optical Data of FranklinfurnaceiteHide

Type:
Biaxial (-)
RI values:
nα = 1.792 nβ = 1.798 nγ = 1.802
2V:
Measured: 79° , Calculated: 78°
Birefringence:
0.10
Max. Birefringence:
δ = 0.010
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v perceptible
Optical Extinction:
Z=b, Y = 29 degrees from c
Pleochroism:
Visible
Comments:
X very dark brown, Z deep brown, Y brown

Chemistry of FranklinfurnaceiteHide

Mindat Formula:
Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8

Zn is tetrahedrally coordinated.
Element Weights:
Element% weight
O34.336 %
Mn26.200 %
Zn15.590 %
Ca9.557 %
Si6.697 %
Fe6.658 %
H0.961 %

Calculated from ideal end-member formula.
O
Mn
Zn
Ca
Si
Fe
H
Common Impurities:
Mg

Crystallography of FranklinfurnaceiteHide

Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
B2
Cell Parameters:
a = 5.48 Å, b = 9.39 Å, c = 14.51 Å
β = 97.05°
Ratio:
a:b:c = 0.584 : 1 : 1.545
Unit Cell V:
741.00 ų (Calculated from Unit Cell)
Morphology:
Platy pseudohexagonal crystals, also plumose to filamentous.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001192FranklinfurnaceitePeacor D R, Rouse R C, Bailey S W (1988) Crystal structure of franklinfurnaceite: A tri-dioctahedral zincosilicate intermediate between chlorite and mica American Mineralogist 73 876-88719880293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits

Type Occurrence of FranklinfurnaceiteHide

General Appearance of Type Material:
Very thin, platy crystal, rarely to 0.3 mm. Sometimes as as polycrystalline aggregates up to 1.0 cm in diameter. Similar in appearance bannisterite and ganophyllite but in a different assemblage.
Place of Conservation of Type Material:
National Museum of Natural History (Smithsonian Institution), Washington, D.C., USA, numbers C06309 and R19144.
Associated Minerals at Type Locality:

Synonyms of FranklinfurnaceiteHide

Other Language Names for FranklinfurnaceiteHide

Relationship of Franklinfurnaceite to other SpeciesHide

Member of:
Other Members of Chlorite Group:
BaileychloreZn5Al(AlSi3O10)(OH)8Tric. 1
Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
ChamositeFe2+5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
DonbassiteAl4.33(AlSi3O10)(OH)8Mon. 2 : B2
GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
GonyeriteMn2+5Fe3+(Fe3+Si3O10)(OH)8Orth.
NimiteNi5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
SudoiteMg2Al3(AlSi3O10)(OH)8Mon. 2/m : B2/m
VakhrushevaiteMg5Cr(AlSi3O10)(OH)8Tric. 1

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Franklinfurnaceite associated with HodgkinsoniteMn2+Zn2(SiO4)(OH)2
2 photos of Franklinfurnaceite associated with FrankliniteZn2+Fe3+2O4

Related Minerals - Strunz-mindat GroupingHide

9.EC.MeifuiteKFe6(Si7Al)O19(OH)4Cl2Tric. 1 : P1
9.EC.BalestraiteKLi2V5+Si4O12Mon. 2 : B2
9.EC.VoloshiniteRb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.
9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon. 2/m
9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.
9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15GanteriteBa0.5(Na,K)0.5Al2(Si2.5Al1.5)O10(OH)2Mon. 2/m : B2/b
9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
9.EC.15RoscoeliteKV3+2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Tobelite(NH4)Al2(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 : B2
9.EC.15MontdoriteKFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2Mon. 2/m : B2/m
9.EC.15ChromphylliteKCr2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
9.EC.15'UM1988-22-SiO:AlCaFFeHKLiMg'KLiMgAl2Si3O10F2Mon.
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.20MasutomiliteK(LiAlMn2+)[AlSi3O10]F2Mon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.20'Chloroferrokinoshitalite'(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20TetraferriphlogopiteKMg3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.20FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4Mon. 2/m : B2/m
9.EC.20'UM2004-49-SiO:AlCsFHKLi'(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.22'Pimelite'Ni3Si4O10(OH)2 · 4H2OHex.
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon. 2/m : B2/m
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon. 2/m : B2/m
9.EC.35ClintoniteCaAlMg2(SiAl3O10)(OH)2Mon. 2/m : B2/m
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.35BityiteCaLiAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m : B2/m
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
9.EC.45ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.
9.EC.45HanjiangiteBa2CaV3+Al(H2AlSi3O12)(CO3)2FMon. 2 : B2
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.52'Tarasovite'near NaKAl11Si13O40(OH)9 · 3H2O
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55VakhrushevaiteMg5Cr(AlSi3O10)(OH)8Tric. 1
9.EC.55NimiteNi5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
9.EC.55GonyeriteMn2+5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55ChamositeFe2+5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55'Orthochamosite'(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55BaileychloreZn5Al(AlSi3O10)(OH)8Tric. 1
9.EC.55SudoiteMg2Al3(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55DonbassiteAl4.33(AlSi3O10)(OH)8Mon. 2 : B2
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon. 2/m : B2/m
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m(32/m) : P31m
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon. 2 : P21
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Fluorescence of FranklinfurnaceiteHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FranklinfurnaceiteHide

References for FranklinfurnaceiteHide

Localities for FranklinfurnaceiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • New Jersey
    • Sussex County
      • Franklin
Dunn et al. (1987) +1 other reference
 
and/or  
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